Disclosed is a hybrid catalyst system for the production of hydrogen/carbon monoxide syngas. The hybrid catalyst system includes a dye, a rhenium (Re) catalyst, and a cobalt (Co) catalyst grafted on a semiconductor metal oxide. The hybrid catalyst system can produce syngas without the aid of external energy and enables control over the ratio of hydrogen/carbon monoxide formed. Therefore, the hybrid catalyst system can find application in various industrial fields, including chemical fuel production.

A hydrocarbon generation system that combines a solid oxide electrolysis cell (SOEC) and a Fischer-Tropsch unit in a single microtubular reactor is described. This system can directly synthesize hydrocarbons from carbon dioxide and water. High temperature co-electrolysis of H.sub.2O and CO.sub.2 and low temperature Fischer-Tropsch (F-T) process are integrated in a single microtubular reactor by designation of a temperature gradient along the axial length of the microtubular reactor. The microtubular reactor can provide direct conversion of CO.sub.2 to hydrocarbons for use as feedstock or energy storage.

Systems, apparatuses and methods of utilizing a Fischer-Tropsch (FT) tail gas purge stream for recycling are disclosed. One or more methods include removing an FT tail gas purge stream from an FT tail gas produced by an FT reactor, treating the FT tail gas purge stream with steam in a water gas shift (WGS) reactor, having a WGS catalyst, to produce a shifted FT purge stream including carbon dioxide and hydrogen, and removing at least a portion of the carbon dioxide from the shifted FT purge stream, producing a carbon dioxide stream and a treated purge stream. Other embodiments are also disclosed.

Systems, apparatuses and methods of utilizing a Fischer-Tropsch (FT) tail gas purge stream for recycling are disclosed. One or more methods include removing an FT tail gas purge stream from an FT tail gas produced by an FT reactor, treating the FT tail gas purge stream with steam in a water gas shift (WGS) reactor, having a WGS catalyst, to produce a shifted FT purge stream including carbon dioxide and hydrogen, and removing at least a portion of the carbon dioxide from the shifted FT purge stream, producing a carbon dioxide stream and a treated purge stream. Other embodiments are also disclosed.

The invention relates to a method for operating a multi-component system for producing hydrocarbon products by means of regeneratively produced energy, wherein an inert gas is introduced into at least a first component of the system and wherein a process-internal gas is used as the inert gas.

The invention relates to a method for operating a multi-component system for producing hydrocarbon products by means of regeneratively produced energy, wherein an inert gas is introduced into at least a first component of the system and wherein a process-internal gas is used as the inert gas.

The present invention relate to a methane synthesis catalyst preparation method, comprising a preparation step for a catalytic body and a prereduction step. The prereduction step comprises: calcining the catalytic body to form a nickel aluminate spinel-containing catalyst precursor; and prereducing the catalyst precursor to acquire the methane synthesis catalyst. The catalyst prepared in the preparation method can be used in high-temperature and high liquid-to-gas ratio conditions, shows performance stability, and obviates the need for a further step of high-temperature reduction during vehicle operation. Also provided is the methane synthesis catalyst precursor. The catalyst precursor contains nickel aluminate spinel.

The present invention relate to a methane synthesis catalyst preparation method, comprising a preparation step for a catalytic body and a prereduction step. The prereduction step comprises: calcining the catalytic body to form a nickel aluminate spinel-containing catalyst precursor; and prereducing the catalyst precursor to acquire the methane synthesis catalyst. The catalyst prepared in the preparation method can be used in high-temperature and high liquid-to-gas ratio conditions, shows performance stability, and obviates the need for a further step of high-temperature reduction during vehicle operation. Also provided is the methane synthesis catalyst precursor. The catalyst precursor contains nickel aluminate spinel.

The present invention relate to a methane synthesis catalyst preparation method, comprising a preparation step for a catalytic body and a prereduction step. The prereduction step comprises: calcining the catalytic body to form a nickel aluminate spinel-containing catalyst precursor; and prereducing the catalyst precursor to acquire the methane synthesis catalyst. The catalyst prepared in the preparation method can be used in high-temperature and high liquid-to-gas ratio conditions, shows performance stability, and obviates the need for a further step of high-temperature reduction during vehicle operation. Also provided is the methane synthesis catalyst precursor. The catalyst precursor contains nickel aluminate spinel.

The present disclosure relates in a broad form to a pseudo-isothermal flow reactor (100) for an exothermal reaction comprising at least two reaction enclosures (108, 114) and a cooling medium enclosure (102) configured to hold a cooling medium under pressure at the boiling point of said cooling medium, said reaction enclosures (108, 114) having an outer surface configured to be in thermal contact with the cooling medium, and each of said reaction enclosures (108, 114) having an inlet and an outlet with the associated benefit of enabling a two-stage pseudo-isothermal operation while only requiring a single cooling medium enclosure (102) and only single cooling medium circuit.