Provided is an organic metal complex having a structure represented by the following general formula (1):

ML.sub.mL.sub.n(1)

where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2):

##STR00001##

and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

A carbon nanobelt represented by formula (1) was synthesized by chemical synthesis:

wherein each Ar is identical or different and represents an aromatic hydrocarbon ring; each R.sup.1 is identical or different and represents hydrogen, alkyl, aryl, or alkoxy; and n represents an integer of 0 or more.

A carbon nanobelt represented by formula (1) was synthesized by chemical synthesis:

wherein each Ar is identical or different and represents an aromatic hydrocarbon ring; each R.sup.1 is identical or different and represents hydrogen, alkyl, aryl, or alkoxy; and n represents an integer of 0 or more.

Provided is an organic metal complex having a structure represented by the following general formula (1):

ML.sub.mL.sub.n(1)

where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2):

##STR00001##

and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

Provided is an organic metal complex having a structure represented by the following general formula (1):

ML.sub.mL.sub.n(1)

where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2):

##STR00001##

and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

Disclosed are an aromatic acetylene or aromatic ethylene compound, an intermediate, a preparation method, a pharmaceutical composition and a use thereof. The aromatic acetylene or aromatic ethylene compound has a significant inhibitory effect on PD-1 and PD-L1, and can effectively relieve or treat cancers and other related diseases.

##STR00001##

Provided is an organic metal complex having a structure represented by the following general formula (1):
ML.sub.mL.sub.n(1)
where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2): ##STR00001##
and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

Provided is an organic metal complex having a structure represented by the following general formula (1):
ML.sub.mL.sub.n(1)
where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2): ##STR00001##
and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

The present invention discloses an iron-based nitrogen doped graphene catalyst, process for preparation thereof and use of said catalyst in oxidant-free catalytic dehydrogenation of alcohols and amines to the corresponding carbonyl compounds, amines and N-heterocylic compounds with extraction of molecular hydrogen as the only by-product.

The present invention discloses an iron-based nitrogen doped graphene catalyst, process for preparation thereof and use of said catalyst in oxidant-free catalytic dehydrogenation of alcohols and amines to the corresponding carbonyl compounds, amines and N-heterocylic compounds with extraction of molecular hydrogen as the only by-product.