Patent classifications
C07C253/26
FLUID DISTRIBUTOR, REACTION DEVICE AND APPLICATION THEREOF
A fluid distributor includes one or more fluid transport main pipe. The fluid transport main pipe is configured to assume a closed shape when its centerlines and/or centerline extensions are joined end-to-end. Each of the fluid transport main pipe has at least one fluid inlet and is connected with a plurality of fluid transport branch pipes. Each of the fluid transport branch pipes has a plurality of open pores disposed along the length of the fluid transport branch pipe and a connection portion. The connection portion is configured to connect the fluid transport branch pipe to the housing after the fluid transport branch pipe passes through the housing of the vessel into the inner cavity.
Method for producing oxide catalyst and method for producing unsaturated nitrile
A method for producing an oxide catalyst containing Mo, V, Sb, and Nb, the method including: a raw material preparation step including sub-step (I) of preparing an aqueous mixed liquid (A) containing Mo, V, and Sb, sub-step (II) of adding hydrogen peroxide to the aqueous mixed liquid (A), thereby facilitating oxidation of the aqueous mixed liquid (A) and obtaining an aqueous mixed liquid (A), and sub-step (III) of mixing the aqueous mixed liquid (A) and a Nb raw material liquid (B), thereby obtaining an aqueous mixed liquid (C); a drying step of drying the aqueous mixed liquid (C), thereby obtaining a dried powder; and a calcination step of calcining the dried powder under an inert gas atmosphere, wherein a time elapsed from addition of the hydrogen peroxide to the aqueous mixed liquid (A) to mixing the Nb raw material liquid (B) therewith is less than 5 minutes and the aqueous mixed liquid (A) before being subjected to the sub-step (III) has an oxidation-reduction potential of 150 to 350 mV.
Method for producing oxide catalyst and method for producing unsaturated nitrile
A method for producing an oxide catalyst containing Mo, V, Sb, and Nb, the method including: a raw material preparation step including sub-step (I) of preparing an aqueous mixed liquid (A) containing Mo, V, and Sb, sub-step (II) of adding hydrogen peroxide to the aqueous mixed liquid (A), thereby facilitating oxidation of the aqueous mixed liquid (A) and obtaining an aqueous mixed liquid (A), and sub-step (III) of mixing the aqueous mixed liquid (A) and a Nb raw material liquid (B), thereby obtaining an aqueous mixed liquid (C); a drying step of drying the aqueous mixed liquid (C), thereby obtaining a dried powder; and a calcination step of calcining the dried powder under an inert gas atmosphere, wherein a time elapsed from addition of the hydrogen peroxide to the aqueous mixed liquid (A) to mixing the Nb raw material liquid (B) therewith is less than 5 minutes and the aqueous mixed liquid (A) before being subjected to the sub-step (III) has an oxidation-reduction potential of 150 to 350 mV.
PROCESSES FOR STABILIZING ANTIMONY CATALYSTS
The present disclosure relates to a process for stabilizing an antimony ammoxidation catalyst in an ammoxidation process. The process may comprise providing an antimony ammoxidation catalyst to a reactor; reacting propylene with ammonia and oxygen in the fluidized bed reactor in the presence of the antimony ammoxidation catalyst to form a crude acrylonitrile product; and adding an effective amount of an antimony-containing compound to the antimony ammoxidation catalyst to maintain catalyst conversion and selectivity; wherein the antimony-containing compound has a melting point less than 375 C. The present disclosure also relates to catalyst compositions and additional processes using the antimony ammoxidation catalyst stabilized by an antimony-containing compound.
PROCESSES FOR STABILIZING ANTIMONY CATALYSTS
The present disclosure relates to a process for stabilizing an antimony ammoxidation catalyst in an ammoxidation process. The process may comprise providing an antimony ammoxidation catalyst to a reactor; reacting propylene with ammonia and oxygen in the fluidized bed reactor in the presence of the antimony ammoxidation catalyst to form a crude acrylonitrile product; and adding an effective amount of an antimony-containing compound to the antimony ammoxidation catalyst to maintain catalyst conversion and selectivity; wherein the antimony-containing compound has a melting point less than 375 C. The present disclosure also relates to catalyst compositions and additional processes using the antimony ammoxidation catalyst stabilized by an antimony-containing compound.
PROCESS AND CATALYSTS FOR THE OXIDATION AND/OR AMMOXIDATION OF OLEFIN
Embodiments of the present disclosure describe a catalyst and/or a precatalyst, in particular a single site catalyst and/or a single site precatalyst, for the oxidation and/or ammoxidation of olefins to produce aldehydes and/or nitriles, methods of preparing a corresponding catalyst and/or precatalyst, in particular single site catalyst and/or single site precatalyst, and methods of using said catalyst and/or precatalyst, in particular said single site catalyst and/or single site precatalyst, to produce aldehydes and/or nitriles.
PROCESS AND CATALYSTS FOR THE OXIDATION AND/OR AMMOXIDATION OF OLEFIN
Embodiments of the present disclosure describe a catalyst and/or a precatalyst, in particular a single site catalyst and/or a single site precatalyst, for the oxidation and/or ammoxidation of olefins to produce aldehydes and/or nitriles, methods of preparing a corresponding catalyst and/or precatalyst, in particular single site catalyst and/or single site precatalyst, and methods of using said catalyst and/or precatalyst, in particular said single site catalyst and/or single site precatalyst, to produce aldehydes and/or nitriles.
PROCESS AND CATALYSTS FOR THE OXIDATION AND/OR AMMOXIDATION OF OLEFIN
Embodiments of the present disclosure describe a catalyst and/or a precatalyst, in particular a single site catalyst and/or a single site precatalyst, for the oxidation and/or ammoxidation of olefins to produce aldehydes and/or nitriles, methods of preparing a corresponding catalyst and/or precatalyst, in particular single site catalyst and/or single site precatalyst, and methods of using said catalyst and/or precatalyst, in particular said single site catalyst and/or single site precatalyst, to produce aldehydes and/or nitriles.
Process for producing unsaturated nitrile
A process for producing unsaturated nitrile, using a fluidized bed reactor having an internal space having a catalyst capable of being fluidized therein, a feed opening to feed a starting material gas comprising hydrocarbon to the internal space, and a discharge port to discharge a reaction product gas from the internal space, the process comprising a reaction step of subjecting the hydrocarbon to a vapor phase catalytic ammoxidation reaction in the presence of the catalyst in the internal space to produce the corresponding unsaturated nitrile, wherein when in the internal space, a space where an existing amount of the catalyst per unit volume is 150 kg/m.sup.3 or more is defined as a dense zone and a space where an existing amount of the catalyst per unit volume is less than 150 kg/m.sup.3 is defined as a sparse zone in the reaction step, a gas residence time in the sparse zone is 5 to 50 sec.
Process for producing unsaturated nitrile
A process for producing unsaturated nitrile, using a fluidized bed reactor having an internal space having a catalyst capable of being fluidized therein, a feed opening to feed a starting material gas comprising hydrocarbon to the internal space, and a discharge port to discharge a reaction product gas from the internal space, the process comprising a reaction step of subjecting the hydrocarbon to a vapor phase catalytic ammoxidation reaction in the presence of the catalyst in the internal space to produce the corresponding unsaturated nitrile, wherein when in the internal space, a space where an existing amount of the catalyst per unit volume is 150 kg/m.sup.3 or more is defined as a dense zone and a space where an existing amount of the catalyst per unit volume is less than 150 kg/m.sup.3 is defined as a sparse zone in the reaction step, a gas residence time in the sparse zone is 5 to 50 sec.