A method for green synthesis of uniform- and large-particle-size polystyrene particles, comprising steps of: prepolymerizing styrene at 70 to 75 for 1 h to 6 h in advance while stirring, adding divinylbenzene dissolved with initiators to the styrene, and stirring for 10 min to 30 min to obtain oil phase; heating lactic acid or an aqueous solution of lactic acid to 70 to 80, adding the oil phase to dispersed phase by a constant-pressure device, maintaining the temperature for 2 h, heating to 805 and then maintaining the temperature for 1 h, and heating to 855 and then maintaining the temperature for 3 h to 6 h, to obtain polystyrene particles with a uniform particle size ranging from 0.7 mm to 2.0 mm.

A method for green synthesis of uniform- and large-particle-size polystyrene particles, comprising steps of: prepolymerizing styrene at 70 to 75 for 1 h to 6 h in advance while stirring, adding divinylbenzene dissolved with initiators to the styrene, and stirring for 10 min to 30 min to obtain oil phase; heating lactic acid or an aqueous solution of lactic acid to 70 to 80, adding the oil phase to dispersed phase by a constant-pressure device, maintaining the temperature for 2 h, heating to 805 and then maintaining the temperature for 1 h, and heating to 855 and then maintaining the temperature for 3 h to 6 h, to obtain polystyrene particles with a uniform particle size ranging from 0.7 mm to 2.0 mm.

Pressure-responsive particles include pressure-responsive base particles and fatty acid metal salt particles, in which the pressure-responsive base particles contain a styrene-based resin which contains styrene and other vinyl monomers as polymerization components and a (meth)acrylic acid ester-based resin which contains at least two kinds of (meth)acrylic acid esters as polymerization components and in which amass ratio of the (meth)acrylic acid esters to all polymerization components is 90% by mass or higher, the pressure-responsive particles have at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30? C. or higher.

Pressure-responsive particles include pressure-responsive base particles and fatty acid metal salt particles, in which the pressure-responsive base particles contain a styrene-based resin which contains styrene and other vinyl monomers as polymerization components and a (meth)acrylic acid ester-based resin which contains at least two kinds of (meth)acrylic acid esters as polymerization components and in which amass ratio of the (meth)acrylic acid esters to all polymerization components is 90% by mass or higher, the pressure-responsive particles have at least two glass transition temperatures, and a difference between the lowest glass transition temperature and the highest glass transition temperature is 30? C. or higher.

A method for producing particles of a fluorinated polymer (A) which has either one or both of structural units (u1) derived from tetrafluoroethylene and structural units (u2) having no sulfonic acid type functional group and having a cyclic structure and fluorine atoms, and which has structural units (u3) having a sulfonic acid type functional group, wherein the proportion of the structural units (u1) is from 0 to 82 mol % in all structural units in the fluorinated polymer (A), the method including: (i) preparing solution or dispersion of the fluorinated polymer (A) having the fluorinated polymer (A) dissolved or dispersed in a solvent (B); and (ii) mixing the solution or dispersion of the fluorinated polymer (A) and a solvent (C) to aggregate the fluorinated polymer (A) to form particles of the fluorinated polymer (A).

A method for producing particles of a fluorinated polymer (A) which has either one or both of structural units (u1) derived from tetrafluoroethylene and structural units (u2) having no sulfonic acid type functional group and having a cyclic structure and fluorine atoms, and which has structural units (u3) having a sulfonic acid type functional group, wherein the proportion of the structural units (u1) is from 0 to 82 mol % in all structural units in the fluorinated polymer (A), the method including: (i) preparing solution or dispersion of the fluorinated polymer (A) having the fluorinated polymer (A) dissolved or dispersed in a solvent (B); and (ii) mixing the solution or dispersion of the fluorinated polymer (A) and a solvent (C) to aggregate the fluorinated polymer (A) to form particles of the fluorinated polymer (A).

A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders.

A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders.

A composite powder includes a core particle comprising a styrene/acrylate polymer resin, and a shell comprising a styrene/acrylate ionomer resin, wherein the styrene/acrylate ionomer resin comprises a metal ion acrylate monomer, and methods of making thereof. Various articles can be manufactured from such composite powders.

Provided is a method of preparing a graft polymer, which includes: polymerizing a monomer mixture comprising a carboxylic acid monomer and methyl acrylate, wherein the carboxylic acid monomer is included at 1.5 to 2.5 wt %, and thus preparing an acrylic coagulant having an average particle diameter of 60 to 70 nm; polymerizing diene-based monomers in the presence of an emulsifier containing a salt of a compound and thus preparing a first diene-based rubber polymer; enlarging the first diene-based rubber polymer using the acrylic coagulant and thus preparing a second diene-based rubber polymer; and graft-polymerizing an aromatic vinyl-based monomer and a vinyl cyanide-based monomer to the second diene-based rubber polymer and thus preparing a graft polymer.