Patent classifications
C07C7/152
GENERATORS FOR 1-METHYLCYCLOPROPENE RELEASE FROM CARRIER COMPLEX
Providing a method for generating and releasing 1-MCP gas from a complex carrier through the use of a 1-MCP generator that enables the application of at least one physical, releasing force to a carrier complex and/or mixture comprising water and the carrier complex, or the interaction of steam with a carrier complex and/or mixture comprising water and the carrier complex, over a determined period of time.
GENERATORS FOR 1-METHYLCYCLOPROPENE RELEASE FROM CARRIER COMPLEX
Providing a method for generating and releasing 1-MCP gas from a complex carrier through the use of a 1-MCP generator that enables the application of at least one physical, releasing force to a carrier complex and/or mixture comprising water and the carrier complex, or the interaction of steam with a carrier complex and/or mixture comprising water and the carrier complex, over a determined period of time.
Separations with ionic liquid solvents
Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
Separations with ionic liquid solvents
Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
Separations with ionic liquid solvents
Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.
SELECTIVE ADSORPTION OF GASEOUS ALKENES INTO NON-POROUS COPPER(I) COMPLEXES: CONTROLLING HEAT OF ADSORPTION AND LOADING PRESSURE
Disclosed are air-stable small-molecule adsorbents trimeric [Cu—Br].sub.3 and [Cu—H].sub.3 that undergo a reversible solid-state molecular rearrangements to [Cu—Br.(alkene)].sub.2 and [Cu—H.(alkene)].sub.2 dimers. The reversible solid-state rearrangement allows one to break adsorbent design trade-offs and achieve low heat of adsorption while retaining high selectivity and uptake.
SELECTIVE ADSORPTION OF GASEOUS ALKENES INTO NON-POROUS COPPER(I) COMPLEXES: CONTROLLING HEAT OF ADSORPTION AND LOADING PRESSURE
Disclosed are air-stable small-molecule adsorbents trimeric [Cu—Br].sub.3 and [Cu—H].sub.3 that undergo a reversible solid-state molecular rearrangements to [Cu—Br.(alkene)].sub.2 and [Cu—H.(alkene)].sub.2 dimers. The reversible solid-state rearrangement allows one to break adsorbent design trade-offs and achieve low heat of adsorption while retaining high selectivity and uptake.
Advanced oxidative coupling of methane
The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C.sub.2+), comprising introducing methane and an oxidant (e.g., O.sub.2) into an oxidative coupling of methane (OCM) reactor that has been retrofitted into a system comprising an ethylene-to-liquids (ETL) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C.sub.2+ compounds. The first product stream can then be directed to a pressure swing adsorption (PSA) unit that recovers at least a portion of the C.sub.2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C.sub.2+ compounds. The second product stream can then be directed to the ETL reactor. The higher hydrocarbon(s) can then be generated from the at least the portion of the C.sub.2+ compounds in the ETL reactor.
Advanced oxidative coupling of methane
The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C.sub.2+), comprising introducing methane and an oxidant (e.g., O.sub.2) into an oxidative coupling of methane (OCM) reactor that has been retrofitted into a system comprising an ethylene-to-liquids (ETL) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C.sub.2+ compounds. The first product stream can then be directed to a pressure swing adsorption (PSA) unit that recovers at least a portion of the C.sub.2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C.sub.2+ compounds. The second product stream can then be directed to the ETL reactor. The higher hydrocarbon(s) can then be generated from the at least the portion of the C.sub.2+ compounds in the ETL reactor.
Advanced oxidative coupling of methane
The present disclosure provides a method for generating higher hydrocarbon(s) from a stream comprising compounds with two or more carbon atoms (C.sub.2+), comprising introducing methane and an oxidant (e.g., O.sub.2) into an oxidative coupling of methane (OCM) reactor that has been retrofitted into a system comprising an ethylene-to-liquids (ETL) reactor. The OCM reactor reacts the methane with the oxidant to generate a first product stream comprising the C.sub.2+ compounds. The first product stream can then be directed to a pressure swing adsorption (PSA) unit that recovers at least a portion of the C.sub.2+ compounds from the first product stream to yield a second product stream comprising the at least the portion of the C.sub.2+ compounds. The second product stream can then be directed to the ETL reactor. The higher hydrocarbon(s) can then be generated from the at least the portion of the C.sub.2+ compounds in the ETL reactor.