Patent classifications
C07C69/73
Living radical polymerization initiator, method for producing polymer, and polymer
A living radical polymerization initiator represented by the following: ##STR00001##
wherein, R.sup.1 represents an aromatic, an alkylcarbonyl, an alkoxycarbonyl, an aminocarbonyl, an alkylaminocarbonyl, a dialkylaminocarbonyl, an arylcarbonyl, an alkylsulfonyl, an aryl sulfonyl or combinations thereof; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are a hydrogen, an aliphatic, an aromatic, an alkylcarbonyl, an alkoxycarbonyl, an aminocarbonyl, an alkylaminocarbonyl, a dialkylaminocarbonyl, an arylcarbonyl, a carboxy, an alkylsulfonyl or an aryl sulfonyl; X and Y are a halogen; m and n are an integer of 1 or more, and ##STR00002## are non-symmetrical so that X and Y have different reactivities to initiate a living radical polymerization.
Living radical polymerization initiator, method for producing polymer, and polymer
A living radical polymerization initiator represented by the following: ##STR00001##
wherein, R.sup.1 represents an aromatic, an alkylcarbonyl, an alkoxycarbonyl, an aminocarbonyl, an alkylaminocarbonyl, a dialkylaminocarbonyl, an arylcarbonyl, an alkylsulfonyl, an aryl sulfonyl or combinations thereof; R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are a hydrogen, an aliphatic, an aromatic, an alkylcarbonyl, an alkoxycarbonyl, an aminocarbonyl, an alkylaminocarbonyl, a dialkylaminocarbonyl, an arylcarbonyl, a carboxy, an alkylsulfonyl or an aryl sulfonyl; X and Y are a halogen; m and n are an integer of 1 or more, and ##STR00002## are non-symmetrical so that X and Y have different reactivities to initiate a living radical polymerization.
Optical element compound, optical material, and optical element
An optical material organic compound having characteristics that the dispersion characteristic (Abbe number (.sub.d)) and the secondary dispersion characteristic (g,F) of the refractive index are high, the transmittance in the visible light region is high, and the chromatic aberration correction function delivers high performance, which represented by the general formula (1) or (2) is provided.
Optical element compound, optical material, and optical element
An optical material organic compound having characteristics that the dispersion characteristic (Abbe number (.sub.d)) and the secondary dispersion characteristic (g,F) of the refractive index are high, the transmittance in the visible light region is high, and the chromatic aberration correction function delivers high performance, which represented by the general formula (1) or (2) is provided.
A COMPOSITION AND A PROCESS FOR A PREPARATION OF POLYURETHANE DISPERSION (AS AMENDED)
This invention relates to a composition for a preparation of polyurethane dispersion, comprising bio-based polyol as shown in structure (I) and polyhydroxy fatty acid compound as shown in structure (II): wherein, R represents a polyhydric alcohol unit that is selected from aliphatic polyhydric alcohol, alicyclic polyhydric alcohol, cyclic polyhydric alcohol, aromatic polyhydric alcohol, or optionally, cyclic polyhydroxyl having heteroatom; R\ represents a hydrocarbon unit obtained from a molecular chain of unsaturated fatty acid having 14-24 carbon atoms and having from 1-6 pairs of vicinal diol group per one molecular chain of such unsaturated fatty acid; n represents an integer from 2 to 8 of an ester group obtained from a reaction of polyhydric alcohol and unsaturated fatty acid; wherein said composition is prepared from a process comprising the steps of: i. mixing fatty acid comprising unsaturated fatty acid and polyhydric alcohol at a ratio of 1 mole equivalent or more of carboxylic group from unsaturated fatty acid per a hydroxy group from polyhydric alcohol; ii. adding organic acid and peroxide compound into the mixture from step i.; iii. adding nucleophilic substance into the mixture from step ii. under acidic condition.
##STR00001##
ISOBUTYRIC ACID ESTER COMPOUND HAVING ALKENOYLOXY GROUP AT ALPHA-POSITION, PERFUME COMPOSITION, AND USE AS PERFUME
A fragrance composition contains a compound represented by Formula (1) below as an active ingredient: where, in Formula (1), R.sup.1 is a linear or branched olefinically unsaturated hydrocarbon group having from 2 to 4 carbons, and R.sup.2 is a linear, branched, or cyclic alkyl group having from 1 to 6 carbons.
##STR00001##
ISOBUTYRIC ACID ESTER COMPOUND HAVING ALKENOYLOXY GROUP AT ALPHA-POSITION, PERFUME COMPOSITION, AND USE AS PERFUME
A fragrance composition contains a compound represented by Formula (1) below as an active ingredient: where, in Formula (1), R.sup.1 is a linear or branched olefinically unsaturated hydrocarbon group having from 2 to 4 carbons, and R.sup.2 is a linear, branched, or cyclic alkyl group having from 1 to 6 carbons.
##STR00001##
METHODS FOR DETECTING AND DETERMINING LEVELS OF MONOLIGNOL ESTER CONJUGATES INCORPORATED INTO LIGNIN AND COMPOUNDS RELATING THERETO
Described is a method of detecting and/or determining levels of incorporation of monolignol ferulate conjugate esters into lignin by derivatizing the lignin, reductively cleaving the lignin, labeling the cleavage products, and then detecting cleavage products derived from monolignol ester conjugates via differential attachment of the label.
METHODS FOR DETECTING AND DETERMINING LEVELS OF MONOLIGNOL ESTER CONJUGATES INCORPORATED INTO LIGNIN AND COMPOUNDS RELATING THERETO
Described is a method of detecting and/or determining levels of incorporation of monolignol ferulate conjugate esters into lignin by derivatizing the lignin, reductively cleaving the lignin, labeling the cleavage products, and then detecting cleavage products derived from monolignol ester conjugates via differential attachment of the label.
POLYMERIZABLE COMPOUND AND LIQUID CRYSTAL COMPOSITION CONTAINING THE SAME
The present invention provides an improved adhesion when a polymerizable liquid crystal composition is applied to a film substrate and cured, improved storage stability of the composition when the composition is used in a PSA display device, and a liquid crystal display device having improved display characteristics. The polymerizable compound is represented by general formula (I). The invention provides an optically anisotropic film using the polymerizable compound, and a liquid crystal display device using the polymerizable compound.
##STR00001##