Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, including cyclopentadiene, and catalyst compositions for use in such process. The process comprises contacting the feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprises a microporous crystalline metallosilicate, a Group 10 metal or compound thereof, and a Group 11 metal or compound thereof.

Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, including cyclopentadiene, and catalyst compositions for use in such process. The process comprises contacting the feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprises a microporous crystalline metallosilicate, a Group 10 metal or compound thereof, and a Group 11 metal or compound thereof.

Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor to obtain a product mixture, separating the product mixture in a separation sub-system such as compression train to obtain a C5-rich fraction comprising CPD and essentially depleted of hydrogen and C1-C4 hydrocarbons, dimerizing the C5-rich fraction in a dimerization reactor to obtain a product effluent comprising DCPD, followed by separating the product effluent to obtain a DCPD-rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.

Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor to obtain a product mixture, separating the product mixture in a separation sub-system such as compression train to obtain a C5-rich fraction comprising CPD and essentially depleted of hydrogen and C1-C4 hydrocarbons, dimerizing the C5-rich fraction in a dimerization reactor to obtain a product effluent comprising DCPD, followed by separating the product effluent to obtain a DCPD-rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.

Processes and systems for making cyclopentadiene and/or dicyclopentadiene include converting acyclic C5 hydrocarbon(s) into CPD in a first reactor to obtain a product mixture, separating the product mixture in a separation sub-system such as compression train to obtain a C5-rich fraction comprising CPD and essentially depleted of hydrogen and C1-C4 hydrocarbons, dimerizing the C5-rich fraction in a dimerization reactor to obtain a product effluent comprising DCPD, followed by separating the product effluent to obtain a DCPD-rich fraction. Multiple-stage of dimerization and separation steps can be optionally used to obtain multiple DCPD-rich fractions of various degrees of purity and quantity. C5-rich fractions from various stages of the process may be recycled to the first reactor, or converted into mogas components after selective hydrogenation. C5-rich fractions and mogas components may be optionally separated to produce value-adding chemicals.

A hydrogen generation system including: a reformer generating hydrogen-containing gas using a raw material and reforming water; a combustor combusting hydrogen-containing gas and air and generating exhaust gas; a first channel passing cooling water; a condenser generating condensed water by heat exchange between exhaust gas and cooling water; a tank storing condensed water as cooling water; a pump supplying cooling water from the tank to the condenser; a second channel branching at a branch between the pump and condenser in the first channel, and passing some cooling water to the reformer as reforming water; a heater provided downstream of the branch, and heating the first channel; a temperature detector detecting the temperature of the first channel; and a controller, in an activation operation mode, determining whether the second channel is filled with reforming water, based on the temperature detected by the temperature detector after the heater has operated.

A hydrogen generation system including: a reformer generating hydrogen-containing gas using a raw material and reforming water; a combustor combusting hydrogen-containing gas and air and generating exhaust gas; a first channel passing cooling water; a condenser generating condensed water by heat exchange between exhaust gas and cooling water; a tank storing condensed water as cooling water; a pump supplying cooling water from the tank to the condenser; a second channel branching at a branch between the pump and condenser in the first channel, and passing some cooling water to the reformer as reforming water; a heater provided downstream of the branch, and heating the first channel; a temperature detector detecting the temperature of the first channel; and a controller, in an activation operation mode, determining whether the second channel is filled with reforming water, based on the temperature detected by the temperature detector after the heater has operated.

A process for aromatizing hydrocarbons comprises: converting at least a portion of highly branched hydrocarbons in a feed stream into selectively convertible components, and aromatizing the selectively convertible components to produce an aromatization reactor effluent. The aromatization reactor effluent comprises an aromatic product. Converting at least the portion of the highly branched hydrocarbons into the selectively convertible components may include contacting the feed stream with an isomerization catalyst in an isomerization reaction system under isomerization reaction conditions; and isomerizing the portion of the highly branched hydrocarbons in the feed stream into the selectively convertible components.

A process for aromatizing hydrocarbons comprises: converting at least a portion of highly branched hydrocarbons in a feed stream into selectively convertible components, and aromatizing the selectively convertible components to produce an aromatization reactor effluent. The aromatization reactor effluent comprises an aromatic product. Converting at least the portion of the highly branched hydrocarbons into the selectively convertible components may include contacting the feed stream with an isomerization catalyst in an isomerization reaction system under isomerization reaction conditions; and isomerizing the portion of the highly branched hydrocarbons in the feed stream into the selectively convertible components.

Venturi-type scrubbers may be utilized in conjunction with removing solids from and quenching a gas-phase reaction product. Methods may comprise: providing a reaction product comprising a hydrocarbon gas and solids; introducing the reaction product into a Venturi-type scrubber; introducing a scrubbing fluid into the Venturi-type scrubber, wherein the scrubbing fluid is at a lower temperature than the reaction product; producing from the Venturi-type scrubber a multi-phase product comprising a scrubbed reaction product and a spent scrubbing fluid, the scrubbed reaction product comprising the hydrocarbon gas and the spent scrubbing fluid comprising the scrubbing fluid and the solids; and separating the hydrocarbon gas from the multi-phase fluid. Systems may comprise a reactor; a Venturi-type scrubber having a first inlet fluidly connected to the reactor and a second inlet configured to receive a scrubbing fluid; and a separation tower configured to receive a multi-phase stream from the Venturi-type scrubber after solids removal.