Patent classifications
C07C5/10
CATALYST COMPRISING AN ACTIVE NICKEL PHASE IN THE FORM OF SMALL PARTICLES AND A NICKEL-COPPER ALLOY
Catalyst comprising nickel and copper, in a proportion of 1% to 50% by weight of nickel element relative to the total weight of the catalyst, in a proportion of 0.5% to 15% by weight of copper element relative to the total weight of the catalyst, and an alumina support, said catalyst being characterized in that: the mole ratio between nickel and copper is between 0.5 and 5 mol/mol; at least one portion of the nickel and copper is in the form of a nickel-copper alloy; the nickel content in the nickel-copper alloy is between 0.5% and 15% by weight of nickel element relative to the total weight of the catalyst, the size of the nickel particles in the catalyst is less than 7 nm.
CATALYST COMPRISING AN ACTIVE NICKEL PHASE DISTRIBUTED IN A SHELL
Catalyst comprising a nickel-based active phase and an alumina support, characterized in that: the nickel is distributed both on a crust at the periphery of the support, and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; the nickel density ratio between the crust and the core is strictly greater than 3; said crust comprises between 40% and 80% by weight of nickel element relative to the total weight of nickel contained in the catalyst.
CATALYST COMPRISING AN ACTIVE NICKEL PHASE DISTRIBUTED IN A SHELL
Catalyst comprising a nickel-based active phase and an alumina support, characterized in that: the nickel is distributed both on a crust at the periphery of the support, and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; the nickel density ratio between the crust and the core is strictly greater than 3; said crust comprises between 40% and 80% by weight of nickel element relative to the total weight of nickel contained in the catalyst.
CATALYST COMPRISING AN ACTIVE NICKEL PHASE DISTRIBUTED IN A SHELL
Catalyst comprising a nickel-based active phase and an alumina support, characterized in that: the nickel is distributed both on a crust at the periphery of the support, and in the core of the support, the thickness of said crust being between 2% and 15% of the diameter of the catalyst; the nickel density ratio between the crust and the core is strictly greater than 3; said crust comprises between 40% and 80% by weight of nickel element relative to the total weight of nickel contained in the catalyst.
PROCESS FOR PREPARING A CATALYST FOR THE HYDROGENATION OF AROMATICS, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a catalyst for the hydrogenation of aromatic or polyaromatic compounds comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING A CATALYST FOR THE HYDROGENATION OF AROMATICS, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a catalyst for the hydrogenation of aromatic or polyaromatic compounds comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING A CATALYST FOR THE HYDROGENATION OF AROMATICS, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a catalyst for the hydrogenation of aromatic or polyaromatic compounds comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING SELECTIVE HYDROGENATION CATALYST, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a selective hydrogenation catalyst comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING SELECTIVE HYDROGENATION CATALYST, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a selective hydrogenation catalyst comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.
PROCESS FOR PREPARING SELECTIVE HYDROGENATION CATALYST, COMPRISING A STEP OF FORMING A NI-CU ALLOY IN PRE-IMPREGNATION
A process for preparing a selective hydrogenation catalyst comprising nickel, copper and a support comprising at least one refractory oxide, comprising the following steps: bringing the support into contact with a solution containing at least one copper precursor and one nickel precursor; drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.; bringing the catalyst precursor into contact with a solution comprising a nickel precursor; a step of drying the catalyst precursor at a temperature of less than 250° C.; reducing the catalyst precursor by bringing said precursor into contact with a reducing gas at a temperature of between 150° C. and 250° C.