Nitrogen heterocyclic carbine ligands and ruthenium catalysts thereof, a preparation method therefor and an application thereof are provided. The structures of the nitrogen heterocyclic carbine ligands are represented by formulas Ia and Ib, respectively, and the corresponding ruthenium catalyst structures are represented by IIa and IIb, respectively. After simultaneously introducing large-steric hindrance and electron-rich groups into the described nitrogen heterocyclic carbine ligand structures, the catalytic activity, stability and application range of the ruthenium complex catalysts thereof are significantly improved.

##STR00001##

The present disclosure provides compositions and methods for metathesizing a first alkenyl or alkynyl group with a second alkenyl or alkynyl group, the composition comprising a ruthenium metathesis catalyst and a photo-redox catalyst that is activated by infrared light.

The present disclosure provides compositions and methods for metathesizing a first alkenyl or alkynyl group with a second alkenyl or alkynyl group, the composition comprising a ruthenium metathesis catalyst and a photo-redox catalyst that is activated by infrared light.

The invention relates to a process (100) for the recycling of an article based on (meth)acrylic thermoplastic polymer resin, characterized in that it comprises the following steps: introduction (110) of the article into a system suitable for the recycling of thermoplastic polymer, at least partial depolymerization (130) of the (meth)acrylic thermoplastic polymer resin so as to form (meth)acrylate monomers, introduction (140) of a hydrolysis catalyst into a hydrolysis reactor, introduction (150) of water into said hydrolysis reactor, and conversion (160), in the hydrolysis reactor, of at least part of the (meth)acrylate monomers into (meth)acrylic acid. The invention also relates to a system for recycling an article based on (meth)acrylic thermoplastic polymer resin.

The invention relates to a process (100) for the recycling of an article based on (meth)acrylic thermoplastic polymer resin, characterized in that it comprises the following steps: introduction (110) of the article into a system suitable for the recycling of thermoplastic polymer, at least partial depolymerization (130) of the (meth)acrylic thermoplastic polymer resin so as to form (meth)acrylate monomers, introduction (140) of a hydrolysis catalyst into a hydrolysis reactor, introduction (150) of water into said hydrolysis reactor, and conversion (160), in the hydrolysis reactor, of at least part of the (meth)acrylate monomers into (meth)acrylic acid. The invention also relates to a system for recycling an article based on (meth)acrylic thermoplastic polymer resin.

The invention relates to a process (100) for the recycling of an article based on (meth)acrylic thermoplastic polymer resin, characterized in that it comprises the following steps: introduction (110) of the article into a system suitable for the recycling of thermoplastic polymer, at least partial depolymerization (130) of the (meth)acrylic thermoplastic polymer resin so as to form (meth)acrylate monomers, introduction (140) of a hydrolysis catalyst into a hydrolysis reactor, introduction (150) of water into said hydrolysis reactor, and conversion (160), in the hydrolysis reactor, of at least part of the (meth)acrylate monomers into (meth)acrylic acid. The invention also relates to a system for recycling an article based on (meth)acrylic thermoplastic polymer resin.

The present invention relates to a novel and improved process for preparing (3S)-3-(4-chloro-3-{[(2S,3R)-2-(4-chlorophenyl)-4,4,4-trifluoro-3-methylbutanoyl]amino}phenyl)-3-cyclopropylpropanoic acid of the formula (I), to the compound of the formula (I) in crystalline form and to their use for the treatment and/or prevention of diseases, in particular for the treatment and/or prevention of cardiovascular, cardiopulmonary and cardiorenal disorders.

The present disclosure provides compositions and methods for metathesizing a first alkenyl or alkynyl group with a second alkenyl or alkynyl group, the composition comprising a ruthenium metathesis catalyst and a photoredox catalyst that is activated by visible light.

The present disclosure provides compositions and methods for metathesizing a first alkenyl or alkynyl group with a second alkenyl or alkynyl group, the composition comprising a ruthenium metathesis catalyst and a photoredox catalyst that is activated by visible light.

The disclosure is directed to improved methods for preparing substituted quinolinylcyclohexylpropanamide compounds.