Patent classifications
C07C407/006
Powder mixture comprising organic peroxide
Powder mixture comprising 20-80 wt % of one or more powdered organic peroxides selected from the group consisting of dibenzoyl peroxide and substituted dibenzoyl peroxides, 20-80 wt % of a powdered filler material, at least 60 wt %, thereof consisting of a solid inorganic flame retardant, and 0-20 wt % water.
AQUEOUS ORGANIC PEROXIDE EMULSION
The present invention relates to an aqueous emulsion of peroxyester, comprising at least one peroxyester, at least one antifreeze and a combination of at least two emulsifiers chosen from the group consisting of a non-ethoxylated sorbitan ester, an ethoxylated sorbitan ester and an ethoxylated fatty alcohol.
AQUEOUS ORGANIC PEROXIDE EMULSION
The present invention relates to an aqueous emulsion of peroxyester, comprising at least one peroxyester, at least one antifreeze and a combination of at least two emulsifiers chosen from the group consisting of a non-ethoxylated sorbitan ester, an ethoxylated sorbitan ester and an ethoxylated fatty alcohol.
Generation of peroxyhydroxycarboxylic acid and the use thereof
Peroxyhydroxycarboxylic acid forming compositions and methods for forming peroxyhydroxycarboxylic acids, preferably in situ, using the peroxyhydroxycarboxylic acid forming compositions are disclosed. Methods of using the peroxyhydroxycarboxylic acids, including for treating a surface or a target in need of antimicrobial or sanitizing treatment are also disclosed. Particular applications of using odor-free, low volatility peroxyhydroxycarboxylic acid sanitizers for direct food contact are disclosed.
METHODS FOR FORMING PEROXYFORMIC ACID AND USES THEREOF
The present invention relates generally to methods for forming peroxyformic acid, comprising contacting formic acid with hydrogen peroxide. The methods for forming peroxyformic acid can include adding formic acid with a relatively lower concentration of hydrogen peroxide, or adding formic acid to a peroxycarboxylic acid composition or forming composition to react with hydrogen peroxide in the compositions. The present invention also relates to peroxyformic acid formed by the above methods. The present invention further relates to the uses of peroxyformic acid for treating a variety of targets, e.g., target water, including target water used in connection with oil- and gas-field operations. The present invention further relates to methods for reducing or removing H.sub.2S or iron sulfide in the treated water source, improving clarity of the treated water source, or reducing the total dissolved oxygen or corrosion in the treated water source, using peroxyformic acid, including peroxyformic acid generated in situ.
METHODS FOR FORMING PEROXYFORMIC ACID AND USES THEREOF
The present invention relates generally to methods for forming peroxyformic acid, comprising contacting formic acid with hydrogen peroxide. The methods for forming peroxyformic acid can include adding formic acid with a relatively lower concentration of hydrogen peroxide, or adding formic acid to a peroxycarboxylic acid composition or forming composition to react with hydrogen peroxide in the compositions. The present invention also relates to peroxyformic acid formed by the above methods. The present invention further relates to the uses of peroxyformic acid for treating a variety of targets, e.g., target water, including target water used in connection with oil- and gas-field operations. The present invention further relates to methods for reducing or removing H.sub.2S or iron sulfide in the treated water source, improving clarity of the treated water source, or reducing the total dissolved oxygen or corrosion in the treated water source, using peroxyformic acid, including peroxyformic acid generated in situ.
Process for preparing a powdery organic peroxide formulation
Process for preparing a powdery organic peroxide formulation, said process comprises the following steps: a) preparing a reaction mixture comprising: 40-80 wt % water 10-25 wt % of an acid chloride or chloroformate, 1-4 wt % hydrogen peroxide, 2-8 wt % alkali metal hydroxide, 1-25 wt % of a phlegmatizer selected from the group consisting of ethylene glycol dibenzoate, phenyl benzoate, trimethylol propane tribenzoate, glyceryl tribenzoate, ethylene glycol ditoluate, 1,3-propanediol ditoluate, ethylene glycol 4-tert-butylbenzoate, ethylene glycol monobenzoate monotoluate, 2,3-butanediol dibenzoate, 4-methylphenyl benzoate acid ester, trimethylolpropane dibenzoate, and combinations thereof 0.002-0.20 wt % of a surfactant, and 0.25-5.0 wt % of an inert organic solvent, all percentages based on the weight of the reaction mixture, b) heating the reaction mixture at a temperature in the range 5-50° C.
Process for preparing a powdery organic peroxide formulation
Process for preparing a powdery organic peroxide formulation, said process comprises the following steps: a) preparing a reaction mixture comprising: 40-80 wt % water 10-25 wt % of an acid chloride or chloroformate, 1-4 wt % hydrogen peroxide, 2-8 wt % alkali metal hydroxide, 1-25 wt % of a phlegmatizer selected from the group consisting of ethylene glycol dibenzoate, phenyl benzoate, trimethylol propane tribenzoate, glyceryl tribenzoate, ethylene glycol ditoluate, 1,3-propanediol ditoluate, ethylene glycol 4-tert-butylbenzoate, ethylene glycol monobenzoate monotoluate, 2,3-butanediol dibenzoate, 4-methylphenyl benzoate acid ester, trimethylolpropane dibenzoate, and combinations thereof 0.002-0.20 wt % of a surfactant, and 0.25-5.0 wt % of an inert organic solvent, all percentages based on the weight of the reaction mixture, b) heating the reaction mixture at a temperature in the range 5-50° C.
USE OF UREA OR A UREA/CHELATOR COMBINATION TO CHEMICALLY STABILIZE PEROXYCARBOXYLIC ACID AND PEROXIDE FORMULATIONS
Stabilized peroxide-containing compositions stabilized with urea and urea/chelator stabilizer blends are provided. The compositions are particularly suitable for, but not limited to, cleaning applications on surfaces within food and beverage industries which may require the use of materials that are acceptable for incidental food/food products/feed contact. Further, the stabilized compositions are particularly suitable for applications requiring materials that are generally regarded as safe (GRAS) or for applications where non-GRAS materials must be minimized. Methods of stabilizing peroxide-containing compositions and methods of using the compositions are also provided.
USE OF UREA OR A UREA/CHELATOR COMBINATION TO CHEMICALLY STABILIZE PEROXYCARBOXYLIC ACID AND PEROXIDE FORMULATIONS
Stabilized peroxide-containing compositions stabilized with urea and urea/chelator stabilizer blends are provided. The compositions are particularly suitable for, but not limited to, cleaning applications on surfaces within food and beverage industries which may require the use of materials that are acceptable for incidental food/food products/feed contact. Further, the stabilized compositions are particularly suitable for applications requiring materials that are generally regarded as safe (GRAS) or for applications where non-GRAS materials must be minimized. Methods of stabilizing peroxide-containing compositions and methods of using the compositions are also provided.