Patent classifications
C07C51/377
Oxidation catalysts
Disclosed are catalysts comprised of platinum and gold. The catalysts are generally useful for the selective oxidation of compositions comprised of a primary alcohol group and at least one secondary alcohol group wherein at least the primary alcohol group is converted to a carboxyl group. More particularly, the catalysts are supported catalysts including particles comprising gold and particles comprising platinum, wherein the molar ratio of platinum to gold is in the range of about 100:1 to about 1:4, the platinum is essentially present as Pt(0) and the platinum-containing particles are of a size in the range of about 2 to about 50 nm. Also disclosed are methods for the oxidative chemocatalytic conversion of carbohydrates to carboxylic acids or derivatives thereof. Additionally, methods are disclosed for the selective oxidation of glucose to glucaric acid or derivatives thereof using catalysts comprising platinum and gold. Further, methods are disclosed for the production of such catalysts.
PROCESS FOR PRODUCING ACRYLIC ACID
Provided is a process for producing acrylic acid, the process including supplying a lactic acid raw material to an upper portion of a distillation tower; supplying water to a lower portion of the distillation tower; supplying a first lactic acid vapor vaporized in the distillation tower to a reactor; and supplying a second aqueous lactic acid solution not vaporized in the distillation tower to a middle portion of the distillation tower. The process uses a distillation tower instead of a vaporizer, and is capable of preventing formation of a lactic acid oligomer during vaporization of an aqueous lactic acid solution, and, by introducing a concentrated lactic acid raw material to the distillation tower as it is, is capable of producing acrylic acid without a separate dilution device.
PROCESS FOR PRODUCING ACRYLIC ACID
Provided is a process for producing acrylic acid, the process including supplying a lactic acid raw material to an upper portion of a distillation tower; supplying water to a lower portion of the distillation tower; supplying a first lactic acid vapor vaporized in the distillation tower to a reactor; and supplying a second aqueous lactic acid solution not vaporized in the distillation tower to a middle portion of the distillation tower. The process uses a distillation tower instead of a vaporizer, and is capable of preventing formation of a lactic acid oligomer during vaporization of an aqueous lactic acid solution, and, by introducing a concentrated lactic acid raw material to the distillation tower as it is, is capable of producing acrylic acid without a separate dilution device.
PROCESS FOR PRODUCING ACRYLIC ACID
Provided is a process for producing acrylic acid, the process including supplying a lactic acid raw material to an upper portion of a distillation tower; supplying water to a lower portion of the distillation tower; supplying a first lactic acid vapor vaporized in the distillation tower to a reactor; and supplying a second aqueous lactic acid solution not vaporized in the distillation tower to a middle portion of the distillation tower. The process uses a distillation tower instead of a vaporizer, and is capable of preventing formation of a lactic acid oligomer during vaporization of an aqueous lactic acid solution, and, by introducing a concentrated lactic acid raw material to the distillation tower as it is, is capable of producing acrylic acid without a separate dilution device.
METHOD FOR PRODUCING CATALYST FOR DEHYDROGENATION OF 3-HYDROXYPROPIONIC ACID, CATALYST FOR DEHYDROGENATION OF 3-HYDROXYPROPIONIC ACID, AND METHOD FOR PRODUCING ACRYLIC ACID USING SAME
A method for preparing a catalyst for a dehydration reaction of 3-hydroxypropionic acid, the catalyst for dehydration reaction of 3-hydroxypropionic acid, and a method for producing acrylic acid using the same.
METHOD FOR PRODUCING CATALYST FOR DEHYDROGENATION OF 3-HYDROXYPROPIONIC ACID, CATALYST FOR DEHYDROGENATION OF 3-HYDROXYPROPIONIC ACID, AND METHOD FOR PRODUCING ACRYLIC ACID USING SAME
A method for preparing a catalyst for a dehydration reaction of 3-hydroxypropionic acid, the catalyst for dehydration reaction of 3-hydroxypropionic acid, and a method for producing acrylic acid using the same.
METHOD FOR PRODUCING CATALYST FOR DEHYDROGENATION OF 3-HYDROXYPROPIONIC ACID, CATALYST FOR DEHYDROGENATION OF 3-HYDROXYPROPIONIC ACID, AND METHOD FOR PRODUCING ACRYLIC ACID USING SAME
A method for preparing a catalyst for a dehydration reaction of 3-hydroxypropionic acid, the catalyst for dehydration reaction of 3-hydroxypropionic acid, and a method for producing acrylic acid using the same.
Renewable acrylic acid production and products made therefrom
Processes and methods for making biobased acrylic acid products including acrylic acid, acrylic acid oligomers, acrylic acid esters, acrylic acid polymers and articles from renewable carbon resources are described herein.
Renewable acrylic acid production and products made therefrom
Processes and methods for making biobased acrylic acid products including acrylic acid, acrylic acid oligomers, acrylic acid esters, acrylic acid polymers and articles from renewable carbon resources are described herein.
Recombinant Host Cells For The Production Of 3-Hydroxypropionic Acid
Provided herein are recombinant host cells having an active 3-Hydroxypropionic Acid (3-HP) pathway wherein the host cells comprise a heterologous polynucleotide encoding a 3-hydroxypropionate dehydrogenase (3-HPDH). Also described are methods of using the recombinant cells to produce 3-HP and derivatives of 3-HP (e.g., acrylic acid).