The present invention relates to a method for preparing a modified conjugated diene-based polymer having excellent physical properties such as tensile properties and viscoelasticity properties with a high modification ratio.

A vehicle tire rubber composite material, raw materials of the vehicle tire rubber composite material comprise the following components by weight: 30-40 weight distributions of solution-polymerized styrene-butadiene rubber, 35-55 weight distributions of rare earth butadiene rubber, 10-30 weight distributions of phenyl modified natural rubber, 5-14 weight distributions of polyurethane elastomer, 3-9 weight distributions of acetylene carbon black, 2-5 weight distributions of multifunctional abrasion-resistant flame retardant Cu@HNT@MoS.sub.2-PZE, 3-6 weight distributions of elastic fiber, 1-3 weight distributions of heat stabilizer, 2-3 weight distributions of silane coupling agent, 1-2.5 weight distributions of anti-scorching agent, 1-2.5 weight distributions of turpentine oil, and 4-6 weight distributions of accelerator.

The invention relates to the field of modified diene-containing (co)polymers, in particular, to modified butadiene-styrene copolymers that can be used as flame retardants for polymer compositions based on expandable polystyrene. In particular, the invention relates to a modified diene-containing (co)polymer, a method for preparing thereof and the use of the same as a flame retardant for expandable polystyrene. The modified diene-containing (co)polymer according to the invention is characterized by a high heat resistance, in particular, a 5% weight loss temperature of at least 180° C., a molecular weight of at least 1500 g/mol, and a halogen content of at least 35 wt. % based on the total weight of the (co)polymer.

The invention relates to the field of modified diene-containing (co)polymers, in particular, to modified butadiene-styrene copolymers that can be used as flame retardants for polymer compositions based on expandable polystyrene. In particular, the invention relates to a modified diene-containing (co)polymer, a method for preparing thereof and the use of the same as a flame retardant for expandable polystyrene. The modified diene-containing (co)polymer according to the invention is characterized by a high heat resistance, in particular, a 5% weight loss temperature of at least 180° C., a molecular weight of at least 1500 g/mol, and a halogen content of at least 35 wt. % based on the total weight of the (co)polymer.

Disclosed herein are modified diene-containing (co)polymers, in particular, modified styrene-butadiene copolymer, which can be used as flame retardants for expandable polystyrene polymer compositions. In particular, disclosed is a modified diene-containing (co)polymer, a method for preparing it, and use as a flame retardant for expandable polystyrene. The modified diene-containing (co)polymer claimed in the invention is characterized by high thermostability, namely, a 5% weight loss temperature of at least 180° C., a molecular weight of at least 1500 g/mol and a halogen content of at least 35 wt. %; the content of tertiary and/or allyl halogenides is in the range from 0 to less than 1.5 wt. %, and also does not affect the polymerization process and the formation of polystyrene granules either, and allows to obtain polystyrene granules with a yellowness index of 2 to 6 units, comparable to the yellowness index of polystyrene granules containing HBCD (from 0 to 3 units).

An iodine complex is formed by complexing a unit having a structure as represented by formula (I) with iodine molecules or iodine molecules with polyiodide ions formed by combining iodine ions. As a carrier, a polymer is complexed with iodine to obtain an iodine complex for formula (I).

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The iodine complex can be used as a radioactive marker, or used in an iodine therapeutic agent, or used in a polarizer. The polymer carrier has good biocompatibility. The content of iodine in the iodine complex can be adjusted according to requirements, and the content of the iodine can be adjusted within a range of 0.001-60%. The difference in the content of the iodine can affect the transmission clarity of the iodine complex as a radiographic marker.

An iodine complex is formed by complexing a unit having a structure as represented by formula (I) with iodine molecules or iodine molecules with polyiodide ions formed by combining iodine ions. As a carrier, a polymer is complexed with iodine to obtain an iodine complex for formula (I).

##STR00001##

The iodine complex can be used as a radioactive marker, or used in an iodine therapeutic agent, or used in a polarizer. The polymer carrier has good biocompatibility. The content of iodine in the iodine complex can be adjusted according to requirements, and the content of the iodine can be adjusted within a range of 0.001-60%. The difference in the content of the iodine can affect the transmission clarity of the iodine complex as a radiographic marker.

Modified diene polymers containing heteroatoms are disclosed, as is their production, rubber mixtures comprising these modified diene rubbers, and to their use for the production of rubber vulcanizates, which serve, in particular, for the production of rubber moldings and the production of tires.

Modified diene polymers containing heteroatoms are disclosed, as is their production, rubber mixtures comprising these modified diene rubbers, and to their use for the production of rubber vulcanizates, which serve, in particular, for the production of rubber moldings and the production of tires.

Methods are provided to efficiently produce butyl rubber via a slurry polymerization process. The process comprises providing at least two monomers, wherein at least one monomer is an isoolefin and at least one monomer is a multiolefin. The monomers are combined with an initiator and an organic diluent comprising 40-60 volume % of methyl chloride and 40-60 volume % of 1,1,1, 2-tetrafluoroethane and polymerized.