The present invention relates to a process for neutralizing a composition A comprising 1-chloro-3,3,3-trifluoropropene, 1,1-dichloro-1,3,3-trifluoropropane and one or more acid compound(s) of formula HX with X═F or Cl; said process comprising the step a) of bringing said composition A into contact with a solution B under conditions capable of limiting the formation of 1-chloro-1,3,3-trifluoropropene.

The present invention relates to a process for neutralizing a composition A comprising 1-chloro-3,3,3-trifluoropropene, 1,1-dichloro-1,3,3-trifluoropropane and one or more acid compound(s) of formula HX with X═F or Cl; said process comprising the step a) of bringing said composition A into contact with a solution B under conditions capable of limiting the formation of 1-chloro-1,3,3-trifluoropropene.

The invention relates to a process comprising contacting a composition comprising a (hydro)halocarbon and a compound of formula R.sub.f—C≡CX with a basic solution comprising an hydroxide, an alkoxide and/or an amide to reduce the concentration of R.sub.f—C≡CX, wherein R.sub.f is a perfluorinated alkyl group and X is H, F, Cl, Br, or I. The invention further relates to process for preparing a (hydro)halocarbon comprising (i) converting a starting material, optionally in the presence of HF and/or a catalyst, to a composition comprising the (hydro)halocarbon and a compound of formula R.sub.f—C≡CX, wherein R.sub.f is a perfluorinated alkyl group and X is H, F, Cl, Br, or I; (ii) contacting the composition with a basic solution comprising an hydroxide, an alkoxide and/or an amide to reduce the concentration of the compound of formula R.sub.f—C≡CX; and (iii) recovering the (hydro)halocarbon.

The invention relates to a process comprising contacting a composition comprising a (hydro)halocarbon and a compound of formula R.sub.f—C≡CX with a basic solution comprising an hydroxide, an alkoxide and/or an amide to reduce the concentration of R.sub.f—C≡CX, wherein R.sub.f is a perfluorinated alkyl group and X is H, F, Cl, Br, or I. The invention further relates to process for preparing a (hydro)halocarbon comprising (i) converting a starting material, optionally in the presence of HF and/or a catalyst, to a composition comprising the (hydro)halocarbon and a compound of formula R.sub.f—C≡CX, wherein R.sub.f is a perfluorinated alkyl group and X is H, F, Cl, Br, or I; (ii) contacting the composition with a basic solution comprising an hydroxide, an alkoxide and/or an amide to reduce the concentration of the compound of formula R.sub.f—C≡CX; and (iii) recovering the (hydro)halocarbon.

The invention relates to a process comprising contacting a composition comprising a (hydro)halocarbon and a compound of formula R.sub.f—C≡CX with a basic solution comprising an hydroxide, an alkoxide and/or an amide to reduce the concentration of R.sub.f—C≡CX, wherein R.sub.f is a perfluorinated alkyl group and X is H, F, Cl, Br, or I. The invention further relates to process for preparing a (hydro)halocarbon comprising (i) converting a starting material, optionally in the presence of HF and/or a catalyst, to a composition comprising the (hydro)halocarbon and a compound of formula R.sub.f—C≡CX, wherein R.sub.f is a perfluorinated alkyl group and X is H, F, Cl, Br, or I; (ii) contacting the composition with a basic solution comprising an hydroxide, an alkoxide and/or an amide to reduce the concentration of the compound of formula R.sub.f—C≡CX; and (iii) recovering the (hydro)halocarbon.

Provided is a method for producing a deuterated aromatic compound and a deuterated reaction composition. The method includes performing a deuterated reaction of an aromatic compound including one or more hydrocarbon aromatic rings using a solution comprising heavy water, an organic compound which can be hydrolyzed by the heavy water, the aromatic compound, and an organic solvent. The method has an advantage in that impurities due to hydrogen gas are not generated, the deuterium substitution rate is high, and the deuterated reaction can be performed under a lower pressure and a lower temperature.

Provided is a method for producing a deuterated aromatic compound and a deuterated reaction composition. The method includes performing a deuterated reaction of an aromatic compound including one or more hydrocarbon aromatic rings using a solution comprising heavy water, an organic compound which can be hydrolyzed by the heavy water, the aromatic compound, and an organic solvent. The method has an advantage in that impurities due to hydrogen gas are not generated, the deuterium substitution rate is high, and the deuterated reaction can be performed under a lower pressure and a lower temperature.

The present invention relates to a process for purifying 1-chloro-3,3,3-trifluoropropene comprising the steps of: a) providing a stream comprising 1-chloro-3,3,3-trifluoropropene and at least one compound of formula HX wherein X is F or Cl; b) bringing the stream from step a) into contact with a solution A comprising at least one sulfite salt of formula Y.sup.n+.sub.mSO.sub.3 wherein Y is an alkali or alkaline-earth metal, n=1 or 2, and m=2 when n=1 or m=1 when n=2; in order to form a neutralized stream A1 comprising 1-chloro-3,3,3-trifluoropropene.

The present invention relates to a process for purifying 1-chloro-3,3,3-trifluoropropene comprising the steps of: a) providing a stream comprising 1-chloro-3,3,3-trifluoropropene and at least one compound of formula HX wherein X is F or Cl; b) bringing the stream from step a) into contact with a solution A comprising at least one sulfite salt of formula Y.sup.n+.sub.mSO.sub.3 wherein Y is an alkali or alkaline-earth metal, n=1 or 2, and m=2 when n=1 or m=1 when n=2; in order to form a neutralized stream A1 comprising 1-chloro-3,3,3-trifluoropropene.

The present invention relates to a process for purifying 1-chloro-3,3,3-trifluoropropene comprising the steps of: a) providing a stream comprising 1-chloro-3,3,3-trifluoropropene and at least one compound of formula HX wherein X is F or Cl; b) bringing the stream from step a) into contact with a solution A comprising at least one sulfite salt of formula Y.sup.n+.sub.mSO.sub.3 wherein Y is an alkali or alkaline-earth metal, n=1 or 2, and m=2 when n=1 or m=1 when n=2; in order to form a neutralized stream A1 comprising 1-chloro-3,3,3-trifluoropropene.