An energy-releasing process for making fertilizer by consumption of a charable, reduced carbon source. The process comprises: (a) combining the carbon source with an oxide of an active metal to form a feedstock for high-temperature processing; (b) heating the feedstock in a furnace to yield an effluent gas entraining a carbide of the active metal; (c) cooling the effluent gas entraining the carbide of the active metal; (d) introducing nitrogen into the cooled effluent gas entraining the carbide of the active metal, to yield a cyanamide of the active metal and elemental carbon; (e) acidically hydrolyzing the cyanamide of the active metal to yield a cyanamide compound and a salt of the active metal; and (f) processing the cyanamide compound to yield an N-type fertilizer.

Provided is a production method for producing a novel fertilizer (e.g., liquid fertilizer) containing a bone tissue degradation product. A production method for producing a fertilizer containing phosphoric acid in accordance with the present disclosure includes at least one of: a step 1 (S7) of producing a fertilizer from a bone solubilization liquid A which has been obtained by treating bone tissue with a solution containing both an acid and a protease; a step 2 (S2) of producing a fertilizer from an acid extract which has been obtained by treating bone tissue with an acid; and a step 3 (S5) of producing a fertilizer from a protease treatment liquid which has been obtained by treating, with a protease, bone tissue which has been treated with an acid.

Provided is a production method for producing a novel fertilizer (e.g., liquid fertilizer) containing a bone tissue degradation product. A production method for producing a fertilizer containing phosphoric acid in accordance with the present disclosure includes at least one of: a step 1 (S7) of producing a fertilizer from a bone solubilization liquid A which has been obtained by treating bone tissue with a solution containing both an acid and a protease; a step 2 (S2) of producing a fertilizer from an acid extract which has been obtained by treating bone tissue with an acid; and a step 3 (S5) of producing a fertilizer from a protease treatment liquid which has been obtained by treating, with a protease, bone tissue which has been treated with an acid.

The present application relates to a process for the reduction of NOx from a gaseous effluent generated in the production of fertilizer comprising the acid digestion of phosphate ore in the presence of urea, wherein said gaseous effluent generated has a NOx composition of 70 to 100 mole % NO.sub.2 and 0 to 30 mole % NO, comprising the steps of: a) contacting said gaseous effluent for 0.5 to 15 seconds with ozone, thereby providing a resultant gas mixture wherein NO and NO.sub.2 present in the NOx are oxidized to higher nitrogen oxides; and; b) removing higher nitrogen oxides from said resultant gas mixture; wherein urea is present during said acid digestion of phosphate ore in an amount of 0.25 wt % or less based on the weight of said phosphate ore; and; ozone is added to said gaseous effluent in an ozone/NOx ratio ranging between 0.5 and 1.4.

The present application relates to a process for the reduction of NOx from a gaseous effluent generated in the production of fertilizer comprising the acid digestion of phosphate ore in the presence of urea, wherein said gaseous effluent generated has a NOx composition of 70 to 100 mole % NO.sub.2 and 0 to 30 mole % NO, comprising the steps of: a) contacting said gaseous effluent for 0.5 to 15 seconds with ozone, thereby providing a resultant gas mixture wherein NO and NO.sub.2 present in the NOx are oxidized to higher nitrogen oxides; and; b) removing higher nitrogen oxides from said resultant gas mixture; wherein urea is present during said acid digestion of phosphate ore in an amount of 0.25 wt % or less based on the weight of said phosphate ore; and; ozone is added to said gaseous effluent in an ozone/NOx ratio ranging between 0.5 and 1.4.

Improved methods for the removal of heavy metals, in particular cadmium, from an aqueous phosphoric acid containing composition, wherein an organothiophosphorous heavy metal precipitating agent and an ionic polymeric surfactant, particularly a cationic polyacrylamide copolymer surfactant, are both added to a phosphoric acid containing composition, particularly under vigorous mixing conditions, such as between 500 and 700 rpm. The ionic polymeric surfactant promotes the precipitation of the heavy metals. More in particular, the phosphoric acid containing composition is obtained by the acid digestion of phosphate rock, preferably by nitric acid, sulfuric acid, or a combination thereof.

Improved methods for the removal of heavy metals, in particular cadmium, from an aqueous phosphoric acid containing composition, wherein an organothiophosphorous heavy metal precipitating agent and an ionic polymeric surfactant, particularly a cationic polyacrylamide copolymer surfactant, are both added to a phosphoric acid containing composition, particularly under vigorous mixing conditions, such as between 500 and 700 rpm. The ionic polymeric surfactant promotes the precipitation of the heavy metals. More in particular, the phosphoric acid containing composition is obtained by the acid digestion of phosphate rock, preferably by nitric acid, sulfuric acid, or a combination thereof.