The present invention relates to a zirconia mullite refractory composite comprising 55 wt.-% to 65 wt.-% Al.sub.2O.sub.3, 15 wt.-% to 25 wt.-% SiO.sub.2, 15 wt.-% to 25 wt.-% ZrO.sub.2 and less than 3 wt.-% raw material based impurities, whereby the mineralogical composition of the composite comprises 65 wt.-% to 85 wt.-% mullite and 15 wt.-% to 35 wt.-% zirconia.

Provided are metal oxide ceramic materials and intermediate materials thereof (e.g., nanozirconia gels, nanozirconia green bodies, pre-sintered ceramic bodies, zirconia dental ceramic materials, and dental articles). The nanozirconia gels are formable gels. Also provided are methods of making and using the metal oxide materials and intermediate materials. The nanozirconia gels can be made using, for example, osmotic processing. The nanozirconia gels can be used to make nanozirconia green bodies, pre-sintered ceramic bodies, zirconia dental ceramic materials, and dental article. The nanozirconia green bodies, pre-sintered ceramic bodies, zirconia dental ceramic materials, and dental articles have desirable properties (e.g., optical properties and mechanical properties).

Scalable 3D-printing of ceramics includes dispensing a preceramic polymer at the tip of a moving nozzle into a gel that can reversibly switch between fluid and solid states, and subsequently thermally cross-linking the entire printed part “at-once” while still inside the same gel. The solid gel, including mineral oil and silica nanoparticles, converts to fluid at the tip of the moving nozzle, allows the polymer solution to be dispensed, and quickly returns to a solid state to maintain the geometry of the printed polymer both during printing and the subsequent high temperature (160° C.) cross-linking. The cross-linked part is retrieved from the gel and converted to ceramic by high temperature pyrolysis. This scalable process opens new opportunities for low-cost, high-speed production of complex 3-dimensional ceramic parts, and will be widely used for high temperature and corrosive environment applications, including electronics and sensors, microelectromechanical systems, energy, and structural applications.

Methods and ceramic matrix composite articles formed thereby, as well as systems for making such ceramic matrix composite articles and carrying out such methods are disclosed herein. The methods include preparing a ceramic matrix composite by steps including (a) providing reinforcing fiber, such as carbon fiber, for impregnation; (b) heat treating the reinforcing fiber; (c) impregnating the heat treated reinforcing fiber with a composition comprising a ceramic forming polymer to form a fiber reinforced, ceramic forming polymer pre-preg; and (d) heat molding the fiber reinforced, ceramic forming polymer pre-preg to form a molded ceramic matrix composite article.

A moldable green-body composite includes milling silicon nitride powder with a solvent and adding a surface modifier to the milled slurry to modify a surface of the silicon nitride particles. A polysiloxane in a solvent and a binder are also added to create a green body slurry. The solvents may be polar or non-polar solvents. A sintering aid, such as yttria-alumina, may be added to the slurry as well. A reduced density silicon nitride ceramic is made from the moldable green-body composite by molding the moldable green-body composite in a mold and curing at a curing temperature to convert the moldable green-body composite to a converted composite. The converted composite can then be sintered to form a reduced density silicon nitride ceramic that has a smooth surface finish and requires no post machining or polishing. The reduced density silicon nitride ceramic may also have very good dielectric properties.

A disclosed method of forming a ceramic article includes forming a pre-ceramic polymer article within a mold tool, and performing a first pyrolizing step on the initial pre-ceramic polymer article to form a ceramic article. The method further includes performing at least one pre-heat treatment polymer infiltration and pyrolizing (PIP) cycle on the ceramic article and an initial heat treatment cycle of the ceramic article after the at least one pre-heat treatment PIP cycle. Subsequent PIP cycles and heat treatment cycles are performed in combination to form a ceramic article including a desired density.

A molding material for producing the carbon clusters using biomass as the main raw material, comprising the biomass and a binder as the derived raw material, wherein the molding material is graphitized, the electrical resistivity of the molding material is equal to or less than 100 μΩm, the diffraction pattern of the molding material by powder X-ray diffraction method has one peak between 2θ(θ is the Bragg angle) of 26 to 27°, and the value of ⅓ width divided by the base of the peak is equal to or less than 0.68. The method for producing the molding material for producing the carbon clusters according to any of claims 1 to 6, comprising following steps of: obtaining a molded precursor containing a calcined biomass and a binder; optionally, further baking the precursor; and graphitizing the precursor at a temperature of 2500° C. or higher.

Particles of a refractory metal or a refractory-metal compound capable of decomposing or reacting into refractory-metal nanoparticles, elemental silicon, and an organic compound having a char yield of at least 60% by weight are combined to form a precursor mixture. The mixture is heating, forming a thermoset and/or metal nanoparticles. Further heating form a composition having nanoparticles of a refractory-metal silicide and a carbonaceous matrix. The composition is not in the form of a powder

To a co-precipitating aqueous solution, aqueous solutions containing (a) Tb ions, (b) at least one other rare earth ions selected from the group consisting of Y ions and lanthanoid rare earth ions (excluding Tb ions), (c) Al ions and (d) Sc ions are added; the resulting solution is stirred at a liquid temperature of 50° C. or less to induce a co-precipitate of the components (a), (b), (c) and (d); the co-precipitate is filtered, heated and dehydrated; and the co-precipitate is fired thereafter at from 1,000° C. to 1,300° C., thereby forming a sinterable garnet-type complex oxide powder.

Shaped ceramic abrasive particles include a first surface having a perimeter having a perimeter comprising at least first and second edges. A first region of the perimeter includes the second edge and extends inwardly and terminates at two corners defining first and second acute interior angles. The perimeter has at most four corners that define acute interior angles. A second surface is disposed opposite, and not contacting, the first surface. A peripheral surface is disposed between and connects the first and second surfaces. The peripheral surface has a first predetermined shape. Methods of making the shaped ceramic abrasive particles, and abrasive articles including them are also disclosed.