C07C15/24

SILYLATIONS OF AROMATIC SUBSTRATES WITH BASE-ACTIVATED ORGANOSILANES
20210122701 · 2021-04-29 ·

The present disclosure describes methods for silylating aromatic organic substrates, and associated chemical systems, said methods comprising or consisting essentially of contacting the aromatic organic substrate with a mixture of (a) at least one organosilane and (b) at least one strong base, under conditions sufficient to silylate the aromatic substrate.

CATALYTIC SYNTHESIS OF SUPER LINEAR ALKENYL ARENES USING RHODIUM CATALYSTS

Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).

CATALYTIC SYNTHESIS OF SUPER LINEAR ALKENYL ARENES USING RHODIUM CATALYSTS

Catalytic methods for synthesis of super linear alkenyl arenes and alkyl arenes are provided. The methods are capable of synthesizing super linear alkyl and alkenyl arenes from simple arene and olefin starting materials and with high selectivity for linear coupling. Methods are also provided for making a 2,6-dimethylnapthalene (DMN) or 2,6-methylethylnapthalene (MEN).

Zuclomiphene Salts and Crystalline Forms Thereof

The present invention provides zuclomiphene salts, zuclomiphene binaphthyl hydrogen phosphate salt (1-A)⋅(BPA) and zuclomiphene oxalate salt (1-A)⋅(OXL), crystalline forms thereof and processes for the preparation thereof.

Zuclomiphene Salts and Crystalline Forms Thereof

The present invention provides zuclomiphene salts, zuclomiphene binaphthyl hydrogen phosphate salt (1-A)⋅(BPA) and zuclomiphene oxalate salt (1-A)⋅(OXL), crystalline forms thereof and processes for the preparation thereof.

Pyrene derivative, organic light-emitting medium, and organic electroluminescent element containing pyrene derivative or organic light- emitting medium

An organic light-emitting medium including a pyrene derivative represented by the following formula (1) and a phenyl-substituted anthracene derivative represented by the following formula (2): ##STR00001##
wherein Ar.sup.1 to Ar.sup.4 are independently a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroaryl group having 5 to 20 ring atoms.

Pyrene derivative, organic light-emitting medium, and organic electroluminescent element containing pyrene derivative or organic light- emitting medium

An organic light-emitting medium including a pyrene derivative represented by the following formula (1) and a phenyl-substituted anthracene derivative represented by the following formula (2): ##STR00001##
wherein Ar.sup.1 to Ar.sup.4 are independently a substituted or unsubstituted aryl group having 6 to 30 ring carbon atoms or a substituted or unsubstituted heteroaryl group having 5 to 20 ring atoms.

Silylations of aromatic substrates with base-activated organosilanes

The present disclosure describes methods for silylating aromatic organic substrates, and associated chemical systems, said methods comprising or consisting essentially of contacting the aromatic organic substrate with a mixture of (a) at least one organosilane and (b) at least one strong base, under conditions sufficient to silylate the aromatic substrate.

Silylations of aromatic substrates with base-activated organosilanes

The present disclosure describes methods for silylating aromatic organic substrates, and associated chemical systems, said methods comprising or consisting essentially of contacting the aromatic organic substrate with a mixture of (a) at least one organosilane and (b) at least one strong base, under conditions sufficient to silylate the aromatic substrate.

Process for Transalkylation of Aromatic Fluids

Systems and methods are provided for an improved transalkylation process that better tolerates the presence of C.sub.10+ aromatics and may be conducted substantially in the liquid phase. The transalkylation feedstock may comprise alkyl-substituted benzenes and naphthalene and the transalkylation effluent comprises alkyl-substituted naphthalene and benzene, toluene, and/or xylenes.