A honeycomb structure includes a pillar-shaped honeycomb structure body having a porous partition wall disposed to surround a plurality of cells, which serving as fluid through channels extending from a first end face to a second end face, wherein the plurality of cells includes: large opening cells having a large opening area on the first end face and the second end face; and small opening cells having an opening area smaller than that of the large opening cells on the first end face and the second end face, a ratio of an opening diameter of the large opening cells to an opening diameter of the small opening cells is larger than 1.11 and smaller than 1.28, and the opening diameter of the small opening cells is larger than 0.78 mm, and a cell density of the honeycomb structure body is larger than 93 pcs/cm.sup.2 and smaller than 104 pcs/cm.sup.2.

A particulate filter and method of manufacture. The particulate filter includes intersecting walls that define longitudinally extending channels The intersecting walls comprise a porous ceramic material having a bare microstructure that comprises an interconnected network of porous spheroidal ceramic beads that has an open intrabead porosity within the beads and an interbead porosity defined by interstices between the beads. Catalyst particles are deposited at least partially within the intrabead porosity within the interbead porosity. The bare microstructure has a bimodal pore size distribution in which an intrabead median pore size of the intrabead porosity is less than an interbead median pore size of the interbead porosity. The filter has a trimodal pore size distribution comprising a first peak corresponding to the interbead porosity, a second peak corresponding to the intrabead porosity, and a third peak corresponding to the intrabead porosity as blocked by the catalyst particles.

The honeycomb catalyst body is equipped with a honeycomb structure body having partition walls that define a plurality of cells extending from a first end face as one of the end faces to a second end face as the other end face and serving as through channels of a fluid. The partition walls each have a base layer containing from 50 to 90 mass % of zeolite and a coat layer with which the surface of the base layer 11 is coated with a thickness of from 1 to 50 μm. The coat layer is either a coat layer (A) containing from 1 to 5 mass % vanadia and titania or a coat layer (B) containing from 1 to 5 mass % vanadia and a composite oxide of titania and tungsten oxide.

The present invention relates to a metal oxide coated composite comprising a core consisting of a mixture of a La stabilised AI.sub.2O.sub.3 phase and an Ce/Zr/RE.sub.2O.sub.3 mixed oxide phase, the core having a specific crystallinity, specific pore volume and a specific pore size distribution, and a method for the production of the metal oxide coated composite.

The honeycomb structure body has a dense part at a part in axial direction including a center region of the inflow end face, the dense part having a change ratio of porosity calculated by the following Expression (1) that is 2 to 8%, and has an outside-diameter increasing part, and the honeycomb structure body has a change ratio of average diameter calculated by the following Expression (2) that is 0.2 to 3%,

(1−Px/Py)×100, Expression (1): in Expression (1), Px denotes the porosity (%) at the center region of the inflow end face, and Py denotes the porosity (%) of a circumferential region of the inflow end face.

(1−Dx/Dy)×100,   Expression (2): in Expression (2), Dx denotes the average diameter (mm) of the inflow end face, and Dy denotes the average diameter (mm) of the outflow end face.

A method for producing a ceramic honeycomb structure comprising a ceramic honeycomb body having large numbers of longitudinal cells partitioned by porous cell walls having porosity of 50% or more, and a peripheral wall formed on a peripheral surface of the ceramic honeycomb body, comprising the steps of extruding moldable ceramic material to form a honeycomb-structured ceramic green body; machining a peripheral portion of the green body or a sintered body obtained from the green body to remove part of cell walls in the peripheral portion to obtain a ceramic honeycomb body having longitudinal grooves on a peripheral surface; applying colloidal metal oxide to a peripheral surface of the ceramic honeycomb body and drying it, and then applying a coating material comprising ceramic aggregate having an average particle size of 1 μm or more to form the peripheral wall.

A method for producing a catalyst or catalyst precursor is described including: applying a slurry of a particulate catalyst compound in a carrier fluid to an additive layer manufactured support structure to form a slurry-impregnated support, and drying and optionally calcining the slurry-impregnated support to form a catalyst or catalyst precursor. The mean particle size (D50) of the particulate catalyst compound in the slurry is in the range 1-50 μm and the support structure has a porosity ≧0.02 ml/g.

The honeycomb structure includes a honeycomb structure body and a pair of electrode members disposed on a side surface of the honeycomb structure body, each of the pair of electrode members is shaped in the form of a band extending in a cell extending direction, and in a cross section perpendicular to the extending direction of cells, one electrode member is disposed on a side opposite to the other electrode member via a center of the honeycomb structure body, one or more slits opened in the side surface are formed in the honeycomb structure body, the honeycomb structure body has a charging material charged into the at least one slit, the charging material contains aggregates and a neck material, and a ratio (α2/α1) of a thermal expansion coefficient α2 of the charging material to a thermal expansion coefficient α1 of the honeycomb structure body is from 0.6 to 1.5.

A honeycomb body with a honeycomb structure having an inner zone of a first plurality of walls and an outer zone of a second plurality of walls at least partially surrounding the inner zone. The honeycomb structure has Pi that is greater than Po and MPSi that is greater than MPSo, wherein Pi is an average bulk porosity of the first plurality of walls, Po is an average bulk porosity of the second plurality of walls, MPSi is a median pore size of pores in the first plurality of walls, and MPSo is a median pore size of pores in the second plurality of walls. Various honeycomb structures, honeycomb extrusion apparatus, and co-extrusion methods are disclosed.

A honeycomb structure includes a pillar-shaped honeycomb structure body including porous partition walls defining and forming a plurality of cells which extend from an inflow end face to an outflow end face, and a porous outer wall surrounding the partition walls, a porous supporting bulge disposed to extend out from a circumference of the outer wall so that at least a part of the outer wall is exposed, and plugging portions arranged in open ends of the cells, and the supporting bulge has support portions and a side wall portion, and the partition walls and the outer wall of the honeycomb structure body and the support portions and the side wall portion of the supporting bulge are all formed monolithically by formation of a ceramic raw material.