C07C9/08

PROPANE PRODUCTION METHOD AND PROPANE PRODUCTION APPARATUS

A propane production method includes a hydrogenation reaction step of hydrogenation-reacting crude propylene and hydrogen in a presence of a catalyst to obtain gaseous crude propane containing impurities; and an impurity removal step of removing the impurities contained in the gaseous crude propane obtained in the hydrogenation reaction step to obtain purified propane. The impurity removal step includes an adsorptive removal stage of adsorbing and removing water, ethane and propylene contained as impurities in the gaseous crude propane by adsorption treatment in which the gaseous crude propane is brought into contact with an adsorbent, and a separation removal stage of separating and removing hydrogen, oxygen, nitrogen and methane contained as impurities in the crude propane after the adsorption treatment by partial condensation or distillation of crude propane after the adsorption treatment in the adsorptive removal stage.

PROPANE PRODUCTION METHOD AND PROPANE PRODUCTION APPARATUS

A propane production method includes a hydrogenation reaction step of hydrogenation-reacting crude propylene and hydrogen in a presence of a catalyst to obtain gaseous crude propane containing impurities; and an impurity removal step of removing the impurities contained in the gaseous crude propane obtained in the hydrogenation reaction step to obtain purified propane. The impurity removal step includes an adsorptive removal stage of adsorbing and removing water, ethane and propylene contained as impurities in the gaseous crude propane by adsorption treatment in which the gaseous crude propane is brought into contact with an adsorbent, and a separation removal stage of separating and removing hydrogen, oxygen, nitrogen and methane contained as impurities in the crude propane after the adsorption treatment by partial condensation or distillation of crude propane after the adsorption treatment in the adsorptive removal stage.

PROPANE PRODUCTION METHOD AND PROPANE PRODUCTION APPARATUS

A propane production method includes a hydrogenation reaction step of hydrogenation-reacting crude propylene and hydrogen in a presence of a catalyst to obtain gaseous crude propane containing impurities; and an impurity removal step of removing the impurities contained in the gaseous crude propane obtained in the hydrogenation reaction step to obtain purified propane. The impurity removal step includes an adsorptive removal stage of adsorbing and removing water, ethane and propylene contained as impurities in the gaseous crude propane by adsorption treatment in which the gaseous crude propane is brought into contact with an adsorbent, and a separation removal stage of separating and removing hydrogen, oxygen, nitrogen and methane contained as impurities in the crude propane after the adsorption treatment by partial condensation or distillation of crude propane after the adsorption treatment in the adsorptive removal stage.

Catalyst for oxidative coupling reaction of methane, method for preparing the same, and method for oxidative coupling reaction of methane using the same

Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.

Catalyst for oxidative coupling reaction of methane, method for preparing the same, and method for oxidative coupling reaction of methane using the same

Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.

SAPO-34 molecular sieve and method for preparing the same

A SAPO-34 molecular sieve and method for preparing the same, whose chemical composition in the anhydrous state is expressed as: mSDA.(Si.sub.xAl.sub.yP.sub.z)O.sub.2, wherein m is 0.08-0.3, x is 0.01-0.60, y is 0.2-0.60, z is 0.2-0.60, and x+y+z=1. The template agent SDA is in micropores of the molecular sieve. SDA is an organic amine with the structural formula (CH.sub.3).sub.2NRN(CH.sub.3).sub.2, wherein R is a saturated straight-chain or branched-chain alkylene group with having from 2-5 carbon atoms. There is a slight Si enrichment phenomenon on the crystal surface of the molecular sieve crystal, and the ratio of the surface Si content to the bulk Si content of the crystal ranges from 1.50-1.01. Said SAPO-34 molecular sieve, after being calcined at a temperature range from 400-700° C. in air, can be used as a gas adsorbent and catalyst for an acid-catalyzed reaction or oxygenate to olefin reaction.

SAPO-34 molecular sieve and method for preparing the same

A SAPO-34 molecular sieve and method for preparing the same, whose chemical composition in the anhydrous state is expressed as: mSDA.(Si.sub.xAl.sub.yP.sub.z)O.sub.2, wherein m is 0.08-0.3, x is 0.01-0.60, y is 0.2-0.60, z is 0.2-0.60, and x+y+z=1. The template agent SDA is in micropores of the molecular sieve. SDA is an organic amine with the structural formula (CH.sub.3).sub.2NRN(CH.sub.3).sub.2, wherein R is a saturated straight-chain or branched-chain alkylene group with having from 2-5 carbon atoms. There is a slight Si enrichment phenomenon on the crystal surface of the molecular sieve crystal, and the ratio of the surface Si content to the bulk Si content of the crystal ranges from 1.50-1.01. Said SAPO-34 molecular sieve, after being calcined at a temperature range from 400-700° C. in air, can be used as a gas adsorbent and catalyst for an acid-catalyzed reaction or oxygenate to olefin reaction.

Pulsed electrolysis with reference to the open circuit voltage

Various embodiments include an electrolysis method comprising: applying a pulsed voltage or a pulsed current between an anode and a cathode; repeatedly measuring a respective current OCP at the cathode in a zero-current state relative to a reference system; and controlling the pulsed voltage or the pulsed current so a working potential of the cathode in the current-carrying state with respect to the reference system has a defined progression relative to the respective current OCP. The defined progression includes a first phase at a cathodic level and a second phase at an anodic level.

PROCESSES USING MOLECULAR SIEVE SSZ-102
20170233260 · 2017-08-17 ·

Uses are disclosed for a new crystalline molecular sieve designated SSZ-102 synthesized using an N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent. SSZ-102 has ESV framework topology.

PROCESSES USING MOLECULAR SIEVE SSZ-102
20170233260 · 2017-08-17 ·

Uses are disclosed for a new crystalline molecular sieve designated SSZ-102 synthesized using an N,N′-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent. SSZ-102 has ESV framework topology.