C07C67/62

Methods for manufacturing and decolorizing dioctyl terephthalate

A method for manufacturing and a method for decolorizing dioctyl terephthalate are provided. The decolorizing dioctyl terephthalate includes: providing an unpurified dioctyl terephthalate; mixing the unpurified dioctyl terephthalate with a reducing agent and an adsorption medium to obtain a first decolorizing product; and mixing the first decolorizing product with a decolorizing adsorbent material to obtain a second decolorizing product. The method for manufacturing dioctyl terephthalate includes: a transesterification step, an alkaline washing and neutralization step, a redox step, a decolorization step and a stripping step; the decolorizing adsorbent material has an acid value between 0.1 and 2 mg KOH/g, a relative humidity between 2 and 10%, and a fineness between 80 and 100 cm.sup.2/g.

Methods for producing (meth)acrylic acid norbornyl esters

A method for preparing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as catalyst, wherein a) boron trifluoride is initially charged in (meth)acrylic acid or an organic solvent, b) the initial charge is heated to a temperature of 75 to 110° C., c) norbornene is added or a mixture comprising norbornene and (meth)acrylic acid is added and d) the norbornyl (meth)acrylate obtained is isolated from the reaction mixture.

Methods for producing (meth)acrylic acid norbornyl esters

A method for preparing norbornyl (meth)acrylate by reacting norbornene with (meth)acrylic acid in the presence of boron trifluoride as catalyst, wherein a) boron trifluoride is initially charged in (meth)acrylic acid or an organic solvent, b) the initial charge is heated to a temperature of 75 to 110° C., c) norbornene is added or a mixture comprising norbornene and (meth)acrylic acid is added and d) the norbornyl (meth)acrylate obtained is isolated from the reaction mixture.

System for continuously purifying reaction product of esterification

The present disclosure relates to a system and a method for continuously purifying a reaction product of esterification, where the system includes a neutralizer, a distiller, and a product purifier. Through the present system and the method, it is possible to perform a continuous purification process efficiently, and to reduce lower alcohol wastewater generated during purification.

System for continuously purifying reaction product of esterification

The present disclosure relates to a system and a method for continuously purifying a reaction product of esterification, where the system includes a neutralizer, a distiller, and a product purifier. Through the present system and the method, it is possible to perform a continuous purification process efficiently, and to reduce lower alcohol wastewater generated during purification.

Method for producing α-fluoro acrylic acid ester, and composition containing highly-pure fluorocyclopropane derivative, and composition containing highly-pure α-fluoro acrylic acid ester

The present invention provides a production method of α-fluoroacrylate ester, a composition containing a highly-pure fluorocyclopropane derivative and a composition containing highly-pure α-fluoroacrylate ester. The present invention relates to a method of producing a compound represented by the following formula (F), including subjecting a composition containing a compound represented by the following formula (A) to a purification treatment in the order of distillation and washing with an aqueous alkali solution to give a purified product containing a compound represented by the following formula (A), and subjecting the purified product to a thermal decomposition reaction, a composition containing a highly-pure compound represented by the following formula (A), and a composition containing a highly-pure compound represented by the following formula (F), wherein R may be the same or different and is a monovalent hydrocarbon group, and X is a halogen atom: ##STR00001##

Method for producing α-fluoro acrylic acid ester, and composition containing highly-pure fluorocyclopropane derivative, and composition containing highly-pure α-fluoro acrylic acid ester

The present invention provides a production method of α-fluoroacrylate ester, a composition containing a highly-pure fluorocyclopropane derivative and a composition containing highly-pure α-fluoroacrylate ester. The present invention relates to a method of producing a compound represented by the following formula (F), including subjecting a composition containing a compound represented by the following formula (A) to a purification treatment in the order of distillation and washing with an aqueous alkali solution to give a purified product containing a compound represented by the following formula (A), and subjecting the purified product to a thermal decomposition reaction, a composition containing a highly-pure compound represented by the following formula (A), and a composition containing a highly-pure compound represented by the following formula (F), wherein R may be the same or different and is a monovalent hydrocarbon group, and X is a halogen atom: ##STR00001##

METHODS FOR MANUFACTURING AND DECOLORIZING DIOCTYL TEREPHTHALATE
20210122699 · 2021-04-29 ·

A method for manufacturing and a method for decolorizing dioctyl terephthalate are provided. The decolorizing dioctyl terephthalate includes: providing an unpurified dioctyl terephthalate; mixing the unpurified dioctyl terephthalate with a reducing agent and an adsorption medium to obtain a first decolorizing product; and mixing the first decolorizing product with a decolorizing adsorbent material to obtain a second decolorizing product. The method for manufacturing dioctyl terephthalate includes: a transesterification step, an alkaline washing and neutralization step, a redox step, a decolorization step and a stripping step; the decolorizing adsorbent material has an acid value between 0.1 and 2 mg KOH/g, a relative humidity between 2 and 10%, and a fineness between 80 and 100 cm.sup.2 /g.

METHODS FOR MANUFACTURING AND DECOLORIZING DIOCTYL TEREPHTHALATE
20210122699 · 2021-04-29 ·

A method for manufacturing and a method for decolorizing dioctyl terephthalate are provided. The decolorizing dioctyl terephthalate includes: providing an unpurified dioctyl terephthalate; mixing the unpurified dioctyl terephthalate with a reducing agent and an adsorption medium to obtain a first decolorizing product; and mixing the first decolorizing product with a decolorizing adsorbent material to obtain a second decolorizing product. The method for manufacturing dioctyl terephthalate includes: a transesterification step, an alkaline washing and neutralization step, a redox step, a decolorization step and a stripping step; the decolorizing adsorbent material has an acid value between 0.1 and 2 mg KOH/g, a relative humidity between 2 and 10%, and a fineness between 80 and 100 cm.sup.2 /g.

ORGANIC REACTIONS CARRIED OUT IN AQUEOUS SOLUTION IN THE PRESENCE OF A HYDROXYALKYL(ALKYL)CELLULOSE OR AN ALKYLCELLULOSE

The present invention relates to a method of carrying out an organic reaction in aqueous solution in the presence of a hydroxyalkyl(alkyl)cellulose or an alkylcellulose.