Patent classifications
C07C37/002
CARDANOL GLYCIDYL ETHER DERIVATIVES
Methacrylated cardanol glycidyl ethers, diglycidyl ethers, intermediates and derivatives thereof are described herein. Compositions and polymers made with such compounds as well as methods of preparation thereof are also described. For example, compounds of Formulas: wherein n, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, and R.sub.6 can each represent various different entities are described in the present disclosure.
Process for preparing tapinarof
The present invention provides processes for the preparation of 3, 5-Dihydroxy-4-isopropyl-trans-stilbene or a salt or solvate thereof and novel intermediates used therein. In some embodiments the 3, 5-Dihydroxy-4-isopropyl-trans-stilbene is prepared from (E)-2-chloro-2-isopropyl-5-styrylcyclohexane-1,3-dione. Also disclosed are crystal forms of 3, 5-Dihydroxy-4-isopropyl-trans-stilbene or a salt or solvate thereof and pharmaceutical compositions comprising same.
Radically curable compound, method for producing radically curable compound, radically curable composition, cured product of the same, and resist-material composition
Provided is a positive photoresist composition excellent in terms of heat resistance. A radically curable compound is represented by a general formula (1) below (where R.sup.1, R.sup.2, and R.sup.3 each independently represent an alkyl group having 1 to 8 carbon atoms; m and n each independently represent an integer of 1 to 4; p represents an integer of 0 to 4; X, Y, and Z each independently represent an acryloyloxy group, a methacryloyloxy group, or a hydroxy group, and at least one of X, Y, and Z represents an acryloyloxy group or a methacryloyloxy group; and t represents 1 or 2). ##STR00001##
PROCESS FOR PREPARING TAPINAROF
The present invention provides processes for the preparation of 3, 5-Dihydroxy-4-isopropyl-trans-stilbene or a salt or solvate thereof and novel intermediates used therein. In some embodiments the 3, 5-Dihydroxy-4-isopropyl-trans-stilbene is prepared from (E)-2-chloro-2-isopropyl-5-styrylcyclohexane-1,3-dione. Also disclosed are crystal forms of 3, 5-Dihydroxy-4-isopropyl-trans-stilbene or a salt or solvate thereof and pharmaceutical compositions comprising same.
CARDANOL-BASED BISPHENOL, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
A method for preparing bisphenol includes: mixing and uniformly stirring cardanol, formaldehyde and an alkaline catalyst, and reacting at a certain temperature to obtain a hydroxymethylation product A; washing the product A multiple times with water until the pH value is neutral, and then centrifuging to remove water to obtain a product B; mixing and uniformly stirring the product B with phenol and an acidic catalyst, and reacting at a certain temperature to obtain a product C after a phenolic alcohol reaction; washing the product C with water until neutral, and distilling same under reduced pressure to obtain a cardanol-based bisphenol product. Cardanol is used which has the structural characteristics of both a benzene ring and an alkane chain, and when protecting phenolic hydroxyl which has high reaction activity, a bisphenol structure which has both benzene ring rigidity and cardanol upper alkane long-chain toughness is obtained.
Chiral multidentate ligand, and application thereof in asymmetric hydrogenation
Disclosed are a chiral multidentate ligand (I), a preparation, and an application thereof. In this method, compound (M1) is subjected to condensation with compound (M2) followed by amine deprotection in the presence of a deprotection reagent to obtain compound (M4). Compound (1) is subjected to deprotonation by butyl lithium and phosphorization followed by dimethylamino group substitution to produce compound (3). The compound (3) and the compound (M4) are reacted in the presence of triethylamine to produce chiral multidentate ligands. ##STR00001##