Patent classifications
C07C227/40
Process for preparing aminobenzoic acid or an aminobenzoic acid conversion product
The present invention relates to a process for preparing aminobenzoic acid or an aminobenzoic acid conversion product, comprising the steps of: (I) providing an aqueous solution of aminobenzoic acid using a fermentation process; (II) adsorbing aminobenzoic acid; (III) desorbing aminobenzoic acid at a pH in the range from −0.8 to 3.0, preferably −0.5 to 3.0, more preferably 0.1 to 3.0, very preferably 0.5 to 2.5, very exceptionally preferably 1.0 to 2.0; (IV) obtaining the aminobenzoic acid from the desorbate obtained in step (III); (V) optionally further converting the aminobenzoic acid obtained in step (IV) to an aminobenzoic acid conversion product.
Process for preparing aminobenzoic acid or an aminobenzoic acid conversion product
The present invention relates to a process for preparing aminobenzoic acid or an aminobenzoic acid conversion product, comprising the steps of: (I) providing an aqueous solution of aminobenzoic acid using a fermentation process; (II) adsorbing aminobenzoic acid; (III) desorbing aminobenzoic acid at a pH in the range from −0.8 to 3.0, preferably −0.5 to 3.0, more preferably 0.1 to 3.0, very preferably 0.5 to 2.5, very exceptionally preferably 1.0 to 2.0; (IV) obtaining the aminobenzoic acid from the desorbate obtained in step (III); (V) optionally further converting the aminobenzoic acid obtained in step (IV) to an aminobenzoic acid conversion product.
Method for purifying aromatic amino acids
A method for purifying an amino acid from an initial mixture is disclosed, in which the amino acid includes an aromatic ring and has an acidity constant Ka, the method including: a first step of putting the initial mixture into contact with a strong cation resin, at a pH greater than or equal to pKa; and a second elution step with an aqueous solution of eluent having a pH greater than the pH of the first step, giving the possibility of collecting a flow enriched in the amino acid.
Method for purifying aromatic amino acids
A method for purifying an amino acid from an initial mixture is disclosed, in which the amino acid includes an aromatic ring and has an acidity constant Ka, the method including: a first step of putting the initial mixture into contact with a strong cation resin, at a pH greater than or equal to pKa; and a second elution step with an aqueous solution of eluent having a pH greater than the pH of the first step, giving the possibility of collecting a flow enriched in the amino acid.
METHODS OF STABILIZING AND PURIFYING AQUEOUS COMPOSITIONS OFALKALI METAL SALTS OF AMINO ACIDS COMPRISING ALKALI METAL HYDROXIDE
Method of purifying an alkali metal salt of a compound of the general Formula (I) or Formula (II)
##STR00001## wherein R.sup.1, R.sup.2 and R.sup.3 are independently H, an alkyl, an alkenyl, or a hydroxyalkyl radical containing from 1 to 18 carbon atoms, or from 1 to 6 carbon atoms; or wherein R.sup.1 and R.sup.2 form jointly together with the N atom a heterocyclic 5- or 6-membered ring; said method comprising providing a mixture comprising said, an alkali metal hydroxide and water, and subjecting the mixture to a step (X): (X) reducing the quantity of removing said alkali metal hydroxide from the mixture; wherein (A) said alkali metal hydroxide is reduced by subjecting said mixture to electrodialysis; and/or (B) said alkali metal hydroxide is reduced by adding an acid to said mixture.
METHODS OF STABILIZING AND PURIFYING AQUEOUS COMPOSITIONS OFALKALI METAL SALTS OF AMINO ACIDS COMPRISING ALKALI METAL HYDROXIDE
Method of purifying an alkali metal salt of a compound of the general Formula (I) or Formula (II)
##STR00001## wherein R.sup.1, R.sup.2 and R.sup.3 are independently H, an alkyl, an alkenyl, or a hydroxyalkyl radical containing from 1 to 18 carbon atoms, or from 1 to 6 carbon atoms; or wherein R.sup.1 and R.sup.2 form jointly together with the N atom a heterocyclic 5- or 6-membered ring; said method comprising providing a mixture comprising said, an alkali metal hydroxide and water, and subjecting the mixture to a step (X): (X) reducing the quantity of removing said alkali metal hydroxide from the mixture; wherein (A) said alkali metal hydroxide is reduced by subjecting said mixture to electrodialysis; and/or (B) said alkali metal hydroxide is reduced by adding an acid to said mixture.
METHODS OF STABILIZING AND PURIFYING AQUEOUS COMPOSITIONS OFALKALI METAL SALTS OF AMINO ACIDS COMPRISING ALKALI METAL HYDROXIDE
Method of purifying an alkali metal salt of a compound of the general Formula (I) or Formula (II)
##STR00001## wherein R.sup.1, R.sup.2 and R.sup.3 are independently H, an alkyl, an alkenyl, or a hydroxyalkyl radical containing from 1 to 18 carbon atoms, or from 1 to 6 carbon atoms; or wherein R.sup.1 and R.sup.2 form jointly together with the N atom a heterocyclic 5- or 6-membered ring; said method comprising providing a mixture comprising said, an alkali metal hydroxide and water, and subjecting the mixture to a step (X): (X) reducing the quantity of removing said alkali metal hydroxide from the mixture; wherein (A) said alkali metal hydroxide is reduced by subjecting said mixture to electrodialysis; and/or (B) said alkali metal hydroxide is reduced by adding an acid to said mixture.
Process for the separation of long chain amino acids and dibasic acids
There is disclosed a process for the separation of long chain amino acid and long chain dibasic acid, comprising: (1) adding an ammonium salt to the mixture of alkali salts of long chain amino acid and long chain dibasic acid; (2) heating to remove ammonia; and (3) separating long chain amino acid by solid-liquid separation; and (4) acidifying the salt of long chain dibasic acid with an acid to separate long chain dibasic acid.
Process for the separation of long chain amino acids and dibasic acids
There is disclosed a process for the separation of long chain amino acid and long chain dibasic acid, comprising: (1) adding an ammonium salt to the mixture of alkali salts of long chain amino acid and long chain dibasic acid; (2) heating to remove ammonia; and (3) separating long chain amino acid by solid-liquid separation; and (4) acidifying the salt of long chain dibasic acid with an acid to separate long chain dibasic acid.
PROCESS FOR DRYING N,N-DIMETHYL GLYCINATE SALTE
The application relates to a process for drying a composition comprising an alkali metal salt of a compound of general formula (I) R.sup.1R.sup.2NCHR.sup.3COOM or formula (II) R.sup.1R.sup.2NCHR.sup.3CHR.sup.3COOM, in particular N,N-dimethyl glycinate salt, and the use thereof. In the process, the composition, in particular the N,N-di methyl glycinate salt, is dried by feeding the composition into a fluidized bed dryer and subjecting the composition to a heat treatment by contacting the composition in the fluidized bed dryer with a drying gas stream, and during the heat treatment a solution or dispersion of the composition is sprayed onto at least a portion of the composition present in the fluidized bed dryer, or alternatively or in addition the composition, in particular N,N-dimethyl glycinate salt, is fed into a fluidized bed dryer and subjected to heat treatment in the fluidized bed dryer by contacting the composition with a drying gas stream, and the temperature of the composition in the fluidized bed during the heat treatment does not exceed 50 C.