This invention relates to the field of contaminated plastic waste decomposition. More specifically, the invention comprises methods and systems to decompose contaminated plastic waste and transform it into value-added products.

A method for producing adipic acid and cyclohexanone oxime from cyclohexane is provided. Cyclohexane and NO.sub.x undergo oxidation-nitration reaction to produce a mixture of adipic acid, nitrocyclohexane, nitrogen oxides and by-product A, from which adipic acid and nitrocyclohexane are separated. The nitrocyclohexane is catalytically hydrogenated with hydrogen to produce cyclohexanone oxime and a small amount of cyclohexylamine, where cyclohexanone oxime is collected, and the cyclohexylamine is partially oxidized with molecular oxygen to obtain cyclohexanone oxime and by-product B. Without separation, or after removing part or all of water from the reaction mixture, under the action of a catalyst, the reaction mixture undergoes hydrogenation and amination simultaneously or sequentially, or the hydrogenation alone, and separation to give cyclohexanone oxime.

Digestion of impure alumina with sulfuric acid dissolves all constituents except silica. The resulting sulfatesaluminum sulfate, ferric sulfate, titanyl sulfate, and magnesium sulfate for alumina contaminated with iron-, titanium-, and/or magnesium-containing speciesremain in solution at approximately 90 C. Hot filtration separates silica. Solution flow over metallic iron reduces ferric sulfate to ferrous sulfate. Controlled ammonia addition promotes hydrolysis and precipitation of hydrated titania from titanyl sulfate that is removed by filtration. Addition of ammonium sulfate forms ferrous ammonium sulfate and ammonium aluminum sulfate solutions. Alum is preferentially separated by crystallization. Addition of ammonium bicarbonate to an ammonium alum solution precipitates ammonium aluminum carbonate which may be heated to produce alumina, ammonia, and carbon dioxide. The remaining iron rich liquor also contains magnesium sulfate. The addition of oxalic acid generates insoluble ferrous oxalate which is thermally decomposed to ferrous oxide and carbon monoxide which is used to reduce the ferrous oxide to metallic iron. Further oxalic acid addition precipitates magnesium oxalate which is thermally decomposed to magnesium oxide.

The present invention relates to a novel process for manufacturing a sugar acid for the use in the agricultural market as an adjuvant wherein the process includes the following steps of providing a reactor and introducing a source of nitric acid, water and a source of starch into the reactor to form a mixture and further includes introducing an external heat source to the mixture to ascertain a mixture temperature of at least 70? C. and discontinuing the external heat source once the mixture reaches about 70? C.; and further enabling an internal heat source in the form of an exothermic reaction to occur between the reagents for at least two (2) hours. The invention also relates to the use of the product as obtained from the process.

The present invention relates to a novel process for manufacturing a sugar acid for the use in the agricultural market as an adjuvant wherein the process includes the following steps of providing a reactor and introducing a source of nitric acid, water and a source of starch into the reactor to form a mixture and further includes introducing an external heat source to the mixture to ascertain a mixture temperature of at least 70? C. and discontinuing the external heat source once the mixture reaches about 70? C.; and further enabling an internal heat source in the form of an exothermic reaction to occur between the reagents for at least two (2) hours. The invention also relates to the use of the product as obtained from the process.

Described are methods for preparing phenols, benzene carboxylic acids, esters and anhydrides thereof from furanic compounds by reaction with a dienophile, wherein the furanic compounds are reacted with a hydrazine and/or oxime and then reacted with a dienophile.

Described are methods for preparing phenols, benzene carboxylic acids, esters and anhydrides thereof from furanic compounds by reaction with a dienophile, wherein the furanic compounds are reacted with a hydrazine and/or oxime and then reacted with a dienophile.

Described are methods for preparing phenols, benzene carboxylic acids, esters and anhydrides thereof from furanic compounds by reaction with a dienophile, wherein the furanic compounds are reacted with a hydrazine and/or oxime and then reacted with a dienophile.

A method of catalytic oxidation of a lignite using oxygen as an oxidant at atmospheric pressure is provided. The method includes the following steps, pulverizing the lignite to 200-mesh or less; drying the pulverized lignite at a temperature of 80 C. in vacuum for 10 h; weighing 0.5 g of the dried lignite and sequentially adding 10 ml of acetic acid, 0.5 mmol of a catalyst and 0.15-0.25 mmol of a cocatalyst into a round-bottom flask filled with the oxygen, keeping oxygen pressure at 0.1 MPa, reacting at a temperature of 80-120 C. for 4-12 h; using oxygen as the oxidant to catalytically oxidize the reacted lignite at an atmospheric pressure of 0.1 MPa; filtering after the reaction is finished; decompressing the filtrate to remove the acetic acid, adding a small amount of ethyl acetate to dissolve, and using an excess CH.sub.2N.sub.2/ether solution to esterify for 10 h at room temperature; and analyzing the esterified product through a gas chromatography-mass spectrometer.

A method of catalytic oxidation of a lignite using oxygen as an oxidant at atmospheric pressure is provided. The method includes the following steps, pulverizing the lignite to 200-mesh or less; drying the pulverized lignite at a temperature of 80 C. in vacuum for 10 h; weighing 0.5 g of the dried lignite and sequentially adding 10 ml of acetic acid, 0.5 mmol of a catalyst and 0.15-0.25 mmol of a cocatalyst into a round-bottom flask filled with the oxygen, keeping oxygen pressure at 0.1 MPa, reacting at a temperature of 80-120 C. for 4-12 h; using oxygen as the oxidant to catalytically oxidize the reacted lignite at an atmospheric pressure of 0.1 MPa; filtering after the reaction is finished; decompressing the filtrate to remove the acetic acid, adding a small amount of ethyl acetate to dissolve, and using an excess CH.sub.2N.sub.2/ether solution to esterify for 10 h at room temperature; and analyzing the esterified product through a gas chromatography-mass spectrometer.