A method for preparing a novel waterborne polyurethane foam layer for synthetic leather is disclosed. The method includes first preparing a charged cellulose nanofiber by using a wood pulp as a raw material; meanwhile, subjecting a polyisocyanate, a macromolecular diol, a hydrophilic chain extender and a small molecular chain extender to a polyaddition reaction and an acid-base neutralization reaction in sequence, to obtain a cationic or anionic waterborne polyurethane; adding the charged cellulose nanofiber and a certain amount of a crosslinking agent to the oppositely charged ionic waterborne polyurethane emulsion, stirring the resulting mixture, forming a bimolecular layer at the gas/liquid interface by a self-assembly of the cellulose nanofiber and waterborne polyurethane nanoparticles through electrostatic interactions to obtain a stable Pickering foam; using the stable Pickering foam as a template, drying and solidifying to obtain the waterborne polyurethane foam layer for synthetic leather.

The present invention relates to a film comprising hydrophobically modified cellulose fibers in which cellulose fibers are bound to a modifying group at one or more members selected from anionic groups and hydroxyl groups, and an oil having an SP value of 10 or less. The film of the present invention can be utilized in the fields of materials for packaging containers for cosmetics and foods.

The present invention relates to a film comprising hydrophobically modified cellulose fibers in which cellulose fibers are bound to a modifying group at one or more members selected from anionic groups and hydroxyl groups, and an oil having an SP value of 10 or less. The film of the present invention can be utilized in the fields of materials for packaging containers for cosmetics and foods.

A fine cellulose fiber composite in which a modifying group is bound to a carboxy group of fine cellulose fibers, the fine cellulose fibers having a carboxy group content of 0.1 mmol/g or more, wherein the fine cellulose fiber composite has an average aspect ratio of 1 or more and 150 or less; and a resin composition containing the fine cellulose fiber composite and a resin. The resin composition containing a fine cellulose fiber composite of the present invention has excellent heat resistance, and the molded article of this resin composition has excellent mechanical strength, heat resistance, and dimensional stability. Accordingly, the present invention can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, and automobile parts.

A fine cellulose fiber composite in which a modifying group is bound to a carboxy group of fine cellulose fibers, the fine cellulose fibers having a carboxy group content of 0.1 mmol/g or more, wherein the fine cellulose fiber composite has an average aspect ratio of 1 or more and 150 or less; and a resin composition containing the fine cellulose fiber composite and a resin. The resin composition containing a fine cellulose fiber composite of the present invention has excellent heat resistance, and the molded article of this resin composition has excellent mechanical strength, heat resistance, and dimensional stability. Accordingly, the present invention can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, and automobile parts.

A composition comprising nanocellulose is disclosed, wherein the nanocellulose contains very low or essentially no sulfur content. The nanocellulose may be in the form of cellulose nanocrystals, cellulose nanofibrils, or both. The nanocellulose is characterized by a crystallinity of at least 80%, an onset of thermal decomposition of 300° F. or higher, and a low light transmittance over the range 400-700 nm. Other variations provide a composition comprising lignin-coated hydrophobic nanocellulose, wherein the nanocellulose contains very low or essentially no sulfur content. Some variations provide a composition comprising nanocellulose, wherein the nanocellulose contains about 0.1 wt % equivalent sulfur content, or less, as SO.sub.4 groups chemically or physically bound to the nanocellulose. In some embodiments, the nanocellulose contains essentially no hydrogen atoms (apart from hydrogen structurally contained in nanocellulose itself) bound to the nanocellulose. Various compositions, materials, and products may incorporate the nanocellulose compositions disclosed herein.

A composition comprising nanocellulose is disclosed, wherein the nanocellulose contains very low or essentially no sulfur content. The nanocellulose may be in the form of cellulose nanocrystals, cellulose nanofibrils, or both. The nanocellulose is characterized by a crystallinity of at least 80%, an onset of thermal decomposition of 300° F. or higher, and a low light transmittance over the range 400-700 nm. Other variations provide a composition comprising lignin-coated hydrophobic nanocellulose, wherein the nanocellulose contains very low or essentially no sulfur content. Some variations provide a composition comprising nanocellulose, wherein the nanocellulose contains about 0.1 wt % equivalent sulfur content, or less, as SO.sub.4 groups chemically or physically bound to the nanocellulose. In some embodiments, the nanocellulose contains essentially no hydrogen atoms (apart from hydrogen structurally contained in nanocellulose itself) bound to the nanocellulose. Various compositions, materials, and products may incorporate the nanocellulose compositions disclosed herein.

An effect paint for automobiles, comprising water, a dispersant (A), cellulose nanofibers (B), and an effect pigment (C).

The present invention relates to a method for manufacturing an intermediate product that can be stored and transported and efficiently converted into microfibrillated cellulose with limited energy input at the time of conversion. More specifically, the invention involves the use of dewatered carboxymethylcellulose or carboxylated cellulose fiber having a low degree of substitution and a high amount of additives.

The present invention relates to a method for manufacturing an intermediate product that can be stored and transported and efficiently converted into microfibrillated cellulose with limited energy input at the time of conversion. More specifically, the invention involves the use of dewatered carboxymethylcellulose or carboxylated cellulose fiber having a low degree of substitution and a high amount of additives.