Provided are a catalyst system for olefin oligomerization reaction and a method for olefin oligomerization, and more particularly, a catalyst system for olefin oligomerization reaction and a method for olefin oligomerization, which enable more efficient preparation of alpha-olefin, because a catalytic active ingredient is supported on a support, thereby exhibiting high activity in olefin oligomerization reaction even by using smaller amounts of a catalyst composition and a cocatalyst.

The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.

Cis and trans ruthenium complexes that can be used as catalysts for ring opening metathesis polymerisation (ROMP) are described. The complexes are generally square pyramidal in nature, having two anionic ligands X. Corresponding cationic complexes where one or both of the anionic ligands X are replaced by a non-co-ordinating anionic ligand are also described. Polymers such as polydicyclopentadiene (PDCPD) can be prepared using the catalysts.

A neutral or cationic mononuclear ruthenium divalent complex represented by formula (1) can actualize exceptional catalytic activity in at least one reaction among a hydrosilylation reaction, hydrogenation reaction, and carbonyl compound reduction reaction. ##STR00001##
(In the formula, R.sup.1-R.sup.6 each independently represent a hydrogen atom or an alkyl group, aryl group, aralkyl group, organooxy group, monoorganoamino group, diorganoamino group, monoorganophosphino group, diorganophosphino group, monoorganosilyl group, diorganosilyl group, triorganosilyl group, or organothio group optionally substituted by X; at least one pair comprising any of R.sup.1-R.sup.3 and any of R.sup.4-R.sup.6 together represents a crosslinkable substituent; X represents a halogen atom, organooxy group, monoorganoamino group, diorganoamino group, or organothio group; L each independently represent a two-electron ligand other than CO and thiourea ligands; two L may bond to each other; and m represents an integer of 3 or 4.)

Provided are a catalyst composition and a method of oligomerizing olefins using the same. When the catalyst composition according to the present invention is used, oligomerization and copolymerization of olefin monomers may be performed in a single reactor at the same time with high efficiency without a separate process of preparing alpha-olefin. Therefore, costs for preparing or purchasing comonomers which are expensive raw materials may be reduced, thereby reducing the production cost of a final product. Contents of SCB (short chain branch) and LCB (long chain branch) in the polyolefin may be increased without separate feeding of comonomers, thereby producing high-quality linear low-density polyethylene.

The present invention relates to a pincer-based cobalt catalyst of formula (I) for hydrogenation of alkynes, and its process of preparation thereof. More particularly the present invention also relates to a process for the hydrogenation of alkynes to alkenes.

##STR00001##

Methods of polymer and/or oligomer depolymerization are described herein which, in some embodiments, enable facile polymer and/or oligomer decomposition under mild, non-energy intensive conditions. Briefly, a method of depolymerization comprises providing a reaction mixture comprising a transition metal catalyst, and a polymer or oligomer having a backbone including cyclobutane units, and decomposing the polymer or oligomer to provide diene monomer or alkene monomer.

The method for oligomerizing olefin according to the present disclosure is a method for oligomerizing olefin using an oligomerization catalyst system and includes deteriorating the activity of the oligomerization catalyst system by injecting a deactivator in a latter part of a multimerization reaction of olefin. The deactivator may include an additive for polymer containing at least one functional group selected from the group consisting of a hydroxyl group, an amine group and an amide group. According to the oligomerizing method, the isomer of 1-hexene and/or 1-octene and alpha-olefins with C.sub.10 to C.sub.40 may be decreased via the restraint of the additional side reaction of a product. Since the deactivator is an additive for enhancing the physical properties of a polymer, a separating process thereof is not required, thereby improving economic feasibility and productivity.

The present invention relates generally to catalysts and processes for the Z-selective formation of internal olefin(s) from terminal olefin(s) via homo-metathesis reactions.

The present disclosure relates to a catalyst composition including an organic ligand compound of a specific chemical structure; and a chromium compound and a method for synthesizing alpha-olefin using the catalyst composition, and when the catalyst composition is used, alpha-olefin may be stably synthesized with high selectivity and reaction activity.