Patent classifications
C08F4/16
Solid catalyst component for olefin polymerization
To produce an olefin-based polymer having a minor amount of decrease in bulk density due to heat. A solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and as internal electron donor, and having an envelope E1 calculated by the following Formula (1) in a range of 0.810 to 0.920.
E1=LE1/LS1 (1) (In Formula, LE1 is a convex hull perimeter of the solid catalyst component for olefin polymerization obtained from an image of the solid catalyst component for olefin polymerization captured with a scanning electron microscope, and LS1 is an actual perimeter of the solid catalyst component for olefin polymerization obtained from the image of the solid catalyst component for olefin polymerization captured with the scanning electron microscope.)
Solid catalyst component for olefin polymerization
To produce an olefin-based polymer having a minor amount of decrease in bulk density due to heat. A solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and as internal electron donor, and having an envelope E1 calculated by the following Formula (1) in a range of 0.810 to 0.920.
E1=LE1/LS1 (1) (In Formula, LE1 is a convex hull perimeter of the solid catalyst component for olefin polymerization obtained from an image of the solid catalyst component for olefin polymerization captured with a scanning electron microscope, and LS1 is an actual perimeter of the solid catalyst component for olefin polymerization obtained from the image of the solid catalyst component for olefin polymerization captured with the scanning electron microscope.)
Polyolefin Dispersants and Methods of Making and Using Thereof
Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below
##STR00001##
where R.sup.x is cationic initiator residue; R.sup.a is a polyolefin group; R.sup.1 and R.sup.2 are each, independently in each —(CR.sup.1R.sup.2) unit, H, alkyl, alkoxy, or alkylaryl; R.sup.3 and R.sup.4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.
Polyolefin Dispersants and Methods of Making and Using Thereof
Provided herein are polyolefin dispersants, as well as methods for producing polyolefin dispersants. The polyolefin dispersants can be defined by the formula below
##STR00001##
where R.sup.x is cationic initiator residue; R.sup.a is a polyolefin group; R.sup.1 and R.sup.2 are each, independently in each —(CR.sup.1R.sup.2) unit, H, alkyl, alkoxy, or alkylaryl; R.sup.3 and R.sup.4 are each, independently, H, alkyl, or alkoxy; m is an integer from 1 to 20; n is an integer from 1 to 6; r is an integer from 1 to 4; Y is a polyvalent amine linker comprising one or more tertiary amines, wherein the polyvalent amine linker does not include a primary amine or a secondary amine; and A is absent, or comprises a dispersive moiety.
Multisite heterogeneous catalyst, process for preparing the same and process for obtaining polyolefins using said catalyst
The instant invention relates to the use of titanium-based oxopolymers for preparing suitable catalysts for reactions of olefin polymerization and/or olefin and alpha-olefin copolymerization. The instant invention further discloses the synthesis of catalyst formulated from titanium-based oxopolymers, as well as its use for olefin polymerization and/or copolymerization reactions.
Process for preparing high-reactivity isobutene homo- or copolymers
The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
Process for preparing high-reactivity isobutene homo- or copolymers
The present invention relates to a novel process for preparing high-reactivity isobutene homo- or copolymers with a content of terminal vinylidene double bonds per polyisobutene chain end of at least 70 mol %. The present invention further relates to novel isobutene polymers.
CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
A catalyst mixture made from or containing (a) particles of a solid catalyst component comprising Ti, Mg, Cl, and (b) from 0.5 to 5.0% by weight, based upon the total weight of the mixture, of particles of a solid compound having particle size ranging from 0.1 m to 1 mm containing more than 50% by weight of SiO.sub.2 units.
CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS
A catalyst mixture made from or containing (a) particles of a solid catalyst component comprising Ti, Mg, Cl, and (b) from 0.5 to 5.0% by weight, based upon the total weight of the mixture, of particles of a solid compound having particle size ranging from 0.1 m to 1 mm containing more than 50% by weight of SiO.sub.2 units.
METHODS OF RECYCLING AND RESHAPING THERMOSETTING POLYMERS AND COMPOSITES THEREOF
Various methods of reshaping and recycling thermoset polymers and composites containing thermoset polymers are provided. The methods involve the bond exchange reaction of exchangeable covalent bonds in the polymer matrix with a suitable small molecule solvent in the presence of a catalyst. In some aspects, the methods are applied to a carbon fiber reinforced polymer or a thermoset polymer where the thermoset polymer matrix includes a plurality of ester bonds. Using a small molecule alcohol, the methods provide for recycling one or both of the carbon fiber and the polymer, for welding two surfaces, or for repairing a damaged surface in the materials.