The present invention relates to improving the efficacy of man-made and/or natural organic-based animal manure fertilizers by administration of an organic solvent formula containing polyorganic acids and/or their salts. The formulation liberates nutrient(s) that are normally bound in the soil as insoluble salts and complexes. These delivery formulations also provide an environmentally sound and inherently safe solvating system that improves diffusion of polyorganic acids to the granule fertilizer. These delivery formulations enable safe storage, transport and subsequent application or blending with solid or liquid fertilizers. The combined formulation and fertilizer can be applied to soil to provide improved efficacy of fertilizer by liberating nutrients bound in the soil for uptake by plant life.

A calcium sulfate urea (UCS) fertilizer granule and methods for making and using the same are disclosed. The granule can include urea, calcium sulfate, and a calcium sulfate urea adduct. The granule can contain 33 wt. % to 40 wt. % elemental nitrogen, 2 wt. % to 5 wt. % elemental calcium, and 2 wt. % to 5 wt. % elemental sulfur.

A composition comprising a) one or more seeds and b) a liquid coating wherein the liquid coating is a non-aqueous liquid formulation, wherein said non-aqueous liquid formulation comprises a) one or more Poly(organic acids) [P(OA)]s, and/or their salts, completely dissolved in b) a Non-aqueous Organo Solvent Delivery System (NOSDS), wherein the NOSDS is a delivery system for adding the one or more [P(OA)]s and/or their salts to the surface of said one or more said seeds.

Disclosed is a fertilizer granule containing a core containing at least 90 wt. % of urea, and a shell containing a urea calcium sulfate (UCS) adduct, where the shell covers at least a portion of an outer surface of the core, and blends of the fertilizer granules with other fertilizers. Methods of making and using the fertilizer granule and the blends are also disclosed.

The present invention relates to improving the efficiency of man-made and/or natural organic-based animal manure fertilizers by administration of formulations containing poly(organic acids), [P(OA)]s, and/or their salts dispersed in a Non-aqueous Organic Solvent Delivery System (NOSDS). Utilizing a NOSDS allows for coating all components in a fertilizer formulation including but not limited to Urea, Manure, mono-ammonium phosphate (MAP), di-ammonium phosphate (DAP), solid micronutrients such as lime, zinc chloride, etc.) with a layer of [P(OA)]s and/or their salts that liberates, in a plant available form, the micronutrient metals and macronutrients, that are bound as insoluble salts and complexes in the soil. The carboxylic groups of a [P(OA)] that can exist within the [P(OA)] as carboxylic acids, carboxylic anhydrides and/or carboxylic imides, dispersed within the NOSDS, can be neutralized with one or more metals in the form of elemental metals, metal oxides, metal hydroxides, metal alkylates and metal carbonates and/or nitrogen containing compounds such as ammonia, ammonium hydroxide or organoamines to form a stable dispersion that can contain completely complexed micronutrients and provide the vehicle for the delivery of these nutrients to soils and/or as a coating to the surfaces fertilizer granules and seeds.

Methods and system for increasing the water solubility and availability of zinc in granular fertilizers using acid treatments. The treatment of granular fertilizers with an acidic solution increases an amount of water-soluble zinc, which in turn, increases the efficiency of zinc uptake and reduces the costs and equipment otherwise needed to mitigate zinc deficiencies.

The present invention relates to a process for inhibiting, at least in part, nitrification activity of ammonium-containing fertilizers (a1) and/or of ammonium-producing fertilizers (a2), which process comprises the steps of: a) Applying to soil and/or to foliage a nitrification inhibitory amount of one or more compounds (b) that are selected from the group consisting of (b1) polysulfides and/or (b2) thiosulfates and/or (b3) hydrosulfides; b) Wherein the one or more compounds (b) are applied simultaneously with, before or after the fertilizers (a) are applied to the soil and/or to the foliage such that the compounds (b) are in direct contact with the ammonium-containing fertilizers (a1) and/or the ammonium-producing fertilizers (a2); c) Wherein the one or more nitrification inhibiting compounds (b) are applied in an amount: i. such that the ratio (w/w) of total protectable nitrogen over sulfur from compounds (b) is at most about 8:1, preferably at most about 7.5:1, more preferably at most about 7:1, and/or ii. corresponding to a soil level of S (sulfur) that is between about 50 and about 300 ppm, preferably between about 75 and about 300 ppm, more preferably between about 100 and about 250 ppm; and d) Wherein compounds (b) are different from compounds (a).

The invention relates to a sulfur coated granular fertilizer, having a polymer coating on the sulfur layer, wherein the polymer coating comprises polycaprolactone. The sulfur coated granular fertilizer may have an aliphatic polyester a polymer coating on the sulfur layer, and has the following characteristics when tested in a standardized water leach test: a. an initial release of about 20% nutrient or less in 24 h, preferably of about 15% or less; b. a release of more than 4% of the nutrient content between the days 14 and 21 from the beginning of the water leach test, preferable of about 5% or more.

The invention relates to a sulfur coated granular fertilizer, having a polymer coating on the sulfur layer, wherein the polymer coating comprises polycaprolactone. The sulfur coated granular fertilizer may have an aliphatic polyester a polymer coating on the sulfur layer, and has the following characteristics when tested in a standardized water leach test: a. an initial release of about 20% nutrient or less in 24 h, preferably of about 15% or less; b. a release of more than 4% of the nutrient content between the days 14 and 21 from the beginning of the water leach test, preferable of about 5% or more.

The present invention relates to improving the efficiency of man-made and/or natural organic-based animal manure fertilizers by administration of formulations containing poly(organic acids), [P(OA)]s, and/or their salts dispersed in a Non-aqueous Organic Solvent Delivery System (NOSDS). Utilizing a NOSDS allows for coating all components in a fertilizer formulation including but not limited to Urea, Manure, mono-ammonium phosphate (MAP), di-ammonium phosphate (DAP), solid micronutrients such as lime, zinc chloride, etc.) with a layer of [P(OA)]s and/or their salts that liberates, in a plant available form, the micronutrient metals and macronutrients, that are bound as insoluble salts and complexes in the soil. The carboxylic groups of a [P(OA)] that can exist within the [P(OA)] as carboxylic acids, carboxylic anhydrides and/or carboxylic imides, dispersed within the NOSDS, can be neutralized with one or more metals in the form of elemental metals, metal oxides, metal hydroxides, metal alkylates and metal carbonates and/or nitrogen containing compounds such as ammonia, ammonium hydroxide or organoamines to form a stable dispersion that can contain completely complexed micronutrients and provide the vehicle for the delivery of these nutrients to soils and/or as a coating to the surfaces fertilizer granules and seeds.