Processes for converting C8 aromatic hydrocarbons. In some embodiments, the process can include feeding a gaseous hydrocarbon feed that can include meta-xylene, ortho-xylene, or both into a conversion zone. The process can also include contacting the gaseous hydrocarbon feed with a catalyst that can include a ZSM-11 zeolite in the conversion zone under conversion conditions to effect isomerization of at least a portion of any meta-xylene, or at least a portion of any ortho-xylene, or both to produce a conversion product rich in para-xylene. In some embodiments, the ZSM-11 zeolite can have an alpha value of 1 to 3,000 and a molar ratio of silica to alumina of from 15 to 200.

The invention relates to the extraction of organic compounds from mixtures of said compounds with water, using a nanoporous carbon membrane. The invention can be used in any field where it is desired to separate an organic compound of interest from water, such as the drying of alcohols or alkanes.

The invention relates to the extraction of organic compounds from mixtures of said compounds with water, using a nanoporous carbon membrane. The invention can be used in any field where it is desired to separate an organic compound of interest from water, such as the drying of alcohols or alkanes.

A photoreactor having computer actuated input/output ports is operated by introducing reactant through an input port and collecting product through an output port, and upon closure of the input and output ports, treating photocatalyst within the photoreactor to remove intermediates limiting performance of the photocatalyst. Once the photocatalyst is regenerated, introduction of reactant to the photoreactor through the input port and collection of product from the output port can be resumed. The automated process does not require removal of catalyst from the photoreactor and significantly improves process economics.

A photoreactor having computer actuated input/output ports is operated by introducing reactant through an input port and collecting product through an output port, and upon closure of the input and output ports, treating photocatalyst within the photoreactor to remove intermediates limiting performance of the photocatalyst. Once the photocatalyst is regenerated, introduction of reactant to the photoreactor through the input port and collection of product from the output port can be resumed. The automated process does not require removal of catalyst from the photoreactor and significantly improves process economics.

A system and method for converting carbon dioxide into products by contacting the carbon dioxide with catalyst in the presence of hydrogen in a reactor.

A system and method for converting carbon dioxide into products by contacting the carbon dioxide with catalyst in the presence of hydrogen in a reactor.

A MXene support for a noble metal that forms a catalyst having active sites comprising single metal-layer nanostructures. The catalyst is stable under conditions for methane conversion to higher hydrocarbons and provides reduced coke formation. The results show a supported metal catalyst using the MXene where Pt atoms form one or more layers of atoms on the surface of the Mo.sub.2TiC.sub.2T.sub.x support after it is reduced at 750° C. The catalyst shows high selectivity for C.sub.2-hydrocarbons with reduced coke formation, which can cost effectively convert methane into other valuable products.

A MXene support for a noble metal that forms a catalyst having active sites comprising single metal-layer nanostructures. The catalyst is stable under conditions for methane conversion to higher hydrocarbons and provides reduced coke formation. The results show a supported metal catalyst using the MXene where Pt atoms form one or more layers of atoms on the surface of the Mo.sub.2TiC.sub.2T.sub.x support after it is reduced at 750° C. The catalyst shows high selectivity for C.sub.2-hydrocarbons with reduced coke formation, which can cost effectively convert methane into other valuable products.

Organosilicon Lewis acids supported on activated oxides and metal oxo complexes grafted on the organosilicon Lewis acids as heterogeneous catalysts and the related compositions, methods and systems are described. These organosilicon Lewis acids and the grafted metal oxo complexes catalyze industrially important chemical reactions including, respectively, C—F bond activation and olefin metathesis reactions such as homocoupling and polymerizations.