A method of controlling or arresting the rate of depolymerization of a polymer composition during a biocide treatment, and use of such methods in oilfield and industrial applications. Also disclosed are methods of preparing a visco-stable application fluid containing a biocide in an amount effective to reduce bacteria count, as well as additive compositions capable of reducing bacteria count in application fluids while maintaining viscosity in such fluids. Also disclosed are methods of preparing biocide-containing application fluids with improved friction reducing properties, as well as related compositions.

A method of controlling or arresting the rate of depolymerization of a polymer composition during a biocide treatment, and use of such methods in oilfield and industrial applications. Also disclosed are methods of preparing a visco-stable application fluid containing a biocide in an amount effective to reduce bacteria count, as well as additive compositions capable of reducing bacteria count in application fluids while maintaining viscosity in such fluids. Also disclosed are methods of preparing biocide-containing application fluids with improved friction reducing properties, as well as related compositions.

A synergistic composition comprising a THP salt and a biopenetrant, in which the biopenetrant comprises a polymer of an unsaturated carboxylic acid or a copolymer of an unsaturated carboxylic acid with a sulphonic acid, said polymer or copolymer being terminated by a mono- or diphosphonated unsaturated carboxylic acid group or having such monomers incorporated into the polymer backbone. This composition acts synergistically to enhance the biocidal efficacy of the THP salt against both planktonic (free-swimming) and sessile (attached) bacteria, and also acts synergistically to enhance the efficacy of the THP salt in the dissolution of iron sulphide scale.

A synergistic composition comprising a THP salt and a biopenetrant, in which the biopenetrant comprises a polymer of an unsaturated carboxylic acid or a copolymer of an unsaturated carboxylic acid with a sulphonic acid, said polymer or copolymer being terminated by a mono- or diphosphonated unsaturated carboxylic acid group or having such monomers incorporated into the polymer backbone. This composition acts synergistically to enhance the biocidal efficacy of the THP salt against both planktonic (free-swimming) and sessile (attached) bacteria, and also acts synergistically to enhance the efficacy of the THP salt in the dissolution of iron sulphide scale.

A synergistic composition comprising a THP salt and a biopenetrant, in which the biopenetrant comprises a polymer of an unsaturated carboxylic acid or a copolymer of an unsaturated carboxylic acid with a sulphonic acid, said polymer or copolymer being terminated by a mono- or diphosphonated unsaturated carboxylic acid group or having such monomers incorporated into the polymer backbone. This composition acts synergistically to enhance the biocidal efficacy of the THP salt against both planktonic (free-swimming) and sessile (attached) bacteria, and also acts synergistically to enhance the efficacy of the THP salt in the dissolution of iron sulphide scale.

A composition comprising: (a) tetrakis(hydroxymethyl)phosphonium sulfate (THPS); (b) water; and (c) methanol; wherein the weight percentages of (a), (b) and (c) are within the area on a ternary phase diagram for (a), (b) and (c) bounded by four points: (A) 5% THPS/58% water/37% methanol; (B) 5% THPS/36% water/59% methanol; (C) 65% THPS/27% water/8% methanol; and (D) 65% THPS/29% water/6% methanol.

A composition comprising: (a) tetrakis(hydroxymethyl)phosphonium sulfate (THPS); (b) water; and (c) methanol; wherein the weight percentages of (a), (b) and (c) are within the area on a ternary phase diagram for (a), (b) and (c) bounded by four points: (A) 5% THPS/58% water/37% methanol; (B) 5% THPS/36% water/59% methanol; (C) 65% THPS/27% water/8% methanol; and (D) 65% THPS/29% water/6% methanol.

A composition comprising: (a) tetrakis(hydroxymethyl)phosphonium sulfate (THPS); (b) water; and (c) methanol; wherein the weight percentages of (a), (b) and (c) are within the area on a ternary phase diagram for (a), (b) and (c) bounded by four points: (A) 5% THPS/58% water/37% methanol; (B) 5% THPS/36% water/59% methanol; (C) 65% THPS/27% water/8% methanol; and (D) 65% THPS/29% water/6% methanol.

The present disclosure relates to multi-functional anti-microbial polymers comprising a first monomer having a polymerizable cyclic aromatic moiety which forms part of the backbone of the polymer and a second monomer having an ethylenically unsaturated monomer having a double or triple bond and a quaternary ammonium or quaternary phosphonium moiety.

The present disclosure relates to multi-functional anti-microbial polymers comprising a first monomer having a polymerizable cyclic aromatic moiety which forms part of the backbone of the polymer and a second monomer having an ethylenically unsaturated monomer having a double or triple bond and a quaternary ammonium or quaternary phosphonium moiety.