C07F5/069

ALUMINUM COMPOUNDS AND METHODS OF FORMING ALUMINUM- CONTAINING FILM USING THE SAME

The present disclosure relates to a novel aluminum-containing compound, a method of preparing the aluminum-containing compound, a precursor composition for forming a film including the aluminum-containing precursor compound, and a method of forming an aluminum-containing film using the precursor composition for forming a film.

LOW REFRACTIVE INDEX COMPOUND AND ELECTRONIC APPARATUS INCLUDING THE SAME
20210159427 · 2021-05-27 ·

A metallic compound for use in an electronic apparatus having an organic light emitting element, the metallic compound having a refractive index: n.sub.620 nm≤about 1.60; n.sub.530 nm≤about 1.65; and n.sub.460nm≤about 1.68.

Synthesis of metal complexes and uses thereof
10974234 · 2021-04-13 · ·

The present disclosure provides novel methods of making aluminum complexes with utility for promoting epoxide carbonylation reactions. Methods include reacting neutral metal carbonyl compounds with alkylaluminum complexes. For example, a compound of formula I: ##STR00001##
is reacted with a neutral metal carbonyl compound (such as Q′.sub.dM.sub.e(CO).sub.w′) to produce an aluminum-based carbonylation catalyst: ##STR00002##

PROCESS TO CONTINUOUSLY PREPARE A CYCLIC CARBONATE
20230406836 · 2023-12-21 · ·

The invention is directed to a process to continuously prepare a cyclic carbonate product by reacting an epoxide compound with carbon dioxide in the presence of a supported dimeric aluminium salen complex. The process is performed in a reactor comprising a slurry of the supported dimeric aluminium salen complex and liquid cyclic carbonate product. The produced cyclic carbonate is discharged from the reactor while the supported dimeric aluminium salen complex remains in the reactor. The liquid carbonate product is purified by means of distillation. Between the reactor and the distillation one or more buffer vessels are present having a volume of between 5 and 50 m.sup.3 per kmol of dimeric aluminium salen complex as present in the reactor.

PROCESS FOR THE GENERATION OF METAL-CONTAINING FILMS

Described herein is a process for preparing inorganic metal-containing films including bringing a solid substrate in contact with a compound of general formula (I) or (II) in the gaseous state

##STR00001##

where A is NR.sub.2 or OR with R being an alkyl group, an alkenyl group, an aryl group, or a silyl group, E is NR or O, n is 1, 2 or 3, and R is hydrogen, an alkyl group, an alkenyl group, an aryl group, or a silyl group, wherein if n is 2 and E is NR or A is OR, at least one R in NR or OR bears no hydrogen atom in the 1-position.

PROCESS FOR THE GENERATION OF METAL-CONTAINING FILMS

Described herein is a process including bringing a solid substrate in contact with a compound of general formula (I), (II), (III), or (IV) in the gaseous state

##STR00001##

where A is NR.sub.2 or OR with R being an alkyl group, an alkenyl group, an aryl group, or a silyl group, E is NR or O, n is 0, 1 or 2, m is 0, 1 or 2, and R is hydrogen, an alkyl group, an alkenyl group, an aryl group, or a silyl group.

PROCESS FOR PREPARING METAL-CHELATE RETARDER BY SOL-GEL METHOD

The present invention relates to a process for preparing a metal-chelate retarder by a sol-gel method. The method comprises the following steps: weighing calcium nitrate tetrahydrate, aluminum nitrate nonahydrate and ferric nitrate nonahydrate according to a certain mass ratio and adding them into deionized water; placing the mixed solution on a magnetic stirrer and stirring the mixed solution evenly; adding citric acid monohydrate or gluconic acid, ethylene glycol or glycerol, and placing the mixed solution into a water bath to react to obtain the metal-chelate retarder. The process of the present invention has a reliable principle, overcomes the defects of long production period, complex preparation and the like of the existing retarders, has the advantages of simple process operation, cheap and easily available raw materials, and short production period. The prepared retarder has wide temperature adaptation range and adjustable thickening time, is suitable for large-scale industrial production, and has a wide market application prospect.

FLUORESCENT TURN-ON CHEMOSENSORS FOR DETECTION OF ALUMINUM ION AND AZIDE
20210041423 · 2021-02-11 ·

Two rhodamine derivatives, L.sub.1 and L.sub.2, bearing 2-methoxy-1-naphthaldehyde and 5-bromo-3-methoxy salicylaldehyde units were synthesized using microwave-assisted organic synthesis and used for reversible sequential fluorescence detection of aluminum ion (Al.sup.3+) and azide (N.sub.3.sup.) in aqueous acetonitrile solution.

Systems and methods for regioselective carbonylation of 2,2-disubstituted epoxides for the production of alpha,alpha-disubstituted beta-lactones

Provided are methods of producing carbonyl compounds (e.g., carbonyl containing compounds) and catalysts for producing carbonyl compounds. Also provided are methods of making polymers from carbonyl compounds and polymers formed from carbonyl compounds. A method may produce carbonyl compounds, such as, for example ,-disubstituted carbonyl compounds (e.g., ,-disubstituted -lactones). The polymers may be produced from ,-disubstituted -lactones, which may be produced by a method described herein.

SO2-BASED ELECTROLYTE FOR A RECHARGEABLE BATTERY CELL, AND RECHARGEABLE BATTERY CELLS
20210036358 · 2021-02-04 ·

This disclosure relates to an SO.sub.2-based electrolyte for a rechargeable battery cell containing at least one conducting salt of the Formula (I)

##STR00001##

wherein M is a metal selected from the group consisting of alkali metals, alkaline earth metals, metals of group 12 of the periodic table of the elements and aluminum; x is an integer from 1 to 3; the substituents R, R.sup.2, R.sup.3 and R.sup.4 are each independently selected from the group consisting of C.sub.1-C.sub.10 alkyl, C.sub.2-C.sub.1 alkenyl, C.sub.2-C.sub.1 alkynyl, C.sub.3-C.sub.10 cycloalkyl, C.sub.6-C.sub.14 aryl, and C.sub.5-C.sub.14 heteroaryl; and Z is aluminum or boron.