A ferrite sintered magnet 100 comprises M-type ferrite crystal grains 4 having a hexagonal structure, two-crystal grain boundaries 6a formed between two of the M-type ferrite crystal grains 4, and multiple-crystal grain boundaries 6b surrounded by three or more of the M-type ferrite crystal grains 4. This ferrite sintered magnet 100 contains at least Fe, Ca, B, and Si, and contains B in an amount of 0.005 to 0.9 mass % in terms of B.sub.2O.sub.3, the two-crystal grain boundaries 6a and the multiple-crystal grain boundaries 6b contain Si and Ca, and in a cross-section parallel to a c-axis of the ferrite sintered magnet, when the number of multiple-crystal grain boundaries 6b having a maximum length of 0.49 to 5 m per cross-sectional area of 76 m.sup.2 is N, N is 7 or less.

A ferrite sintered magnet comprising an M type Sr ferrite having a hexagonal structure as a main phase, wherein the ferrite sintered magnet comprises La and Co, a content of B is 0.005 to 0.9% by mass in terms of B.sub.2O.sub.3, a content of Zn is 0.01 to 1.2% by mass in terms of ZnO, and the ferrite sintered magnet satisfies [La]/[Zn]0.79 and [Co]/[Zn]0.67 when an atomic concentration of La is represented by [La], an atomic concentration of Co is represented by [Co], and an atomic concentration of Zn is represented by [Zn].

A ferrite sintered magnet comprising an M type Sr ferrite having a hexagonal structure as a main phase, wherein the ferrite sintered magnet does not substantially comprise a rare earth element and Co, a content of B is 0.005 to 0.9% by mass in terms of B.sub.2O.sub.3, and a content of Zn is 0.01 to 1.2% by mass in terms of ZnO.

This ferrite sintered magnet comprises metallic elements at an atomic ratio represented by formula (1):

Ca.sub.1-w-xR.sub.wSr.sub.xFe.sub.zCo.sub.m (1) in formula (1), R is at least one element selected from the group consisting of rare-earth elements and Bi, and R comprises at least La, in formula (1), w, x, z and m satisfy formulae (2) to (5):

0.360w0.420 (2)

0.110x0.173 (3)

8.51z9.71 (4)

0.208m0.269 (5), and in a section parallel to an axis of easy magnetization, when the number of total ferrite grains is N and the number of ferrite grains having a stacking fault is n, 0n/N0.20 is satisfied.

A ferrite sintered magnet comprises a plurality of main phase grains containing a ferrite having a hexagonal structure, wherein at least some of the main phase grains are core-shell structure grains each having a core and a shell covering the core; and wherein the minimum value of the content of La in the core is [La]c atom %; the minimum value of the content of Co in the core is [Co]c atom %; the maximum value of the content of La in the shell is [La]s atom %; the maximum value of the content of Co in the shell is [Co]s atom %; [La]c+[Co]c is 3.08 atom % or more and 4.44 atom % or less; and [La]s+[Co]s is 7.60 atom % or more and 9.89 atom % or less.

Novel methods of fabricating porous structures (e.g., nanostructures) and resulting structures are disclosed. The novel methods use precision optics to cure a slurry made from one or more powders mixed with photopolymers. Pore size control preferably is achieved by controlling the powder size and powder loading in the slurry. As the disclosed methods are based on optics to control the thickness preferably without any mechanical movements, extreme tight thickness tolerance, as well as control of the profile structure, may be achieved. The novel disclosed methods are highly-cost effective with shorter manufacturing cycle time compared to conventional methods. Moreover, a supporting substrate may not be required as the resultant structure made by the novel fabrication techniques disclosed herein has enough strength to be free-standing.

The present invention relates to a method of printing a composite material (1), for example polymeric, carbonaceous, siliconic or metallic comprising steps of: i) providing a plurality of bundles (2) of reinforcement fibers (4), wherein the reinforcement fibers (4) have a length in the range 3-50 mm and are in the number of about 1,000-100,000 in each bundle (2); ii) aligning the bundles (2) along a predetermined path (X, X); iii) incorporating at least part of the bundles (2) into a matrix (6, 8), for example polymeric, carbonaceous, siliconic or metallic, preserving the alignment along said path (X, X); iv) laying and solidifying at least one layer (8) of the matrix (6, 8) of step iii) to make the composite material (1).

Provided is a ferrite sintered magnet including a ferrite phase having a magnetoplumbite-type crystal structure. x, y, and m satisfy the following Equations (1), (2), and (3) when composition of the ferrite sintered magnet is represented by R.sub.1-xA.sub.xFe.sub.m-yCo.sub.y, where R denotes at least one kind of element selected from rare earth elements including Y and A denotes Ca or Ca and elements including at least one kind selected from Sr or Ba. The content of B in the ferrite sintered magnet is from 0.1% to 0.6% by mass in terms of B.sub.2O.sub.3.

0.2x0.8(1)

0.1y0.65(2)

3m<14(3)

A grain-oriented M-type hexagonal ferrite has the formula MeFe.sub.12O.sub.19, and a dopant effective to provide planar magnetic anisotropy and magnetization in a c-plane, or a cone anisotropy, in the hexagonal crystallographic structure wherein Me is Sr.sup.+, Ba.sup.2+ or Pb.sup.2+, and wherein greater than 30%, preferably greater than 80%, of c-axes of the ferrite grains are aligned perpendicular to the c-plane.

The present invention provides a ferrite sintered magnet comprising (1) main phase grains containing a ferrite having a hexagonal structure, (2) two-grain boundaries formed between two of the main phase grains, and (3) multi-grain boundaries surrounded by three or more of the main phase grains. The above ferrite sintered magnet comprises Ca, R, Sr, Fe and Co, with R being at least one element selected from the group consisting of rare earth elements and Bi, and comprising at least La. The number Nm of the above main phase grains and the number Ng of the above multi-grain boundaries in the cross section including the direction of the easy magnetization axis of the above ferrite sintered magnet satisfy the formula (1A):

50%Nm/(Nm+Ng)65%(1A).