Patent classifications
C07C51/50
Method for inhibiting unwanted radical polymerisation of acrylic acid present in a liquid phase P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with furfural in an amount that results in a furfural content in the range from 25 to 1000 ppmw based on the weight of the acrylic acid present in P. Liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 25 to 1000 ppmw of furfural in each case based on the weight of the acrylic acid present in P.
Method for inhibiting unwanted radical polymerisation of acrylic acid present in a liquid phase P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with furfural in an amount that results in a furfural content in the range from 25 to 1000 ppmw based on the weight of the acrylic acid present in P. Liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 25 to 1000 ppmw of furfural in each case based on the weight of the acrylic acid present in P.
Method of recovering organic acids from aqueous solutions
A method of recovering an organic acid from an aqueous solution may include extracting the organic acid dissolved in the aqueous solution into a water immiscible extraction phase. The water immiscible extraction phase has an extractant for the organic acid. The method may also include separating the extraction phase from the aqueous solution, adding an alcohol to the extraction phase separated from the aqueous solution, and forming an ester from the organic acid and the alcohol.
Method of recovering organic acids from aqueous solutions
A method of recovering an organic acid from an aqueous solution may include extracting the organic acid dissolved in the aqueous solution into a water immiscible extraction phase. The water immiscible extraction phase has an extractant for the organic acid. The method may also include separating the extraction phase from the aqueous solution, adding an alcohol to the extraction phase separated from the aqueous solution, and forming an ester from the organic acid and the alcohol.
METHODS AND SYSTEMS FOR PRODUCING ACETIC ACID
Methods and systems for producing acetic acid, including glacial acetic acid. A first stream of a reactor fluid that includes methyl acetate, water, and a first amount of carbon monoxide may be forwarded from a reactor to a reactor cooler to form a cooled reactor fluid. The cooled reactor fluid may have a concentration of methyl acetate that is lower than the concentration of methyl acetate in the reactor fluid.
METHODS AND SYSTEMS FOR PRODUCING ACETIC ACID
Methods and systems for producing acetic acid, including glacial acetic acid. A first stream of a reactor fluid that includes methyl acetate, water, and a first amount of carbon monoxide may be forwarded from a reactor to a reactor cooler to form a cooled reactor fluid. The cooled reactor fluid may have a concentration of methyl acetate that is lower than the concentration of methyl acetate in the reactor fluid.
METHOD FOR SEPARATING TRANS ISOMERIC CROCETIN FROM CIS ISOMERIC CROCETIN
A method for separating trans isomer crocetin from cis isomer crocetin is provided. The method comprises crystallizing all-trans crocetin with calcium ions first by using different binding capabilities between cis and trans isomeric crocetin to calcium ions and acidifying the all-trans crocetin to obtain 13-cis crocetin.
METHOD FOR SEPARATING TRANS ISOMERIC CROCETIN FROM CIS ISOMERIC CROCETIN
A method for separating trans isomer crocetin from cis isomer crocetin is provided. The method comprises crystallizing all-trans crocetin with calcium ions first by using different binding capabilities between cis and trans isomeric crocetin to calcium ions and acidifying the all-trans crocetin to obtain 13-cis crocetin.
METHOD FOR INHIBITING UNWANTED RADICAL POLYMERISATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with furfural in an amount that results in a furfural content in the range from 25 to 1000 ppmw based on the weight of the acrylic acid present in P. Liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 25 to 1000 ppmw of furfural in each case based on the weight of the acrylic acid present in P.
METHOD FOR INHIBITING UNWANTED RADICAL POLYMERISATION OF ACRYLIC ACID PRESENT IN A LIQUID PHASE P
Process for inhibiting the undesired free-radical polymerization of acrylic acid present in a liquid phase P, wherein the acrylic acid content of P is at least 10% by weight, the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal based on the weight of the acrylic acid present in P and the liquid phase P is admixed with furfural in an amount that results in a furfural content in the range from 25 to 1000 ppmw based on the weight of the acrylic acid present in P. Liquid phase P, wherein the acrylic acid content of P is at least 10% by weight and the liquid phase P comprises in the range from 25 to 1000 ppmw of glyoxal and in the range from 25 to 1000 ppmw of furfural in each case based on the weight of the acrylic acid present in P.