Patent classifications
C07C69/75
Method and apparatus for producing fluorine-containing organic compound
Provided is a method for producing a fluorine-containing organic compound. The method can immediately detect the occurrence of a side reaction in direct fluorination reaction using fluorine gas and can give a highly pure fluorine-containing organic compound at a high yield. A raw material liquid (1) containing a raw material organic compound having a hydrogen atom and two or more carbon atoms is reacted with fluorine gas in a reaction container (11) to replace the hydrogen atom of the raw material organic compound with a fluorine atom to give a fluorine-containing organic compound. In the reaction, tetrafluoromethane contained in a gas phase (2) in the reaction container (11) is continuously measured, and the amount of the fluorine gas supplied to the reaction container (11) is controlled depending on the measured value of the tetrafluoromethane.
Method for producing ester group-containing compound
The present invention provides a novel method for producing an ester group-containing compound and a derivative produced using the compound as a synthetic intermediate. The invention also provides a polymerizable composition containing the compound obtained by the production method and a film-shaped polymer obtained by polymerizing the polymerizable composition. The present invention is a method for producing an ester group-containing compound, the method including a mixing step of mixing a condensing agent, a Bronsted acid, a carboxylic acid, and a phenol or an alcohol to prepare a reaction mixture. The Bronsted acid selected is other than the condensing agent, the carboxylic acid, and the phenol.
Method for producing ester group-containing compound
The present invention provides a novel method for producing an ester group-containing compound and a derivative produced using the compound as a synthetic intermediate. The invention also provides a polymerizable composition containing the compound obtained by the production method and a film-shaped polymer obtained by polymerizing the polymerizable composition. The present invention is a method for producing an ester group-containing compound, the method including a mixing step of mixing a condensing agent, a Bronsted acid, a carboxylic acid, and a phenol or an alcohol to prepare a reaction mixture. The Bronsted acid selected is other than the condensing agent, the carboxylic acid, and the phenol.
PROCESS FOR REGENERATION OF HYDROGENATION CATALYSTS
The invention provides a process for regenerating a catalyst used for the hydrogenation of an aromatic species, consisting of several steps. First the system is purged with nitrogen, then air is metered in stepwise, and the addition of nitrogen is subsequently ended until only air is present.
PROCESS FOR REGENERATION OF HYDROGENATION CATALYSTS
The invention provides a process for regenerating a catalyst used for the hydrogenation of an aromatic species, consisting of several steps. First the system is purged with nitrogen, then air is metered in stepwise, and the addition of nitrogen is subsequently ended until only air is present.
PROCESS FOR REGENERATION OF HYDROGENATION CATALYSTS
The invention provides a process for regenerating a catalyst used for the ring hydrogenation of an aromatic species, especially an aromatic ester, wherein a gas stream containing a particular amount of oxygen is used for the regeneration.
PROCESS FOR REGENERATION OF HYDROGENATION CATALYSTS
The invention provides a process for regenerating a catalyst used for the ring hydrogenation of an aromatic species, especially an aromatic ester, wherein a gas stream containing a particular amount of oxygen is used for the regeneration.
CYCLOHEXANE TRIESTER-BASED PLASTICIZER COMPOSITION AND RESIN COMPOSITION INCLUDING THE SAME
The present disclosure relates to a plasticizer composition characterized in having alkyl groups derived from an isomer mixture of hexyl alcohol with the degree of branching of less than 2.0 as a cyclohexane triester. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties may be maintained to equal or better levels, migration and loss properties and plasticization efficiency may keep balance, and light resistance and heat resistance may be markedly improved.
CYCLOHEXANE TRIESTER-BASED PLASTICIZER COMPOSITION AND RESIN COMPOSITION INCLUDING THE SAME
The present disclosure relates to a plasticizer composition characterized in having alkyl groups derived from an isomer mixture of hexyl alcohol with the degree of branching of less than 2.0 as a cyclohexane triester. When the plasticizer composition is applied to a resin, stress resistance and mechanical properties may be maintained to equal or better levels, migration and loss properties and plasticization efficiency may keep balance, and light resistance and heat resistance may be markedly improved.
CONTINUOUS PRODUCTION METHOD OF DIESTER-BASED MATERIAL
The present disclosure relates to a continuous production method of a diester-based material in a continuous production process comprising a reaction part in which a total of N reaction units from a first reaction unit to an N-th reaction unit are connected in series. The method comprising the step of feeding dicarboxylic acid and a primary alcohol, wherein the feed of the primary alcohol is divided into front-end feed of being fed into a first reaction unit and rear-end feed of being fed into one or more reaction units selected among from a second reaction unit to an N-th reaction unit, wherein the amount of the rear-end feed is 5 to 80 wt % based on the total feed amount of the primary alcohol into a reaction part, and the N is an integer of 3 to 6. According to the present invention, it is possible to ensure the ease of process operation through reducing the amount of reflux compared to a typical batch process and reducing the volume of steam for heating a reactor, and to ensure the economic feasibility of a product through saving energy.