C07C39/04

METHODS OF ISOLATING PHENOLS FROM PHENOL-CONTAINING MEDIA

Methods of isolating phenols from phenol-containing media. The methods include combining a phospholipid-containing composition with the phenol-containing medium to generate a combined medium, incubating the combined medium to precipitate phenols in the combined medium and thereby form a phenol precipitate phase and a phenol-depleted phase, and separating the phenol precipitate phase and the phenol-depleted phase. The methods can further include extracting phenols from the separated phenol precipitate phase. The extracting can include mixing the separated phenol precipitate phase with an extraction solvent to solubilize in the extraction solvent at least a portion of the phenols originally present in the phenol precipitate phase.

METHOD FOR PRODUCING A HYDROXY COMPOUND BY DECARBOXYLATION IN THE ABSENCE OF A CATALYST
20210395177 · 2021-12-23 ·

The invention relates to a method for producing a specific hydroxyl compound by decarboxylating a specific carboxylic acid compound or a salt of said carboxylic acid compound in the absence of a catalyst and to a method for producing a bisphenol.

METHOD FOR PRODUCING A HYDROXY COMPOUND BY DECARBOXYLATION IN THE ABSENCE OF A CATALYST
20210395177 · 2021-12-23 ·

The invention relates to a method for producing a specific hydroxyl compound by decarboxylating a specific carboxylic acid compound or a salt of said carboxylic acid compound in the absence of a catalyst and to a method for producing a bisphenol.

ACETONE RECOVERY AND PURIFICATION

Methods and systems for preparing acetone from cumene hydroperoxide (CHP) are disclosed. The disclosed methods involve cleaving CHP to form a cleavage product stream. In some embodiments, the cleavage product stream is separated into an overhead stream and a bottoms stream. The bottoms stream is neutralized, washed and then treated in a crude acetone column to provide a crude acetone stream. The overhead stream of the cleavage product is flashed forward in the process, bypassing the neutralization, washing, and crude acetone column and is then combined with the crude acetone stream. The combined acetone streams are provided to an acetone product column. According to some embodiments, the acetone product column comprises a side draw for obtaining a recycle acetone stream, which is recycled to the cleavage reactor(s). The recycle acetone side draw may be located lower on the acetone product column than the point from which product acetone is obtained. The disclosed methods increase the efficiency of the process.

ACETONE RECOVERY AND PURIFICATION

Methods and systems for preparing acetone from cumene hydroperoxide (CHP) are disclosed. The disclosed methods involve cleaving CHP to form a cleavage product stream. In some embodiments, the cleavage product stream is separated into an overhead stream and a bottoms stream. The bottoms stream is neutralized, washed and then treated in a crude acetone column to provide a crude acetone stream. The overhead stream of the cleavage product is flashed forward in the process, bypassing the neutralization, washing, and crude acetone column and is then combined with the crude acetone stream. The combined acetone streams are provided to an acetone product column. According to some embodiments, the acetone product column comprises a side draw for obtaining a recycle acetone stream, which is recycled to the cleavage reactor(s). The recycle acetone side draw may be located lower on the acetone product column than the point from which product acetone is obtained. The disclosed methods increase the efficiency of the process.

Method of decomposing by-product in phenol preparation process

A method of decomposing a phenol by-product produced in a phenol preparation process, in which acetophenone separated from a distillation column is mixed with tar separated and collected in a decomposition reactor, thereby significantly decreasing viscosity of tar. The decomposition method according to the present invention allows tar to have sufficient viscosity for flowability even at room temperature, whereby transfer and storage of tar may be more smoothly done without using any heating device for transfer of tar.

Method of decomposing by-product in phenol preparation process

A method of decomposing a phenol by-product produced in a phenol preparation process, in which acetophenone separated from a distillation column is mixed with tar separated and collected in a decomposition reactor, thereby significantly decreasing viscosity of tar. The decomposition method according to the present invention allows tar to have sufficient viscosity for flowability even at room temperature, whereby transfer and storage of tar may be more smoothly done without using any heating device for transfer of tar.

PURIFICATION AND EXTRACTION OF CANNABINOIDS
20210370198 · 2021-12-02 ·

A method for purification and extraction of cannabinoids includes: providing a cannabis oil including phospholipids and cannabinoid acids; contacting the cannabis oil with a degumming solvent, wherein the degumming solvent and cannabis oil are substantially immiscible; and separating an aqueous phase including the degumming solvent and at least a portion of the phospholipids from an oil phase including the cannabis oil. The method may further include contacting the oil phase with an extraction solvent, where the extraction solvent and oil phase are substantially immiscible; and separating an aqueous phase including the extraction solvent and at least a portion of the cannabinoid acids from a second oil solvent phase including the oil phase and/or simply the liberated cannabinoids following acidification of the extraction solvent.

PURIFICATION AND EXTRACTION OF CANNABINOIDS
20210370198 · 2021-12-02 ·

A method for purification and extraction of cannabinoids includes: providing a cannabis oil including phospholipids and cannabinoid acids; contacting the cannabis oil with a degumming solvent, wherein the degumming solvent and cannabis oil are substantially immiscible; and separating an aqueous phase including the degumming solvent and at least a portion of the phospholipids from an oil phase including the cannabis oil. The method may further include contacting the oil phase with an extraction solvent, where the extraction solvent and oil phase are substantially immiscible; and separating an aqueous phase including the extraction solvent and at least a portion of the cannabinoid acids from a second oil solvent phase including the oil phase and/or simply the liberated cannabinoids following acidification of the extraction solvent.

BIO-BASED ETHYLENE FOR THE PRODUCTION OF BIO-BASED POLYMERS, COPOLYMERS, AND OTHER BIO-BASED CHEMICAL COMPOUNDS

Bio-based ethanol, such as ethanol produced from lignocellulosic materials, for example, is processed to produce bio-based ethylene, which can then be processed further to produce other bio-based materials including bio-based polymers and copolymers, including bio-based polyethylene, bio-based α-olefins, bio-based 1,2-diols, as well as other compounds.