C07C1/22

Method for Depolymerising Oxygenated Polymer Materials

The present invention concerns a method for depolymerizing oxygenated polymer materials and the use of said method in the recycling of plastic materials and the preparation of aromatic compounds that can be used as fuel, synthesis intermediates and raw materials in the construction sectors and in the petrochemical, electrical, electronic, textile, aeronautical, pharmaceutical, cosmetics and agrochemical industries. The present invention also concerns the use of aromatic compounds obtained by the method for depolymerizing oxygenated polymer materials according to the invention, in the production of fuels, electronic components, plastic polymers, rubber, drugs, vitamins, cosmetic products, perfumes, food products, synthetic threads and fibres, synthetic leathers, glues, pesticides and fertilizers.

Method for Depolymerising Oxygenated Polymer Materials

The present invention concerns a method for depolymerizing oxygenated polymer materials and the use of said method in the recycling of plastic materials and the preparation of aromatic compounds that can be used as fuel, synthesis intermediates and raw materials in the construction sectors and in the petrochemical, electrical, electronic, textile, aeronautical, pharmaceutical, cosmetics and agrochemical industries. The present invention also concerns the use of aromatic compounds obtained by the method for depolymerizing oxygenated polymer materials according to the invention, in the production of fuels, electronic components, plastic polymers, rubber, drugs, vitamins, cosmetic products, perfumes, food products, synthetic threads and fibres, synthetic leathers, glues, pesticides and fertilizers.

Method for producing bio-aromatics from glycerol

Provided is a method for producing bio-aromatic compounds from glycerol. The method uses a primary alcohol, secondary alcohol or a combination thereof as a mixing medium in converting glycerol into an aromatic compound, and thus overcomes the high viscosity of glycerol and improves the problem of rapid catalytic deactivation, thereby increasing the yield of aromatic compounds and improving the stability of catalyst. In addition, the method for producing bio-aromatic compounds uses a zeolite-based catalyst that is a kind of solid acid catalysts, and suggests optimum reaction conditions, and thus imparts a high added value to glycerol produced as a byproduct in a biodiesel production process and increases the cost-efficiency of process.

Solar-enriched biofuels via looped oxide catalysis

The invention is an integrated thermochemical process, also known as a looped-oxide catalysis, for providing an upgraded biofuel composition from a biomass-derived feedstock. First, the feedstock is deoxygenated through reaction with a low-valence metal oxide or zero-valent metal to yield a deoxygenated biofuel composition and a high-valence metal oxide. Second, the low-valence metal oxide is regenerated by reducing the high-valence metal oxide using solar thermal energy.

Solar-enriched biofuels via looped oxide catalysis

The invention is an integrated thermochemical process, also known as a looped-oxide catalysis, for providing an upgraded biofuel composition from a biomass-derived feedstock. First, the feedstock is deoxygenated through reaction with a low-valence metal oxide or zero-valent metal to yield a deoxygenated biofuel composition and a high-valence metal oxide. Second, the low-valence metal oxide is regenerated by reducing the high-valence metal oxide using solar thermal energy.

FUELS AND METHODS OF MAKING THE SAME

The present disclosure relates to a method that includes a first treating of a first mixture that includes a carboxylic acid having between 2 and 12 carbon atoms, inclusively, to form a second mixture that includes a ketone having between 2 and 25 carbon atoms, inclusively, and a second treating of at least a first portion of the second mixture to form a first product that includes a paraffin having 8 or more carbon atoms.

FUELS AND METHODS OF MAKING THE SAME

The present disclosure relates to a method that includes a first treating of a first mixture that includes a carboxylic acid having between 2 and 12 carbon atoms, inclusively, to form a second mixture that includes a ketone having between 2 and 25 carbon atoms, inclusively, and a second treating of at least a first portion of the second mixture to form a first product that includes a paraffin having 8 or more carbon atoms.

A MILD CATALYTIC REDUCTION OF C-O BONDS AND C=O BONDS USING A RECYCLABLE CATALYST SYSTEM

A method of reducing a C—O bond to the corresponding C—H bond in a substrate, which could be a benzylic alcohol, allylic alcohol, ester or an ether bond beta to a hydroxyl group or alpha to a carbonyl group using a recyclable metal catalyst system. The recyclable catalyst system is also applicable to reducing a C═O bond to the corresponding C—OH bond and then C—H bond. These methodologies can be linked in one-pot to selective oxidation and depolymerizations of aromatic polyols such as lignin.

A MILD CATALYTIC REDUCTION OF C-O BONDS AND C=O BONDS USING A RECYCLABLE CATALYST SYSTEM

A method of reducing a C—O bond to the corresponding C—H bond in a substrate, which could be a benzylic alcohol, allylic alcohol, ester or an ether bond beta to a hydroxyl group or alpha to a carbonyl group using a recyclable metal catalyst system. The recyclable catalyst system is also applicable to reducing a C═O bond to the corresponding C—OH bond and then C—H bond. These methodologies can be linked in one-pot to selective oxidation and depolymerizations of aromatic polyols such as lignin.

A MILD CATALYTIC REDUCTION OF C-O BONDS AND C=O BONDS USING A RECYCLABLE CATALYST SYSTEM

A method of reducing a C—O bond to the corresponding C—H bond in a substrate, which could be a benzylic alcohol, allylic alcohol, ester or an ether bond beta to a hydroxyl group or alpha to a carbonyl group using a recyclable metal catalyst system. The recyclable catalyst system is also applicable to reducing a C═O bond to the corresponding C—OH bond and then C—H bond. These methodologies can be linked in one-pot to selective oxidation and depolymerizations of aromatic polyols such as lignin.