C07C7/14875

COS and CS.SUB.2 .abatement method

Disclosed is method for removing carbonyl sulphide and/or carbon disulphide from a sour gas stream. The method comprises subjecting the gas stream to simultaneous contact with an absorption liquid, such as an aqueous amine solution, and with a catalyst suitable for hydrolyzing carbonyl sulphide and/or carbon disulphide. To this end, the invention also provides a reactor system wherein both an absorption liquid and a catalyst are present. In a preferred embodiment, the catalyst is a heterogeneous catalyst present on or in an absorption column, either coated on the trays of a column with trays, or contained in the packing of a packed column.

METHODS OF REMOVING CARBONYL-CONTAINING ORGANIC COMPOUNDS

Provided are methods of treating a mixture, such as a hydrocarbon mixture, that includes one or more C2-C4 carbonyl containing organic compounds. The methods may include contacting a hydrocarbon mixture with an aqueous liquid including an agent. The agent may reduce the amount of one or more C2-C4 carbonyl containing organic compounds in the mixture.

METHODS OF REMOVING CARBONYL-CONTAINING ORGANIC COMPOUNDS

Provided are methods of treating a mixture, such as a hydrocarbon mixture, that includes one or more C2-C4 carbonyl containing organic compounds. The methods may include contacting a hydrocarbon mixture with an aqueous liquid including an agent. The agent may reduce the amount of one or more C2-C4 carbonyl containing organic compounds in the mixture.

Removal of aromatic impurities from an alkene stream using an acid catalyst, such as an acidic ionic liquid

A process for the preparation of a chemical composition comprising an aromatic compound in a concentration B by weight, based on the total weight of the chemical composition, comprising: a. providing the following reaction components: i. a chemical composition comprising the following: a) The aromatic compound in a concentration A by weight based on the total weight of the chemical composition, and b) An olefin in an amount in an amount of about 50 to about 99.99 wt. %, based on the total weight of the chemical composition, and ii. An acid; and b. reacting the components to obtain the chemical composition comprising the aromatic compound in a concentration B by weight based on the total weight of the chemical composition; wherein the concentration B is less than the concentration A.

Removal of aromatic impurities from an alkene stream using an acid catalyst, such as an acidic ionic liquid

A process for the preparation of a chemical composition comprising an aromatic compound in a concentration B by weight, based on the total weight of the chemical composition, comprising: a. providing the following reaction components: i. a chemical composition comprising the following: a) The aromatic compound in a concentration A by weight based on the total weight of the chemical composition, and b) An olefin in an amount in an amount of about 50 to about 99.99 wt. %, based on the total weight of the chemical composition, and ii. An acid; and b. reacting the components to obtain the chemical composition comprising the aromatic compound in a concentration B by weight based on the total weight of the chemical composition; wherein the concentration B is less than the concentration A.

METHODS FOR MAKING LINEAR INTERNAL OLEFINS FROM MIXTURES OF LINEAR AND BRANCHED OLEFINS
20240051900 · 2024-02-15 ·

Processes for producing a linear internal olefin product include the steps of contacting an olefin feed containing C.sub.10-C.sub.20 vinylidenes and a C.sub.10-C.sub.20 normal alpha olefin and/or C.sub.10-C.sub.20 linear internal olefins, a first acid catalyst, and a C.sub.1 to C.sub.18 carboxylic acid to form a first reaction product containing linear internal olefins, trisubstituted olefins, and secondary esters, then removing all or a portion of the secondary esters from the first reaction product, followed by contacting the secondary esters and a second acid catalyst to form a second reaction product comprising linear internal olefins, and then removing all or a portion of the linear internal olefins from the second reaction product to form the linear internal olefin product. Linear alkanes subsequently can be produced by hydrogenating the linear internal olefin product to form a linear alkane product.

METHODS FOR MAKING LINEAR INTERNAL OLEFINS FROM MIXTURES OF LINEAR AND BRANCHED OLEFINS
20240051900 · 2024-02-15 ·

Processes for producing a linear internal olefin product include the steps of contacting an olefin feed containing C.sub.10-C.sub.20 vinylidenes and a C.sub.10-C.sub.20 normal alpha olefin and/or C.sub.10-C.sub.20 linear internal olefins, a first acid catalyst, and a C.sub.1 to C.sub.18 carboxylic acid to form a first reaction product containing linear internal olefins, trisubstituted olefins, and secondary esters, then removing all or a portion of the secondary esters from the first reaction product, followed by contacting the secondary esters and a second acid catalyst to form a second reaction product comprising linear internal olefins, and then removing all or a portion of the linear internal olefins from the second reaction product to form the linear internal olefin product. Linear alkanes subsequently can be produced by hydrogenating the linear internal olefin product to form a linear alkane product.

Methods and systems for purifying 1,3-butadiene from a C4 hydrocarbon stream

The presently disclosed subject matter relates to methods and systems for purifying 1,3-butadiene from a C4 hydrocarbon stream. An example method includes introducing a C4 hydrocarbon stream including 1,3-butadiene and acetlyenes to an organic azide in the presence of a catalyst to generate a first stream including triazole, separating triazole from the first stream to produce a second stream including 1,3-butadiene, and distilling 1,3-butadiene from the second stream to produce a purified 1,3-butadiene product stream.

Methods and systems for purifying 1,3-butadiene from a C4 hydrocarbon stream

The presently disclosed subject matter relates to methods and systems for purifying 1,3-butadiene from a C4 hydrocarbon stream. An example method includes introducing a C4 hydrocarbon stream including 1,3-butadiene and acetlyenes to an organic azide in the presence of a catalyst to generate a first stream including triazole, separating triazole from the first stream to produce a second stream including 1,3-butadiene, and distilling 1,3-butadiene from the second stream to produce a purified 1,3-butadiene product stream.

METHODS AND SYSTEMS FOR PURIFYING 1,3-BUTADIENE FROM A C4 HYDROCARBON STREAM

The presently disclosed subject matter relates to methods and systems for purifying 1,3-butadiene from a C.sub.4 hydrocarbon stream. An example method includes introducing a C.sub.4 hydrocarbon stream including 1,3-butadiene and acetylenes to an organic azide in the presence of a catalyst to generate a first stream including triazole, separating triazole from the first stream to produce a second stream including 1,3-butadiene, and distilling 1,3-butadiene from the second stream to produce a purified 1,3-butadiene product stream.