A composition can photocatalytically reduce carbon dioxide.

A composition can photocatalytically reduce carbon dioxide.

[Solution] The present invention relates to a method for partially oxidizing an alkane, including contacting an alkane with a supported catalyst in a presence of an oxidizer to convert the alkane into an aldehyde, wherein the supported catalyst is composed of a bimetallic oxide and a support carrying the bimetallic oxide, and the bimetallic oxide is represented by the following formula and includes oxygen and two metals selected from metals of groups 8 to 10 of the periodic table:

A.sub.mB.sub.nO.sub.x wherein the bimetallic oxide and support are each a metal selected from metallic elements of groups 8 to 10 of the periodic table; the bimetallic oxide and support are not the same metallic element; m, n, and x mean amounts ((mmol)) of the bimetallic oxide, the support, and oxygen, respectively, per 1 g of the supported catalyst; m is more than 0 [mmol/g-cat] and less than 1 [mmol/g-cat]; n is more than 0 [mmol/g-cat] and less than 1 [mmol/g-cat]; and x is a value [mmol/g-cat] satisfying oxidation states of the bimetallic oxide and the support.

[Solution] The present invention relates to a method for partially oxidizing an alkane, including contacting an alkane with a supported catalyst in a presence of an oxidizer to convert the alkane into an aldehyde, wherein the supported catalyst is composed of a bimetallic oxide and a support carrying the bimetallic oxide, and the bimetallic oxide is represented by the following formula and includes oxygen and two metals selected from metals of groups 8 to 10 of the periodic table:

A.sub.mB.sub.nO.sub.x wherein the bimetallic oxide and support are each a metal selected from metallic elements of groups 8 to 10 of the periodic table; the bimetallic oxide and support are not the same metallic element; m, n, and x mean amounts ((mmol)) of the bimetallic oxide, the support, and oxygen, respectively, per 1 g of the supported catalyst; m is more than 0 [mmol/g-cat] and less than 1 [mmol/g-cat]; n is more than 0 [mmol/g-cat] and less than 1 [mmol/g-cat]; and x is a value [mmol/g-cat] satisfying oxidation states of the bimetallic oxide and the support.

Various processes for preparing C.sub.4 aldoses and/or ketones thereof are described. Various processes are described for preparing C.sub.4 aldoses and/or ketones thereof from feed compositions comprising glycolaldehyde. Also, various processes for preparing useful downstream products and intermediates, such as erythritol and erythronic acid, from the C.sub.4 aldoses and/or ketones thereof are described.

Various processes for preparing C.sub.4 aldoses and/or ketones thereof are described. Various processes are described for preparing C.sub.4 aldoses and/or ketones thereof from feed compositions comprising glycolaldehyde. Also, various processes for preparing useful downstream products and intermediates, such as erythritol and erythronic acid, from the C.sub.4 aldoses and/or ketones thereof are described.

A process and plant for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide is removed from flue gas from reforming section and used to convert partially or fully all ammonia into urea.

A process and plant for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide is removed from flue gas from reforming section and used to convert partially or fully all ammonia into urea.

The present invention relates to a process for preparing polyoxymethylene dimethyl ethers, comprising the following steps: reaction of formaldehyde and methylal (OME.sub.1) in a reactor R1 to obtain a product mixture, distillative separation of the product mixture in a distillation unit D1 into a top stream which contains OME.sub.1, OME.sub.2, formaldehyde, methanol and water, and a bottom stream which contains OME.sub.≥3, mixing of the top stream drawn off from the distillation unit D1 with a methanol-containing stream, treatment of the mixture in a reactive distillation unit RD2 to form a top stream containing methylal and a water-containing bottom stream, introduction of the bottom stream drawn off from the distillation unit D1 into a distillation unit D3 and distillative separation of the polyoxymethylene dimethyl ethers.

The present invention relates to a process for preparing polyoxymethylene dimethyl ethers, comprising the following steps: reaction of formaldehyde and methylal (OME.sub.1) in a reactor R1 to obtain a product mixture, distillative separation of the product mixture in a distillation unit D1 into a top stream which contains OME.sub.1, OME.sub.2, formaldehyde, methanol and water, and a bottom stream which contains OME.sub.≥3, mixing of the top stream drawn off from the distillation unit D1 with a methanol-containing stream, treatment of the mixture in a reactive distillation unit RD2 to form a top stream containing methylal and a water-containing bottom stream, introduction of the bottom stream drawn off from the distillation unit D1 into a distillation unit D3 and distillative separation of the polyoxymethylene dimethyl ethers.