C07C45/786

DEHYDRATION OF WATER CONTAINING SOURCE OF FORMALDEHYDE, AND A METHOD FOR PRODUCING AN ETHYLENICALLY UNSATURATED CARBOXYLIC ESTER
20190062181 · 2019-02-28 ·

Disclosed are methods for dehydrating a water containing source of formaldehyde in which water is separated from the water containing source of formaldehyde using a zeolite membrane. In certain aspects, the water containing source of formaldehyde includes a separation enhancer having a relative static permittivity ranging from 2.5 to 20, and the water containing source of formaldehyde may further include methanol. In certain aspects, (meth)acrylic acid alkyl ester may be produced using the dehydrated source of formaldehyde.

HYDROFORMYLATION PROCESS

Embodiments of the present invention relate to processes for the hydroformylation of olefins to produce aldehydes. In some embodiments, processes of the present invention are capable of maintaining high C.sub.2-C.sub.4 olefin conversion and/or provide more compact hydroformlyation processes.

HYDROFORMYLATION PROCESS

Embodiments of the present invention relate to processes for the hydroformylation of olefins to produce aldehydes. In some embodiments, processes of the present invention are capable of maintaining high C.sub.2-C.sub.4 olefin conversion and/or provide more compact hydroformlyation processes.

Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester

Disclosed are methods for dehydrating a water containing source of formaldehyde in which water is separated from the water containing source of formaldehyde using a zeolite membrane. In certain aspects, the water containing source of formaldehyde includes a separation enhancer having a relative static permittivity ranging from 2.5 to 20, and the water containing source of formaldehyde may further include methanol. In certain aspects, (meth)acrylic acid alkyl ester may be produced using the dehydrated source of formaldehyde.

Dehydration of water containing source of formaldehyde, and a method for producing an ethylenically unsaturated carboxylic ester

Disclosed are methods for dehydrating a water containing source of formaldehyde in which water is separated from the water containing source of formaldehyde using a zeolite membrane. In certain aspects, the water containing source of formaldehyde includes a separation enhancer having a relative static permittivity ranging from 2.5 to 20, and the water containing source of formaldehyde may further include methanol. In certain aspects, (meth)acrylic acid alkyl ester may be produced using the dehydrated source of formaldehyde.

Method for manufacturing organic processing fluid for patterning of chemical amplification type resist film, organic processing fluid for patterning of chemical amplification type resist film, pattern forming method, method for manufacturing electronic device, and electronic device

There is disclosed a method for manufacturing an organic processing fluid for patterning of a chemical amplification type resist film, comprising a step of causing a fluid containing an organic solvent to pass through a filtration device having a fluid input portion, a fluid output portion, and a filtration filter film provided in a flow path that connects the fluid input portion and the fluid output portion with each other, wherein an absolute value (|T.sub.IT.sub.o|) of a difference between a temperature (T.sub.I) of the fluid in the fluid input portion and a temperature (T.sub.o) of the fluid in the fluid output portion is 3 C. or lower, a filtration speed of the fluid in the filtration device is 0.5 L/min/m.sup.2 or greater, and a filtration pressure by the fluid in the filtration device is 0.10 MPa or lower.

Method for manufacturing organic processing fluid for patterning of chemical amplification type resist film, organic processing fluid for patterning of chemical amplification type resist film, pattern forming method, method for manufacturing electronic device, and electronic device

There is disclosed a method for manufacturing an organic processing fluid for patterning of a chemical amplification type resist film, comprising a step of causing a fluid containing an organic solvent to pass through a filtration device having a fluid input portion, a fluid output portion, and a filtration filter film provided in a flow path that connects the fluid input portion and the fluid output portion with each other, wherein an absolute value (|T.sub.IT.sub.o|) of a difference between a temperature (T.sub.I) of the fluid in the fluid input portion and a temperature (T.sub.o) of the fluid in the fluid output portion is 3 C. or lower, a filtration speed of the fluid in the filtration device is 0.5 L/min/m.sup.2 or greater, and a filtration pressure by the fluid in the filtration device is 0.10 MPa or lower.

Optimized separation technique for work-up of homogeneously catalysed hydroformylation mixtures

The invention relates to a method for producing alcohols by homogeneously catalyzed hydroformylation of olefins to aldehydes and subsequent hydration of the aldehydes. The invention further relates to a system for carrying out the method. The main focus is on the separation technique for work-up of the hydroformylation mixture. The problem addressed by the invention is that specifying a work-up method for hydroformylation mixtures that utilizes the specific advantages of known separation technologies but at the same time largely avoids the specific disadvantages of said separation technologies. The most important objective is to create a catalyst separation system that is as complete and at the same time conservative as possible and that operates in a technically reliable manner and entails low investment and operating costs. The method should be unrestrictedly suitable for processing the reaction output from oxo systems in world scale format. The problem is solved by combining membrane separation units and a thermal separation unit, the thermal separation unit being operated in such a manner that 80% to 98% of the mass introduced with the product stream into the thermal separation unit exits the thermal separation unit again as a head product.

Optimized separation technique for work-up of homogeneously catalysed hydroformylation mixtures

The invention relates to a method for producing alcohols by homogeneously catalyzed hydroformylation of olefins to aldehydes and subsequent hydration of the aldehydes. The invention further relates to a system for carrying out the method. The main focus is on the separation technique for work-up of the hydroformylation mixture. The problem addressed by the invention is that specifying a work-up method for hydroformylation mixtures that utilizes the specific advantages of known separation technologies but at the same time largely avoids the specific disadvantages of said separation technologies. The most important objective is to create a catalyst separation system that is as complete and at the same time conservative as possible and that operates in a technically reliable manner and entails low investment and operating costs. The method should be unrestrictedly suitable for processing the reaction output from oxo systems in world scale format. The problem is solved by combining membrane separation units and a thermal separation unit, the thermal separation unit being operated in such a manner that 80% to 98% of the mass introduced with the product stream into the thermal separation unit exits the thermal separation unit again as a head product.

PROCESS FOR THE HYDROFORMYLATION OF DIISOBUTENE WITH PRECEDING DISTILLATION

A process is developed for the hydroformylation of diisobutene, in which the diisobutene stream used is subjected to a distillation prior to the hydroformylation in order to enrich 2,4,4-trimethylpent-1-ene in the stream to be hydroformylated. The hydroformylation is carried out with synthesis gas in the presence of a homogeneous catalyst system that comprises at least Co or Rh and optionally a phosphorus-containing ligand.