A nanozeolite modified green concrete contains alkali-activated natural pozzolan. Natural pozzolan is a green and sustainable material, potentially useful in green concrete, e.g., to curb greenhouse gas emissions associated with ordinary Portland cement production. Nanozeolite (NZ) is present as an additive to the green concrete, e.g., at 3 to 5 wt. %, of natural pozzolan to improve strength development and microstructural properties, resulting in superior strength and denser microstructure compared to a green concrete without nanozeolite.

Clay polymer nanocomposites may be mixed with an aggregate material and heat treated to make a structural stabilizer. In an embodiment, the composition is a structural stabilizer resulting from thermal casting and heat treatment. The structural stabilizer does not include cement or water. The heat treatment may be any suitable heat application, including microwave heating, convection oven heating or heating in thermal mixers. The structural stabilizer can be rapidly synthesized to provide high compressive strength and high homogeneity, and to be substantially free of fractures and cracks. Methods of repairing cracks in concrete and stabilizing soil, rock and sand dune formations using the structural stabilizer include thermal casting. Thermal casting ductile concrete molds can include a coating of aluminum foil. The concrete is self-compact, ecofriendly, lightweight, self-repairing and self pre-stressing with homogeneity and low density. The concrete resists steel corrosion, sudden collapse, and does not produce pollution.

A variety of systems, methods and compositions are disclosed, including, in one method, a method of cementing may comprise: providing a cement composition comprising: a hydraulic cement comprising Portland cement in an amount of about 50% by weight of hydraulic cement or less, water, and a phosphorylated amino polycarboxylic acid cement retarder; placing the cement composition in a wellbore; and allowing the cement composition to set. A cement composition, the composition comprising: a hydraulic cement comprising Portland cement in an amount of about 50% by weight of hydraulic cement or less; water; and a phosphorylated amino polycarboxylic acid cement retarder.

The disclosure relates to embodiments of a thixotropic, non-cementitious, thermal grout and applications or methods of use of the grout related to horizontal directional drilling, trenchless technology, trenching, and installation of pipe, conduits, ducts, utility lines, and other product lines which may, e.g., be in trenches, underground, or under obstacles, such as a body of water or roadways.

A green concrete and mortar compositions free of Portland cement are disclosed. The compositions comprise Natural pozzolan, nanosilica particles, and alkaline activator. The green concrete produced from the composition of the invention is cured at ambient temperature and has higher compressive strength than that of concrete made with Portland cement.

An activator composition for a non-OPC hydraulically-active material comprises CaO or lime and a polycarboxylate-ether-based (PCE) superplasticiser, and is mixable with a hydraulically active material comprising ground granulated blast furnace slag (GGBS) and/or pulverized fuel ash (PFA) to form a cementitious binder. The cementitious binder does not comprise any Portland cement and is, therefore, more environmentally friendly.

A concrete composition for use in construction that is free of cement includes calcium sulfate hemihydrate (CSH), polypropylene (PP) fiber, sand, retarders, and superplasticizers. The retarders include poly condensed amino acid and calcium (Ca) salt. The superplasticizers include specially formulated polycarboxylate powder. Further, a method of using the concrete composition in one or more construction related activities (e.g., architectural applications) includes adding the concrete composition to water in a mixer, the concrete composition including CSH, PP fiber, sand, a retarder, and a superplasticizer; and blending the concrete composition with water in the mixer for a first predetermined amount of time. The method further includes mixing the concrete composition with water at a predetermined sheer in the mixer for a second predetermined amount of time. The method excludes the steps of steam curing, accelerated curing, and water curing that are used in conventional solutions.

A method of providing a chemically inert concrete includes the steps of providing and mixing an aqueous colloidal silica dispersion with a quantity of glass particles. The chemically inert concrete includes, based on dry weight, about 50% to about 95% by weight of the glass particles and about 3% to about 40% by weight of the colloidal silica particles. The chemically inert concrete is substantially or totally free of Group I and Group II metal oxides, exclusive of the glass particles, and is substantially or totally free of cement.

A cement composition for use in a well that penetrates a subterranean formation comprising: hydrated lime; a silicate; and water, wherein the composition is substantially free of a hydraulic cement. A method of treating a subterranean formation comprising: introducing the cement composition into the subterranean formation; and allowing the cement composition to set.

Disclosed is a hydraulic binder composition including: a hydraulic binder including at least one alumino-silicate compound, for example blast furnace slag, and an alkaline or sulfate activator and a maximum of 10 wt % of clinker, preferably between 0 and 10 wt % of clinker; a guanidine salt and/or a zinc salt; a polymer (P) including units of formulae (I) and (II):

##STR00001##