The disclosure provides methods for the production of liquefied petroleum gas from sustainable feedstocks, including methods comprising conversion of alcohols produced by gas fermentation for the production of propane and/or butane.

A method produces acetic acid and includes a reaction step, a first purification step, a second purification step, and a third purification step. In the reaction step, a material mixture including methanol, carbon monoxide, a catalyst, and an iodide is subjected to a methanol carbonylation reaction in a reactor (1) to form acetic acid. In the first purification step, a crude acetic acid stream including acetic acid formed in the reaction step is subjected to distillation in a distillation column (3) to give a first acetic acid stream enriched with acetic acid. In the second purification step, the first acetic acid stream is subjected to distillation in a distillation column (5) to give a second acetic acid stream further enriched with acetic acid. In the third purification step, an acetic acid stream is subjected to purification in an additional purification unit (e.g., a distillation column (6)) while controlling the corrosive iodine concentration in the acetic acid stream passing through the unit to 100 ppm or less, to give a third acetic acid stream still further enriched with acetic acid. The method for producing acetic acid is suitable for restraining corrosion of the acetic acid production equipment.

A method produces acetic acid and includes a reaction step, a first purification step, a second purification step, and a third purification step. In the reaction step, a material mixture including methanol, carbon monoxide, a catalyst, and an iodide is subjected to a methanol carbonylation reaction in a reactor (1) to form acetic acid. In the first purification step, a crude acetic acid stream including acetic acid formed in the reaction step is subjected to distillation in a distillation column (3) to give a first acetic acid stream enriched with acetic acid. In the second purification step, the first acetic acid stream is subjected to distillation in a distillation column (5) to give a second acetic acid stream further enriched with acetic acid. In the third purification step, an acetic acid stream is subjected to purification in an additional purification unit (e.g., a distillation column (6)) while controlling the corrosive iodine concentration in the acetic acid stream passing through the unit to 100 ppm or less, to give a third acetic acid stream still further enriched with acetic acid. The method for producing acetic acid is suitable for restraining corrosion of the acetic acid production equipment.

A method produces acetic acid and includes a reaction step, a first purification step, a second purification step, and a third purification step. In the reaction step, a material mixture including methanol, carbon monoxide, a catalyst, and an iodide is subjected to a methanol carbonylation reaction in a reactor (1) to form acetic acid. In the first purification step, a crude acetic acid stream including acetic acid formed in the reaction step is subjected to distillation in a distillation column (3) to give a first acetic acid stream enriched with acetic acid. In the second purification step, the first acetic acid stream is subjected to distillation in a distillation column (5) to give a second acetic acid stream further enriched with acetic acid. In the third purification step, an acetic acid stream is subjected to purification in an additional purification unit (e.g., a distillation column (6)) while controlling the corrosive iodine concentration in the acetic acid stream passing through the unit to 100 ppm or less, to give a third acetic acid stream still further enriched with acetic acid. The method for producing acetic acid is suitable for restraining corrosion of the acetic acid production equipment.

This invention relates to a catalyst used in a carbonylation of methanol using carbon monoxide to acetic acid, and more particularly to a heterogeneous catalyst represented by Rh/WxC (where x is an integer of 1 or 2) in which a complex of a rhodium compound and 3-benzoylpyridine is fixed on a support of tungsten carbide.

This invention relates to a catalyst used in a carbonylation of methanol using carbon monoxide to acetic acid, and more particularly to a heterogeneous catalyst represented by Rh/WxC (where x is an integer of 1 or 2) in which a complex of a rhodium compound and 3-benzoylpyridine is fixed on a support of tungsten carbide.

This invention relates to a catalyst used in a carbonylation of methanol using carbon monoxide to acetic acid, and more particularly to a heterogeneous catalyst represented by Rh/WxC (where x is an integer of 1 or 2) in which a complex of a rhodium compound and 3-benzoylpyridine is fixed on a support of tungsten carbide.

Recycled content triacetin (r-triacetin) is produced using a process and system that applies physical and/or credit-based recycled content from one or more feed materials to triacetin produced from the feed materials.

Recycled content triacetin (r-triacetin) is produced using a process and system that applies physical and/or credit-based recycled content from one or more feed materials to triacetin produced from the feed materials.

The present disclosure relates to methods of removing halides from a reactor effluent comprising treating the halide containing carbonylation product with a resin or material comprising a metal ion with a metal loading of greater than 15 wt % are provided herein. In some aspects, the methods involve treating the halide containing carbonylation product with a silver loaded resin which comprises a loading of greater than 15 wt % of silver to remove inorganic or organic halides.