The present invention provides a method for producing a catalyst for polymerization of an olefin, which suppresses a decrease in polymerization activity due to early deactivation of the active site after the catalyst has been formed, exhibits excellent catalyst activity at the time of polymerization of olefins, and can produce polymers of olefins, which are excellent in stereoregularity. The method for producing a catalyst for polymerization of an olefin includes contacting a solid catalyst component (A) containing magnesium, titanium, halogen and an internal electron-donating compound, and a specific organoaluminum compound (B) represented by the general formula (I), with each other, wherein at least one selected from the solid catalyst component (A) and the organoaluminum compound (B) is previously subjected to contact treatment with a hydrocarbon compound having one or more vinyl groups.

The present invention provides a method for producing a catalyst for polymerization of an olefin, which suppresses a decrease in polymerization activity due to early deactivation of the active site after the catalyst has been formed, exhibits excellent catalyst activity at the time of polymerization of olefins, and can produce polymers of olefins, which are excellent in stereoregularity. The method for producing a catalyst for polymerization of an olefin includes contacting a solid catalyst component (A) containing magnesium, titanium, halogen and an internal electron-donating compound, and a specific organoaluminum compound (B) represented by the general formula (I), with each other, wherein at least one selected from the solid catalyst component (A) and the organoaluminum compound (B) is previously subjected to contact treatment with a hydrocarbon compound having one or more vinyl groups.

Embodiments of polyethylene formulations and articles comprising polyethylene formulations are disclosed. The polyethylene formulation may include from 45 wt. % to 90 wt. % of an MDPE having a density of from 0.930 g/cc to 0.950 g/cc and a melt index (I.sub.2) from 0.05 g/10 min to 0.5 g/10 min; from 10 wt. % to 50 wt. % of a polyethylene composition having a density from 0.910 g/cc to 0.936 g/cc and a melt index (I.sub.2) from 0.7 g/10 min to 1.0 g/10 min; and from 0.5 wt. % to 5% of a masterbatch composition. The polyethylene composition may comprise a first polyethylene fraction area in a temperature range of 45° C. to 87° C. of an elution profile via improved comonomer composition distribution (iCCD) analysis method and a second polyethylene fraction area in a temperature range of 95° C. to 120° C. of an elution profile via iCCD.

Embodiments of polyethylene formulations and articles comprising polyethylene formulations are disclosed. The polyethylene formulation may include from 45 wt. % to 90 wt. % of an MDPE having a density of from 0.930 g/cc to 0.950 g/cc and a melt index (I.sub.2) from 0.05 g/10 min to 0.5 g/10 min; from 10 wt. % to 50 wt. % of a polyethylene composition having a density from 0.910 g/cc to 0.936 g/cc and a melt index (I.sub.2) from 0.7 g/10 min to 1.0 g/10 min; and from 0.5 wt. % to 5% of a masterbatch composition. The polyethylene composition may comprise a first polyethylene fraction area in a temperature range of 45° C. to 87° C. of an elution profile via improved comonomer composition distribution (iCCD) analysis method and a second polyethylene fraction area in a temperature range of 95° C. to 120° C. of an elution profile via iCCD.

Embodiments of polyethylene formulations and articles comprising polyethylene formulations are disclosed. The polyethylene formulation may include from 45 wt. % to 90 wt. % of an MDPE having a density of from 0.930 g/cc to 0.950 g/cc and a melt index (I.sub.2) from 0.05 g/10 min to 0.5 g/10 min; from 10 wt. % to 50 wt. % of a polyethylene composition having a density from 0.910 g/cc to 0.936 g/cc and a melt index (I.sub.2) from 0.7 g/10 min to 1.0 g/10 min; and from 0.5 wt. % to 5% of a masterbatch composition. The polyethylene composition may comprise a first polyethylene fraction area in a temperature range of 45° C. to 87° C. of an elution profile via improved comonomer composition distribution (iCCD) analysis method and a second polyethylene fraction area in a temperature range of 95° C. to 120° C. of an elution profile via iCCD.

This invention relates to a method comprising contacting C3-C32 alpha olefin with catalyst system comprising activator and catalyst of the formula wherein: M is Hf or Zr; T is a bridging group; each X is independently a leaving group; R1 and R2 are independently hydrogen, or a Ci-Gto optionally substituted hydrocarbyl group, halide, or siloxyl group; R3, R4, R5 and R6 are independently a Ci-Gto optionally substituted hydrocarbyl, halocarbyl, silylcarbyl, aminocarbyl, or siloxyl group; and A is an aliphatic, aromatic or heteroaromatic ring, optionally bearing one or more additional fused rings which may be aliphatic, aromatic or heteroaromatic; obtaining a plurality of vinyl-terminated polyalphaolefins (PAOs) having at least 30 mol % vinyl terminated PAO's.

##STR00001##

This invention relates to a method comprising contacting C3-C32 alpha olefin with catalyst system comprising activator and catalyst of the formula wherein: M is Hf or Zr; T is a bridging group; each X is independently a leaving group; R1 and R2 are independently hydrogen, or a Ci-Gto optionally substituted hydrocarbyl group, halide, or siloxyl group; R3, R4, R5 and R6 are independently a Ci-Gto optionally substituted hydrocarbyl, halocarbyl, silylcarbyl, aminocarbyl, or siloxyl group; and A is an aliphatic, aromatic or heteroaromatic ring, optionally bearing one or more additional fused rings which may be aliphatic, aromatic or heteroaromatic; obtaining a plurality of vinyl-terminated polyalphaolefins (PAOs) having at least 30 mol % vinyl terminated PAO's.

##STR00001##

The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.85 to 0.90 g/cc, (2) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 15 g/10 min, (3) the density (d) and the melt temperature (Tm) satisfying Tm (° C.)=a×d−b of Equation 1 (2,350<a<2,500, and 1,900<b<2,100), and (4) a ratio (hardness/Tm) of the hardness (shore A) to the melt temperature (Tm) in a range of 1.0 to 1.3. The olefin-based polymer according to the present invention exhibits excellent anti-blocking properties due to having improved hardness as a low-density olefin-based polymer.

The present invention relates to an olefin-based polymer, which has (1) a density (d) ranging from 0.85 to 0.90 g/cc, (2) a melt index (MI, 190° C., 2.16 kg load conditions) ranging from 0.1 g/10 min to 15 g/10 min, (3) the density (d) and the melt temperature (Tm) satisfying Tm (° C.)=a×d−b of Equation 1 (2,350<a<2,500, and 1,900<b<2,100), and (4) a ratio (hardness/Tm) of the hardness (shore A) to the melt temperature (Tm) in a range of 1.0 to 1.3. The olefin-based polymer according to the present invention exhibits excellent anti-blocking properties due to having improved hardness as a low-density olefin-based polymer.

A method of continuously producing an ethylene-vinyl acetate copolymer in a polymerization vessel containing a reaction liquid containing ethylene, vinyl acetate, a polymerization initiator and methanol, the polymerization vessel being connected via piping to a heat exchanger circulating a coolant, the method includes the steps of: supplying ethylene, the polymerization initiator and methanol to the polymerization vessel; introducing pressurized gas containing ethylene present in a gas phase portion of the polymerization vessel into the heat exchanger; supplying vinyl acetate cooled to between −50° C. and 23° C. to an upper portion of the heat exchanger; flowing vinyl acetate down in the heat exchanger while absorbing ethylene; letting vinyl acetate dissolving ethylene out of a bottom portion of the heat exchanger and adding to the reaction liquid in the polymerization vessel; and taking the reaction liquid out of the polymerization vessel. This provides a method of efficiently removing heat during polymerization of an ethylene-vinyl acetate copolymer.