Preparation containing: (A) 30 to 90% by weight of at least one organic solvent; (B) 10 to 70% by weight of at least one platinum complex of the type [L1L2Pt[O(CO)R1]X].sub.n, wherein L1 and L2 represent the same or different monoolefin ligands, or together represent a compound L1L2 acting as a diolefin ligand, wherein X is selected from bromide, chloride, iodide, and —O(CO)R2, wherein —O(CO)R1 and —O(CO)R2 represent the same or different C6-C18 non-aromatic monocarboxylic acid groups, or together represent a C8-C18 non-aromatic dicarboxylic acid group —O(CO)R1 R2(CO)O—, wherein they are mononuclear platinum complexes with n=1, or wherein, if L1L2 and/or —O(CO)R1 R2(CO)O— are present, they may be polynuclear platinum complexes with a whole number n>1, and (C) 0 to 10% by weight of at least one additive.

Provided are an organic electroluminescent material and a device thereof. The organic electroluminescent material includes a metal M and at least one C{circumflex over ( )}N bidentate ligand L.sub.a coordinated with the metal M, the maximum emission wavelength of the photoluminescence spectrum of the organic electroluminescent material at room temperature is greater than or equal to 410 nm and less than or equal to 700 nm, and the emission spectrum area ratio of the organic electroluminescent material is less than or equal to 0.145. The metal complex has significant advantages in organic electroluminescent devices, in particular the improvement of device efficiency. Further provided are an organic electroluminescent device including the metal complex and a compound composition including the metal complex.

Provided are organometallic compounds. Also provided are formulations comprising these organometallic compounds. Further provided are OLEDs and related consumer products that utilize these organometallic compounds.

A compound including a first bidentate ligand L.sub.A that includes a structure of Formula I,

##STR00001##

are provided. The ligand L.sub.A is coordinated to a metal M and can be joined with other ligands. In Formula I, in addition to some exclusions, each of X.sup.1, X.sup.2, X.sup.3, and X.sup.4 is C or N; two R.sup.1, R.sup.2, and R.sup.3 can be joined or fused to form a ring; and each R.sup.1, R.sup.2, and R.sup.3 is independently a group containing the metal M, a hydrogen, or a General Substituent defined herein. Formulations, OLEDs, and consumer products containing the compound are also provided.

The present invention relates to methods of forming metal-pyridine derivative complexes using pericyclic reactions with metal-1,2,4-triazine derivative complexes and a dienophile as the reactants. The reactants are bioorthogonal and the methods are particularly useful in preparing imaging agents.

An organometallic compound represented by Formula 1:

##STR00001## wherein, in Formula 1, groups and variables are the same as described in the specification.

An organometallic compound represented by Formula 1:

##STR00001## wherein, in Formula 1, groups and variables are the same as described in the specification.

The present invention relates to a device containing an organometal-complex luminescent material. The device comprises a luminescent layer. The luminescent layer contains an organometal complex which has a structural formula (I), wherein A, B and C refer to substituted or unsubstituted C, N, O and S atoms independently; a dashed ring for linkage between A and B atoms refers to a substituted or unsubstituted conjugated ring structure; L1, L2, L3 and L4 are single bonds or double bonds independently, wherein L3 and L4 are part of the conjugated ring structure for linkage between A and B atoms; X, X1, Y and Y1 are C, N, O and S atoms independently; Ar1 and Ar2 are substituted or unsubstituted conjugated ring structures independently; M refers to Pt, W and Au atoms. An organometal complex in the luminescent material is high in fluorescence quantum efficiency and heat stability and low in quenching constant and can be used for manufacturing high-efficiency and low-efficiency roll-off red-light OLEDs. ##STR00001##

This invention concerns a versatile and simple one-pot method to prepare nanomaterials, and in particular nanoparticles, grafted with an ultra-thin layer of calixarenes by placing at 5 least one oxidized metal with at least one calix[n]arene diazonium salt in the presence of a reducing agent in a solvent, and heating the traction mixture to obtain a metal-based nanomaterial coated with calix[n]arenes. The invention further concerns the coupling of organic molecules or biomolecules to the calixarene-grafted nanomaterials in order to further functionalize the surface of the particles. The metal-based nanomaterial coated with 10 calix[n]arenes can for example be used in immunoassays.

The present disclosure provides four monocarborane cluster-containing platinum complexes and a preparation method and an OLED application. The monocarborane cluster-containing platinum complex has a general structural formula selected from the group consisting of the following general structural formulas:

##STR00001##

wherein —R.sub.1 is selected from the group consisting of C.sub.4-12 linear alkyl; each R and R.sub.5 are independently any one selected from the group consisting of —CH.sub.3, H, tert-butyl and aryl; aryl is any one selected from the group consisting of phenyl, carbazole

##STR00002##

and aniline

##STR00003##

wherein R.sub.2 is any one selected from the group consisting of methyl, tert-butyl and phenyl; R.sub.3 is any one selected from the group consisting of methyl, tert-butyl and phenyl; n is 1 to 3; X is C element; when the ligand of the general structural formula is triazole, X is N element; —CB.sub.11H.sub.11 is monocarborane with a structure of

##STR00004##