The present embodiments are directed to compositions of quinones and/or quinols, such as, but not limited to, ubiquinone and/or ubiquinol, vitamin E quinone and/or vitamin E quinol, vitamin K quinone and/or vitamin K quinol, menaquinones and/or menaquinols, and pyrroloquinoline quinone and/or pyrroloquinoline quinol, and methods for preparations and use thereof. The present embodiments are also directed to compositions of reduced forms of curcuminoid and methods for preparations and use thereof.

The present embodiments are directed to compositions of quinones and/or quinols, such as, but not limited to, ubiquinone and/or ubiquinol, vitamin E quinone and/or vitamin E quinol, vitamin K quinone and/or vitamin K quinol, menaquinones and/or menaquinols, and pyrroloquinoline quinone and/or pyrroloquinoline quinol, and methods for preparations and use thereof. The present embodiments are also directed to compositions of reduced forms of curcuminoid and methods for preparations and use thereof.

The present invention relates to an acetal compound of the following general formula (1) and an acetal compound of the following general formula (2). The present invention relates to processes for preparing the acetal compound (2), comprising subjecting the acetal compound (1) to a hydrogenation reaction to form the acetal compound (2). The present invention provides a process for preparing 2,3,4,4-tetramethylcyclopentanecarbaldehyde of the following formula (3), comprising subjecting the acetal compound (2) to a hydrolysis reaction to form 2,3,4,4-tetramethylcyclopentanecarbaldehyde (3).

##STR00001##

The present invention relates to an acetal compound of the following general formula (1) and an acetal compound of the following general formula (2). The present invention relates to processes for preparing the acetal compound (2), comprising subjecting the acetal compound (1) to a hydrogenation reaction to form the acetal compound (2). The present invention provides a process for preparing 2,3,4,4-tetramethylcyclopentanecarbaldehyde of the following formula (3), comprising subjecting the acetal compound (2) to a hydrolysis reaction to form 2,3,4,4-tetramethylcyclopentanecarbaldehyde (3).

##STR00001##

The present invention relates to an acetal compound of the following general formula (1) and an acetal compound of the following general formula (2). The present invention relates to processes for preparing the acetal compound (2), comprising subjecting the acetal compound (1) to a hydrogenation reaction to form the acetal compound (2). The present invention provides a process for preparing 2,3,4,4-tetramethylcyclopentanecarbaldehyde of the following formula (3), comprising subjecting the acetal compound (2) to a hydrolysis reaction to form 2,3,4,4-tetramethylcyclopentanecarbaldehyde (3). ##STR00001##

The present invention relates to an acetal compound of the following general formula (1) and an acetal compound of the following general formula (2). The present invention relates to processes for preparing the acetal compound (2), comprising subjecting the acetal compound (1) to a hydrogenation reaction to form the acetal compound (2). The present invention provides a process for preparing 2,3,4,4-tetramethylcyclopentanecarbaldehyde of the following formula (3), comprising subjecting the acetal compound (2) to a hydrolysis reaction to form 2,3,4,4-tetramethylcyclopentanecarbaldehyde (3). ##STR00001##

A process for preparing aldehydes by a homogeneously catalysed hydroformylation of C.sub.4 to C.sub.20 olefins involves withdrawing a biphasic stream (liquid/gaseous) and expanding in two stages. Before, between, or after the two stages, the liquid phase is cooled. Only after expansion and cooling is the homogeneously dissolved rhodium catalyst system separated from the residual stream.

A process for preparing aldehydes by a homogeneously catalysed hydroformylation of C.sub.4 to C.sub.20 olefins involves withdrawing a biphasic stream (liquid/gaseous) and expanding in two stages. Before, between, or after the two stages, the liquid phase is cooled. Only after expansion and cooling is the homogeneously dissolved rhodium catalyst system separated from the residual stream.

A process for the preparation of transition metal nanoparticles, the process comprising: (a) providing a mixture comprising one or more salts of one or more transition metals M, one or more complexing agents C, and a solvent system S; (b) optionally adjusting the pH of the mixture provided in (a) to a pH comprised in the range of from 4 to 8; (c) heating the mixture provided in (a) or obtained in (b) for obtaining a colloidal suspension of transition metal nanoparticles; (d) optionally isolating the transition metal nanoparticles obtained in (c), preferably by centrifugation and/or evaporation to dryness of the colloidal suspension obtained in (c) wherein the mixture provided in (a) and heated in (c) or obtained in (b) and heated in (c) does not comprise polyvinyl sulfate and/or polyvinylpyrrolidone.

A process for the preparation of transition metal nanoparticles, the process comprising: (a) providing a mixture comprising one or more salts of one or more transition metals M, one or more complexing agents C, and a solvent system S; (b) optionally adjusting the pH of the mixture provided in (a) to a pH comprised in the range of from 4 to 8; (c) heating the mixture provided in (a) or obtained in (b) for obtaining a colloidal suspension of transition metal nanoparticles; (d) optionally isolating the transition metal nanoparticles obtained in (c), preferably by centrifugation and/or evaporation to dryness of the colloidal suspension obtained in (c) wherein the mixture provided in (a) and heated in (c) or obtained in (b) and heated in (c) does not comprise polyvinyl sulfate and/or polyvinylpyrrolidone.