A nitrogen activator additive to stabilize nitrogen fertilizer, where the activator is coated onto the nitrogen fertilizer, is provided. The nitrogen activator additive contains the novel compound ABT-PNB, a potassium compound, and chitosan, and provides controlled release of the nitrogen fertilizer which fertilizes crops using reduced levels of the nitrogen fertilizer and reduces the release of greenhouse gasses. Urea is an exemplary nitrogen fertilizer that can be used in this regard.

In embodiments, the present invention relates to liquid formulations containing hydrophobic, biodegradable polymers dispersed within a Non-aqueous Organic Solvent Delivery System (NOSDS) that is designed to coat fertilizer granules with a hydrophobic film utilizing simple application equipment such as mixers, blenders and tumblers. This film can impede the dissolution of fertilizer components by water improving fertilizer efficiency. The NOSDS can be aprotic solvents, protic solvents and mixtures of protic and aprotic solvents which are environmentally friendly, have flashpoints above 145 F., and are inherently rated safe for contact with humans and animals. The hydrophobic polymers are the reaction product of aldehyde(s) and nitrogen containing compounds.

An agricultural spray may be produced by admixing citric acid and glutamic acid with a metal salt and a pesticide or other agricultural chemical containing components capable of precipitating with the metal salt in the admixture. The citric acid and the glutamic acid chelate with the metal salt to provide a stability and compatibility-enhancing composition, thereby preventing the metal salt from forming an insoluble solid within the admixture. Such a composition may be produced by admixing citric acid and glutamic acid at a molar ratio of about 6.8:0.5 to about 1:0.29. The composition may include a metal sat, citric acid and glutamic acid in a molar ratio of about 1:6.8:0.5 to about 1:1:0.29 and a pesticide.

An agricultural adjuvant includes microfibrillated cellulose, a dispersant or wetting agent, in a liquid carrier that has been subjected to shear conditions. The resultant adjuvant displays useful rheological structure and the adjuvant is added to agricultural formulations to stabilize and impart useful rheology to the formulations.

Surface-oxygenated biochar compositions and sonication-ozonization methods create advanced hydrophilic biochar materials having higher cation exchange capacity, optimized pH, improved wettability, and toxin free components. These sonicated and ozonized biochar compositions are used as filtration materials for clean water and air, as phosphorus solubilizing reagents to mix with phosphate rock materials to make a slow-releasing phosphate fertilizer, as biochar soil additives to help solubilize phosphorus and reduce phosphorus fertilizer additions required to achieve desired soil phosphorus activity, crop uptake, and yield goals, as sand soilization reagents by utilizing their liquid gel-forming activity in the spaces among sand particles to retain water and nutrients and hold the sand particles together, as plant growth stimulants by using the humic acids-like surface-oxygenated biochar substances at a proper ppm concentration and as carbon sequestration agents to help control climate change for energy and environmental sustainability on Earth.

An agricultural spray may be produced by admixing citric acid and glutamic acid with a metal salt and a pesticide or other agricultural chemical containing components capable of precipitating with the metal salt in the admixture. The citric acid and the glutamic acid chelate with the metal salt to provide a stability and compatibility-enhancing composition, thereby preventing the metal salt from forming an insoluble solid within the admixture. Such a composition may be produced by admixing citric acid and glutamic acid at a molar ratio of about 6.8:0.5 to about 1:0.29. The composition may include a metal sat, citric acid and glutamic acid in a molar ratio of about 1:6.8:0.5 to about 1:1:0.29 and a pesticide.

The present disclosure is concerned with fertilizer compositions that provide controlled, delayed, and/or prolonged release of micronutrients in soil. In one embodiment, the inventive composition comprises a dry, powdered blend of a first target micronutrient source in chelated form and a second source of the same target micronutrient but provided in non-chelated form. In another embodiment, the inventive composition provides at least two sources of boron, with one source being a water-soluble form and the other source being a water-insoluble form. Regardless of the embodiment, the methods of using the fertilizer composition results in increased uptake of the particular micronutrient, nitrogen, and/or potassium compared to the prior art.

In embodiments, the present invention relates to liquid formulations containing hydrophobic, biodegradable polymers disperse within a Non-aqueous Organic Solvent Delivery System (NOSDS) that is designed to coat fertilizer granules with a hydrophobic film utilizing simple application equipment such as mixers, blenders and tumblers. This film can impede the dissolution of fertilizer components by water improving fertilizer efficiency. The NOSDS can be aprotic solvents, protic solvents and mixtures of prone and aprotic solvents which are environmentally friendly, have flashpoints above 145? F. and we inherently rated safe for contact with humans and animals. The hydrophobic polymers an the reaction product of aldehyde(s) and nitrogen containing compounds.

A homogeneous fertilizer granule comprises slow-release (e.g. struvite) and fast release sources of phosphorus (P). The homogeneous fertilizer granule may further contain other essential nutrients and micronutrients required by plants. A number of methods may be used to make such granules. One method includes introducing a struvite slurry or fines and a liquid supply of water soluble P into a granulator. Alternatively, dry raw materials can be mixed with water/steam and/or another binder prior to being fed into a granulator. In another embodiment, pre-mixed dry raw materials are mechanically compacted and crushed to yield homogeneous fertilizer particles.

Interpolymers useful for enhancing the efficacy of nutrients in soil and fertilizers; and methods of inhibiting the precipitation of, and/or dispersing, inorganic elements.