A supported metallocene catalyst includes a carrier and a metallocene component. The carrier includes an inorganic oxide particle and an alkyl aluminoxane material. The inorganic oxide particle includes at least one inorganic oxide compound selected from the group consisting of an oxide of Group 3A and an oxide of Group 4A. The alkyl aluminoxane material includes an alkyl aluminoxane compound and an alkyl aluminum compound that is present in amount ranging from greater than 0.01 wt % to less than 14 wt % base on 100 wt % of the alkyl aluminoxane material. The metallocene component is supported on the carrier, and includes one of a metallocene compound containing a metal from Group 3B, a metallocene compound containing a metal from Group 4B, and a combination thereof. A method for preparing the supported metallocene catalyst and a method for preparing polyolefin using the supported metallocene catalyst are also disclosed.

A processes for effecting the cationic polymerization of olefins in a controlled manner that includes the step of contacting olefin monomers and a catalytically effective amount of an initiating composition containing (A) a recyclable aluminum, gallium, or indium perfluorinated organosulfonate, (B) a solubilizing agent, (C) an initiator selected from the group consisting of (i) carbocation synthons, (ii) halogenium ion synthons, (iii) Brnsted acids, and (iv) silicenium ion synthons, and optionally (D) a nucleophilic additive. The invention further includes a process for recycling aluminum, gallium, or indium perfluorinated organosulfonates that includes the steps of aqueous extraction and dehydration. A novel initiator system is also disclosed.

A processes for effecting the cationic polymerization of olefins in a controlled manner that includes the step of contacting olefin monomers and a catalytically effective amount of an initiating composition containing (A) a recyclable aluminum, gallium, or indium perfluorinated organosulfonate, (B) a solubilizing agent, (C) an initiator selected from the group consisting of (i) carbocation synthons, (ii) halogenium ion synthons, (iii) Brnsted acids, and (iv) silicenium ion synthons, and optionally (D) a nucleophilic additive. The invention further includes a process for recycling aluminum, gallium, or indium perfluorinated organosulfonates that includes the steps of aqueous extraction and dehydration. A novel initiator system is also disclosed.

The present invention relates to an oligomerization catalyst a transition metal or transition metal precursor, a halogen-substituted organic ligand, and a heteroatom ligand, and to a method for selectively preparing 1-hexene or 1-octene from ethylene using the catalyst.

The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.

The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.

A method of forming a light-polyisobutylene may include polymerizing isobutene or an isobutene-containing monomer mixture in presence of a proton-form zeolite catalyst to form a light-polyisobutylene. A light-polyisobutylene may be formed by the method of polymerizing isobutene or an isobutene-containing monomer mixture in presence of a proton-form zeolite catalyst.

A method of forming a light-polyisobutylene may include polymerizing isobutene or an isobutene-containing monomer mixture in presence of a proton-form zeolite catalyst to form a light-polyisobutylene. A light-polyisobutylene may be formed by the method of polymerizing isobutene or an isobutene-containing monomer mixture in presence of a proton-form zeolite catalyst.

A method of curing a free-radically polymerizable composition includes contacting a curable composition with at least one metal oxide selected from the group consisting of magnesium oxide, ferrous metal oxides, aluminum oxide, nickel oxide, silver oxide, and combinations thereof. The curable composition includes: free-radically polymerizable compound; and a beta-dicarbonyl compound represented by the formula (I) or a salt thereof, wherein: X.sup.1 and X.sup.2 independently represent a covalent bond, wherein each R.sup.4 independently represents H or alkyl having from 1 to 18 carbon atoms; R.sup.1 and R.sup.2 independently represent a hydrocarbyl or substituted-hydrocarbyl group having from 1 to 18 carbon atoms, and R.sup.3 represents hydrogen, or a hydrocarbyl or substituted-hydrocarbyl group having from 1 to 18 carbon atoms, or taken together any two of R.sup.1, R.sup.2, or R.sup.3 form a five-membered or six-membered ring; an organic peroxide; and a quaternary ammonium halide. Articles including the cured compositions are also disclosed. ##STR00001##

A method of curing a free-radically polymerizable composition includes contacting a curable composition with at least one metal oxide selected from the group consisting of magnesium oxide, ferrous metal oxides, aluminum oxide, nickel oxide, silver oxide, and combinations thereof. The curable composition includes: free-radically polymerizable compound; and a beta-dicarbonyl compound represented by the formula (I) or a salt thereof, wherein: X.sup.1 and X.sup.2 independently represent a covalent bond, wherein each R.sup.4 independently represents H or alkyl having from 1 to 18 carbon atoms; R.sup.1 and R.sup.2 independently represent a hydrocarbyl or substituted-hydrocarbyl group having from 1 to 18 carbon atoms, and R.sup.3 represents hydrogen, or a hydrocarbyl or substituted-hydrocarbyl group having from 1 to 18 carbon atoms, or taken together any two of R.sup.1, R.sup.2, or R.sup.3 form a five-membered or six-membered ring; an organic peroxide; and a quaternary ammonium halide. Articles including the cured compositions are also disclosed. ##STR00001##