Patent classifications
C07C45/50
RECYCLE CONTENT ALPHA OLEFINS AND FATTY ALCOHOLS
A composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content alpha olefin or by deducting from a recycle inventory a recycle content value applied to an alpha olefin composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by an alpha olefin manufacturer has its origin in recycled waste and/or pyrolysis of recycled waste and/or in thermal steam cracking of recycle content pyoil.
PROCESS FOR REGENERATING A CATALYST FOR THE HYDROFORMYLATION OF OLEFINS IN THE GAS PHASE
The present invention relates to a simple process for regenerating a hydroformylation catalyst consisting of a heterogenized catalyst system on a support consisting of a porous ceramic material. The invention also relates to a process for the start-up of the hydroformylation reaction after regeneration according to the invention.
PROCESS FOR REGENERATING A CATALYST FOR THE HYDROFORMYLATION OF OLEFINS IN THE GAS PHASE
The present invention relates to a simple process for regenerating a hydroformylation catalyst consisting of a heterogenized catalyst system on a support consisting of a porous ceramic material. The invention also relates to a process for the start-up of the hydroformylation reaction after regeneration according to the invention.
Continuous Hydroformylation Process With Catalyst Substitution
The present invention relates to a continuous two-phase hydroformylation process for the production of aldehydes from olefins by means of carbon monoxide, hydrogen and a transition metal catalyst in a reaction zone, the transition metal being in the form of a water-soluble catalyst complex, wherein the process comprising the following steps once or several times:
a) hydroformylating by reacting the olefins, carbon monoxide and hydrogen over a water-soluble transition metal catalyst comprising water-soluble organophosphorus ligands in the reaction zone;
b) reducing the concentration of the olefins in the reaction zone by reducing the olefin feed to the reaction zone and withdrawing at least a portion of the catalyst solution from the reaction system, wherein the catalyst solution withdrawal and olefin concentration reduction substeps may occur in this or reverse order, simultaneously or sequentially;
c) feeding a solvent, a transition metal source and water-soluble organophosphorus ligands to the reaction system, wherein the feeding of the components may occur simultaneously or in any order sequentially;
d) increasing the concentration of the olefins in the reaction zone by increasing the olefin feed to the reaction zone and hydroformylating by reacting the olefins with carbon monoxide and hydrogen.
Continuous Hydroformylation Process With Catalyst Substitution
The present invention relates to a continuous two-phase hydroformylation process for the production of aldehydes from olefins by means of carbon monoxide, hydrogen and a transition metal catalyst in a reaction zone, the transition metal being in the form of a water-soluble catalyst complex, wherein the process comprising the following steps once or several times:
a) hydroformylating by reacting the olefins, carbon monoxide and hydrogen over a water-soluble transition metal catalyst comprising water-soluble organophosphorus ligands in the reaction zone;
b) reducing the concentration of the olefins in the reaction zone by reducing the olefin feed to the reaction zone and withdrawing at least a portion of the catalyst solution from the reaction system, wherein the catalyst solution withdrawal and olefin concentration reduction substeps may occur in this or reverse order, simultaneously or sequentially;
c) feeding a solvent, a transition metal source and water-soluble organophosphorus ligands to the reaction system, wherein the feeding of the components may occur simultaneously or in any order sequentially;
d) increasing the concentration of the olefins in the reaction zone by increasing the olefin feed to the reaction zone and hydroformylating by reacting the olefins with carbon monoxide and hydrogen.
Continuous Hydroformylation Process With Catalyst Substitution
The present invention relates to a continuous two-phase hydroformylation process for the production of aldehydes from olefins by means of carbon monoxide, hydrogen and a transition metal catalyst in a reaction zone, the transition metal being in the form of a water-soluble catalyst complex, wherein the process comprising the following steps once or several times:
a) hydroformylating by reacting the olefins, carbon monoxide and hydrogen over a water-soluble transition metal catalyst comprising water-soluble organophosphorus ligands in the reaction zone;
b) reducing the concentration of the olefins in the reaction zone by reducing the olefin feed to the reaction zone and withdrawing at least a portion of the catalyst solution from the reaction system, wherein the catalyst solution withdrawal and olefin concentration reduction substeps may occur in this or reverse order, simultaneously or sequentially;
c) feeding a solvent, a transition metal source and water-soluble organophosphorus ligands to the reaction system, wherein the feeding of the components may occur simultaneously or in any order sequentially;
d) increasing the concentration of the olefins in the reaction zone by increasing the olefin feed to the reaction zone and hydroformylating by reacting the olefins with carbon monoxide and hydrogen.
RECYCLE CONTENT OXO GLYCOLS
A recycle content oxo glycol and method of making a recycle content oxo glycol wherein the recycle content is derived directly or indirectly from the cracking of recycle content pyrolysis oil and/or gas. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.
RECYCLE CONTENT OXO GLYCOLS
A recycle content oxo glycol and method of making a recycle content oxo glycol wherein the recycle content is derived directly or indirectly from the cracking of recycle content pyrolysis oil and/or gas. The cracking of the pyrolysis oil can be conducted in a gas furnace or a split furnace.
Method for producing carbon monoxide
The present invention concerns a method of production for carbon monoxide using a derivative of formic acid, in particular an alkyl formate. It also concerns a method chosen from among, the method of production of methanol, the method of production of acetic acid (Monsanto and Cativa methods), the method of hydroformylation of olefins (oxo and aldox method, the method of production of hydrocarbons (Fischer-Tropsch method), or the method of carbonylation of nickel (Mond method), comprising a step of production of carbon monoxide using an alkyl formate of formula (I) by the method according to the invention. It further concerns a “CO pump” or “CO liquid storage” method comprising a step of production of carbon monoxide using an alkyl formate of formula (I) according to the method of the invention.
Method for producing carbon monoxide
The present invention concerns a method of production for carbon monoxide using a derivative of formic acid, in particular an alkyl formate. It also concerns a method chosen from among, the method of production of methanol, the method of production of acetic acid (Monsanto and Cativa methods), the method of hydroformylation of olefins (oxo and aldox method, the method of production of hydrocarbons (Fischer-Tropsch method), or the method of carbonylation of nickel (Mond method), comprising a step of production of carbon monoxide using an alkyl formate of formula (I) by the method according to the invention. It further concerns a “CO pump” or “CO liquid storage” method comprising a step of production of carbon monoxide using an alkyl formate of formula (I) according to the method of the invention.