Pathways are disclosed for the production of liquefied petroleum gas (LPG) products comprising propane and/or butane, and in certain cases renewable products having non-petroleum derived carbon. In particular, a gaseous feed mixture comprising CO.sub.2 in combination with CH.sub.4 and/or H.sub.2 is converted by reforming and/or reverse water-gas shift (RWGS) reactions, further in combination with LPG synthesis. A preferred gaseous feed mixture comprises biogas or otherwise a mixture of CO.sub.2 and H.sub.2 that is not readily upgraded using conventional processes. Catalysts described herein have a high activity for reforming (including dry reforming) of CH.sub.4, as well as simultaneously catalyzing RWGS. These attributes improve the management of CO.sub.2 that is input to the disclosed processes, particularly in those utilizing recycle operation to increase overall CO.sub.2 conversion. Economics of small scale operations may be improved, if necessary, using an electrically heated reforming reactor in the first or initial reforming stage or RWGS stage.

Pathways are disclosed for the production of liquefied petroleum gas (LPG) products comprising propane and/or butane, and in certain cases renewable products having non-petroleum derived carbon. In particular, a gaseous feed mixture comprising CO.sub.2 in combination with CH.sub.4 and/or H.sub.2 is converted by reforming and/or reverse water-gas shift (RWGS) reactions, further in combination with LPG synthesis. A preferred gaseous feed mixture comprises biogas or otherwise a mixture of CO.sub.2 and H.sub.2 that is not readily upgraded using conventional processes. Catalysts described herein have a high activity for reforming (including dry reforming) of CH.sub.4, as well as simultaneously catalyzing RWGS. These attributes improve the management of CO.sub.2 that is input to the disclosed processes, particularly in those utilizing recycle operation to increase overall CO.sub.2 conversion. Economics of small scale operations may be improved, if necessary, using an electrically heated reforming reactor in the first or initial reforming stage or RWGS stage.

This method comprises passing a residual stream into a flash drum to form a gaseous overhead flow and liquid bottom flow, and feeding the bottom flow into a distillation column, It comprises cooling the overhead flow in a heat exchanger to form a cooled overhead flow. It comprises the extraction of a gaseous overhead stream at the head of the distillation column, and the formation of at least one effluent stream from the overhead stream and/or from the top stream. The separation of the cooled overhead flow comprises passing the cooled overhead flow into an absorber, and injecting a methane-rich stream into the absorber to place the cooled overhead flow in contact with the methane-rich stream.

This method comprises passing a residual stream into a flash drum to form a gaseous overhead flow and liquid bottom flow, and feeding the bottom flow into a distillation column, It comprises cooling the overhead flow in a heat exchanger to form a cooled overhead flow. It comprises the extraction of a gaseous overhead stream at the head of the distillation column, and the formation of at least one effluent stream from the overhead stream and/or from the top stream. The separation of the cooled overhead flow comprises passing the cooled overhead flow into an absorber, and injecting a methane-rich stream into the absorber to place the cooled overhead flow in contact with the methane-rich stream.

An extractive distillation column system contains a combination column and a side rectification column. A process can be used for separation of butenes from C4-hydrocarbon streams using the extractive distillation column system.

An extractive distillation column system contains a combination column and a side rectification column. A process can be used for separation of butenes from C4-hydrocarbon streams using the extractive distillation column system.

A device and a process to propagate molecular growth of hydrocarbons, either straight or branched chain structures, that naturally occur in the gas phase of a first gas to gas phase molecules of a second gas having higher molecular chain lengths than the hydrocarbons of the first gas. According to one embodiment, the device includes a grounded reactor vessel having a gas inlet, a product outlet, and an electrode within the vessel; a power supply coupled to the electrode for creating an electrostatic field within the vessel for converting the first gas to a second gas.

A device and a process to propagate molecular growth of hydrocarbons, either straight or branched chain structures, that naturally occur in the gas phase of a first gas to gas phase molecules of a second gas having higher molecular chain lengths than the hydrocarbons of the first gas. According to one embodiment, the device includes a grounded reactor vessel having a gas inlet, a product outlet, and an electrode within the vessel; a power supply coupled to the electrode for creating an electrostatic field within the vessel for converting the first gas to a second gas.

A process increases the concentration of normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. A naphtha feed stream may be separated into a normal paraffin stream and a non-normal paraffin stream. An isomerization feed stream may be taken from the non-normal paraffin stream and isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins and produce an isomerization effluent stream. The isomerization effluent stream may be separated into a propane stream and a C4+ hydrocarbon stream optionally in a single column. The C4+ hydrocarbon stream may be recycled to the step of separating a naphtha feed stream.

A process increases the concentration of normal paraffins in a feed stream comprising separating a naphtha feed stream into a normal paraffin rich stream and a non-normal paraffin rich stream. A naphtha feed stream may be separated into a normal paraffin stream and a non-normal paraffin stream. An isomerization feed stream may be taken from the non-normal paraffin stream and isomerized over an isomerization catalyst to convert non-normal paraffins to normal paraffins and produce an isomerization effluent stream. The isomerization effluent stream may be separated into a propane stream and a C4+ hydrocarbon stream optionally in a single column. The C4+ hydrocarbon stream may be recycled to the step of separating a naphtha feed stream.