The present invention relates to fungicidal N-cycloalkyl-N-{[2-(1-substitutedcycloalkyl)phenyl]methylene} carboxamide derivatives and their thiocarbonyl derivatives, their process of preparation and intermediate compounds for their preparation, their use as fungicides, particularly in the form of fungicidal compositions and methods for the control of phytopathogenic fungi of plants using these compounds or their compositions.

Provided is an organic metal complex having a structure represented by the following general formula (1):
ML.sub.mL.sub.n(1)
where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2): ##STR00001##
and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

Provided is an organic metal complex having a structure represented by the following general formula (1):
ML.sub.mL.sub.n(1)
where: M represents a metal atom selected from Ir, Pt, Rh, Os, and Zn; L and L, which are different from each other, each represent a bidentate ligand; m represents an integer of 1 to 3 and n represents an integer of 0 to 2, provided that m+n is 3; a partial structure ML.sub.m represents a structure represented by the following general formula (2): ##STR00001##
and a partial structure ML.sub.n represents a structure including a monovalent bidentate ligand.

Compounds of formula I and formula II

##STR00001##

their intermediates, as well as processes for the preparation of compounds of formula I and formula II, are disclosed. Use of compounds of formula I for the production of compounds of formula VI

##STR00002##

is also disclosed. Additionally, the use of compounds of formula I or formula II for the production of active compounds is disclosed.

The present invention discloses an iron-based nitrogen doped graphene catalyst, process for preparation thereof and use of said catalyst in oxidant-free catalytic dehydrogenation of alcohols and amines to the corresponding carbonyl compounds, amines and N-heterocylic compounds with extraction of molecular hydrogen as the only by-product.

The present invention discloses an iron-based nitrogen doped graphene catalyst, process for preparation thereof and use of said catalyst in oxidant-free catalytic dehydrogenation of alcohols and amines to the corresponding carbonyl compounds, amines and N-heterocylic compounds with extraction of molecular hydrogen as the only by-product.

Compounds which directly inhibit IRE-1 activity in vitro, prodrugs, and pharmaceutically acceptable salts thereof. Such compounds and prodrugs are useful for treating diseases associated with the unfolded protein response and can be used as single agents or in combination therapies.

Methods for the synthesis and use of functionalized, substituted naphthalenes are described. The functionalized, substituted naphthalenes display useful properties including liquid crystals and fluorescence properties, such as solvatochromatic fluorescence, with high quantum yields, Stoke's shift, and show emission maxima that are significantly red-shifted.

.sup.18F-labeled 4-boronophenylalanine (BPA) can be produced by preparing and further processing a precursor of .sup.18F-labeled BPA represented by the following formula: ##STR00001##
in which R.sup.1 represents a bromo group, an iodo group, a fluoro group, a diazaborinane derivative, BX3.sup. or BX3.sup.M.sup.+ (wherein X represents a halogen atom; and M.sup.+ represents a monovalent monoatomic cation, a polyatomic cation or a complex cation).

.sup.18F-labeled 4-boronophenylalanine (BPA) can be produced by preparing and further processing a precursor of .sup.18F-labeled BPA represented by the following formula: ##STR00001##
in which R.sup.1 represents a bromo group, an iodo group, a fluoro group, a diazaborinane derivative, BX3.sup. or BX3.sup.M.sup.+ (wherein X represents a halogen atom; and M.sup.+ represents a monovalent monoatomic cation, a polyatomic cation or a complex cation).