Patent classifications
C07C319/16
DIALKYL SULFIDE, METHOD FOR PRODUCING DIALKYL SULFIDE, EXTREME-PRESSURE ADDITIVE, AND LUBRICATING FLUID COMPOSITION
An object of the present invention is to provide a dialkyl sulfide which can effectively form a metal sulfide film on a metal surface even in a low-temperature environment, has excellent storage stability, and is suitable as an extreme-pressure additive. The present invention provides a dialkyl sulfide represented by general formula (1) below (in the formula, R.sup.1 and R.sup.2 each independently represent an alkyl group, and n is an integer), wherein the content of a compound having an n value of 1 in the general formula (1) is 10.0% by mass or less relative to the total amount of compounds represented by the general formula (1)
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DIALKYL SULFIDE, METHOD FOR PRODUCING DIALKYL SULFIDE, EXTREME-PRESSURE ADDITIVE, AND LUBRICATING FLUID COMPOSITION
An object of the present invention is to provide a dialkyl sulfide which can effectively form a metal sulfide film on a metal surface even in a low-temperature environment, has excellent storage stability, and is suitable as an extreme-pressure additive. The present invention provides a dialkyl sulfide represented by general formula (1) below (in the formula, R.sup.1 and R.sup.2 each independently represent an alkyl group, and n is an integer), wherein the content of a compound having an n value of 1 in the general formula (1) is 10.0% by mass or less relative to the total amount of compounds represented by the general formula (1)
##STR00001##
DIALKYL SULFIDE, METHOD FOR PRODUCING DIALKYL SULFIDE, EXTREME-PRESSURE ADDITIVE, AND LUBRICATING FLUID COMPOSITION
An object of the present invention is to provide a dialkyl sulfide which can effectively form a metal sulfide film on a metal surface even in a low-temperature environment, has excellent storage stability, and is suitable as an extreme-pressure additive. The present invention provides a dialkyl sulfide represented by general formula (1) below (in the formula, R.sup.1 and R.sup.2 each independently represent an alkyl group, and n is an integer), wherein the content of a compound having an n value of 1 in the general formula (1) is 10.0% by mass or less relative to the total amount of compounds represented by the general formula (1)
##STR00001##
Flow reactor vessels and reactor systems
The present invention discloses high pressure flow reactor vessels and associated systems. Also disclosed are processes for producing thiol compounds and sulfide compounds utilizing these flow reactor vessels.
Flow reactor vessels and reactor systems
The present invention discloses high pressure flow reactor vessels and associated systems. Also disclosed are processes for producing thiol compounds and sulfide compounds utilizing these flow reactor vessels.
Flow reactor vessels and reactor systems
The present invention discloses high pressure flow reactor vessels and associated systems. Also disclosed are processes for producing thiol compounds and sulfide compounds utilizing these flow reactor vessels.
SEQUENTIAL AND INDEPENDENT SYNTHESIS OF MERCAPTANS AND ASYMMETRICAL SULFIDES IN A SINGLE REACTOR
The present disclosure generally relates to processes to produce a mercaptan and an asymmetrical sulfide utilize stacked bed catalyst systems containing CoMo and NiMo, and these processes demonstrate a synergistic reduction in the amount of ethylene, methyl mercaptan, ethyl mercaptan, and H.sub.2S in product mixtures. In aspects, the conversion of limiting reactants in the synthesis of asymmetrical sulfides unexpectedly remain high under increased flow rates through the catalyst bed, and under reduced temperatures and pressures. In further aspects, reactor systems configured for the independent synthesis of mercaptans and asymmetrical sulfides in a single fixed bed catalyst vessel are also disclosed as a simplification of existing reactor systems employing separate reactors for separate mercaptan and sulfide syntheses.
SEQUENTIAL AND INDEPENDENT SYNTHESIS OF MERCAPTANS AND ASYMMETRICAL SULFIDES IN A SINGLE REACTOR
The present disclosure generally relates to processes to produce a mercaptan and an asymmetrical sulfide utilize stacked bed catalyst systems containing CoMo and NiMo, and these processes demonstrate a synergistic reduction in the amount of ethylene, methyl mercaptan, ethyl mercaptan, and H.sub.2S in product mixtures. In aspects, the conversion of limiting reactants in the synthesis of asymmetrical sulfides unexpectedly remain high under increased flow rates through the catalyst bed, and under reduced temperatures and pressures. In further aspects, reactor systems configured for the independent synthesis of mercaptans and asymmetrical sulfides in a single fixed bed catalyst vessel are also disclosed as a simplification of existing reactor systems employing separate reactors for separate mercaptan and sulfide syntheses.
Synthesis of Methyl Ethyl Sulfide and Related Production Systems
The present invention discloses processes for producing methyl ethyl sulfide by contacting dimethyl sulfide and diethyl sulfide in the presence of a suitable catalyst. Methyl ethyl sulfide can be used as an odorant in natural gas. Integrated mercaptan and sulfide manufacturing systems and integrated methods for making mercaptans and sulfides also are disclosed.
Flow Reactor Vessels and Reactor Systems
The present invention discloses high pressure flow reactor vessels and associated systems. Also disclosed are processes for producing thiol compounds and sulfide compounds utilizing these flow reactor vessels.