The invention provides a process for the preparation of an olefinic product, the comprising: (a) reacting an oxygenate to produce an effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature at or lower than the dew point temperature of the reaction effluent stream by direct injection of a first aqueous liquid into the effluent stream, to form a quench effluent stream; (d) separating the first quench effluent stream into a liquid quench stream and a gaseous quench stream; and passing the gaseous quench stream into a quench tower and contacting the gaseous quench stream with a second aqueous liquid, to produce a quench tower gaseous stream comprising the olefinic product.

The invention provides a process for the preparation of an olefinic product, the comprising: (a) reacting an oxygenate to produce an effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the effluent stream by means of an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature at or lower than the dew point temperature of the reaction effluent stream by direct injection of a first aqueous liquid into the effluent stream, to form a quench effluent stream; (d) separating the first quench effluent stream into a liquid quench stream and a gaseous quench stream; and passing the gaseous quench stream into a quench tower and contacting the gaseous quench stream with a second aqueous liquid, to produce a quench tower gaseous stream comprising the olefinic product.

The present invention concerns a method (100) for the production of a propylene product (9) in which a component mixture (2) containing propane, propylene and hydrogen is provided using a propane dehydrogenation (10) to which a reaction feed (1) containing propane and hydrogen is subjected, the component mixture (2) or a part thereof being subjected as a first separation feed to a first membrane separation (40), by means of which a first permeate (3) enriched in hydrogen with respect to the first separation feed and a first retentate (4) depleted in hydrogen with respect to the first separation feed and containing hydrogen, propane and propylene are formed, the first retentate (4) or part thereof being subjected to a second membrane separation (50) as a second separation feed, in which a second permeate (6) containing at least the predominant part of the hydrogen of the second separation feed and a second retentate containing at least the predominant part of the propane and the propylene of the second separation feed are formed, wherein the first membrane separation (40) is carried out using a sweep gas (5) containing propane and the first permeate (3) is obtained as a permeate (3) charged with propane of the sweep gas (5) and/or the second membrane separation (50) is carried out using the sweep gas (5) containing propane and the second permeate (6) is obtained as a permeate (6) charged with propane of the sweep gas (5), and wherein the first permeate (3) charged with propane of the sweep gas (5) and/or the second permeate (3) charged with propane of the sweep gas or one or more parts thereof is used in the formation of the reaction feed (1). A corresponding plant is also the subject of this invention.

The present invention concerns a method (100) for the production of a propylene product (9) in which a component mixture (2) containing propane, propylene and hydrogen is provided using a propane dehydrogenation (10) to which a reaction feed (1) containing propane and hydrogen is subjected, the component mixture (2) or a part thereof being subjected as a first separation feed to a first membrane separation (40), by means of which a first permeate (3) enriched in hydrogen with respect to the first separation feed and a first retentate (4) depleted in hydrogen with respect to the first separation feed and containing hydrogen, propane and propylene are formed, the first retentate (4) or part thereof being subjected to a second membrane separation (50) as a second separation feed, in which a second permeate (6) containing at least the predominant part of the hydrogen of the second separation feed and a second retentate containing at least the predominant part of the propane and the propylene of the second separation feed are formed, wherein the first membrane separation (40) is carried out using a sweep gas (5) containing propane and the first permeate (3) is obtained as a permeate (3) charged with propane of the sweep gas (5) and/or the second membrane separation (50) is carried out using the sweep gas (5) containing propane and the second permeate (6) is obtained as a permeate (6) charged with propane of the sweep gas (5), and wherein the first permeate (3) charged with propane of the sweep gas (5) and/or the second permeate (3) charged with propane of the sweep gas or one or more parts thereof is used in the formation of the reaction feed (1). A corresponding plant is also the subject of this invention.

The invention provides a process for preparing an olefin, comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature lower than the dew point temperature of the effluent stream by direct injection of an aqueous liquid into the effluent stream, to form a quench effluent stream; and (d) passing the quench effluent stream into a quench tower and contacting the quench effluent stream with a second aqueous liquid in the presence of at least one set of internals, to produce a quench tower gaseous stream comprising the olefin.

The invention provides a process for preparing an olefin, comprising: (a) reacting an oxygenate, in a reaction zone in the presence of a molecular sieve catalyst, at a temperature from 350 to 1000° C., to produce a effluent stream, comprising at least oxygenate, olefin, water and acidic by-products; (b) cooling the reaction effluent stream by an indirect heat exchange to a temperature greater than the dew point temperature of effluent stream; (c) further rapidly cooling the effluent stream to a temperature lower than the dew point temperature of the effluent stream by direct injection of an aqueous liquid into the effluent stream, to form a quench effluent stream; and (d) passing the quench effluent stream into a quench tower and contacting the quench effluent stream with a second aqueous liquid in the presence of at least one set of internals, to produce a quench tower gaseous stream comprising the olefin.

A burner assembly for and method of producing ethylene having a mechanism to inject either primary fuel, staged fuel, or both by premix methods before combustion in a furnace. The burner assembly has at least one premix injection assembly for either exclusively primary fuel or exclusively staged fuel injection paired with a nozzle mix injection or injection means for primary and staged fuel both by premix methods. The primary fuel premix assembly associates with a burner tile that consists of multiple inlets and outlets connected by venturi channels to direct and combine combustion air and staged fuel coming from staged fuel orifice spuds. Primary fuel and combustion air are mixed in a premix assembly and directed inside the furnace, and above the burner tile to complete the reaction with the staged fuel and combustion air mixture in a combustion zone inside of the furnace.

A burner assembly for and method of producing ethylene having a mechanism to inject either primary fuel, staged fuel, or both by premix methods before combustion in a furnace. The burner assembly has at least one premix injection assembly for either exclusively primary fuel or exclusively staged fuel injection paired with a nozzle mix injection or injection means for primary and staged fuel both by premix methods. The primary fuel premix assembly associates with a burner tile that consists of multiple inlets and outlets connected by venturi channels to direct and combine combustion air and staged fuel coming from staged fuel orifice spuds. Primary fuel and combustion air are mixed in a premix assembly and directed inside the furnace, and above the burner tile to complete the reaction with the staged fuel and combustion air mixture in a combustion zone inside of the furnace.

A process to convert paraffinic feedstocks into renewable poly-alpha-olefins (PAO) basestocks. In a preferred embodiment of the invention, renewable feed comprising triglycerides and/or free fatty acids are hydrotreated producing an intermediate paraffin feedstock. This paraffin feedstock is thermally cracked into a mixture of olefins and paraffins comprising linear alpha olefins. The olefins are separated and the un-reacted paraffins are recycled to the thermal cracker. Light olefins preferably (C2-C6) are oligomerized with a surface deactivated zeolite producing a mixture of slightly branched oligomers comprising internal olefins. The heavier olefins (C6-C16) are oligomerized, preferably with a BF3 catalyst and co-catalyst to produce PAO products. The oligomerized products can be hydrotreated and distilled together or separate to produce finished products that include naphtha, distillate, solvents, and PAO lube basestocks.

Embodiments for an integrated hydrotreating and steam pyrolysis process for the processing of crude oil comprising recycling the higher boiling point fraction of the upgraded crude oil to increase the yield of petrochemicals such as olefins and aromatics.