C08F6/22

ACRYLIC COPOYMER, ACRYLIC COPOYMER-CONTAINING COMPOSITION AND CROSSLINKED PRODUCT OF SAME
20230174696 · 2023-06-08 ·

The present invention aims to provide an acrylic copolymer capable of maintaining excellent storage stability in the uncrosslinked state even after long-term exposure to high temperatures, and a crosslinked acrylic rubber product produced from the acrylic copolymer which maintains good normal-state properties and good water resistance. The present invention is based on the finding that an acrylic copolymer produced by polymerizing a liquid mixture of an alkoxyalkyl (meth)acrylate containing an alkoxyalkyl group and a crosslinkable monomer containing a carboxy group has excellent storage stability and that a crosslinked product produced from the acrylic copolymer has good normal-state properties and good water resistance.

METHOD FOR PRODUCING PARTICULATE POLYMER

A method for producing a particulate polymer includes polymerizing a monomer having a vinyl group in an aqueous solvent in the presence of a surfactin salt and a polymerization initiator, wherein a concentration of the surfactin salt in a polymerization reaction liquid is adjusted depending on a target particle diameter of the particulate polymer.

METHOD FOR PRODUCING PARTICULATE POLYMER

A method for producing a particulate polymer includes polymerizing a monomer having a vinyl group in an aqueous solvent in the presence of a surfactin salt and a polymerization initiator, wherein a concentration of the surfactin salt in a polymerization reaction liquid is adjusted depending on a target particle diameter of the particulate polymer.

METHOD FOR PRODUCING PARTICULATE POLYMER

A method for producing a particulate polymer includes polymerizing a monomer having a vinyl group in an aqueous solvent in the presence of a surfactin salt and a polymerization initiator, wherein a concentration of the surfactin salt in a polymerization reaction liquid is adjusted depending on a target particle diameter of the particulate polymer.

METHOD FOR PREPARING GRAFT COPOLYMER, GRAFT COPOLYMER, AND RESIN COMPOSITION COMPRISING THE SAME

The present disclosure relates to a method for preparing a graft copolymer, a graft copolymer prepared therefrom, and a resin composition including the same. The method includes introducing a polymer coagulant latex including a polymer coagulant to a rubbery polymer latex including a rubbery polymer and coagulating the polymer coagulant latex to prepare an enlarged rubbery polymer latex containing an enlarged rubbery polymer, and introducing an aromatic vinyl-based monomer and a vinyl cyan-based monomer to the prepared enlarged rubbery polymer latex and performing graft polymerization to prepare a graft copolymer latex including a graft copolymer. The polymer coagulant includes an acid group-containing copolymer having a weight average molecular weight of 550,000 g/mol to 750,000 g/mol, and the content of the vinyl cyan-based monomer is 15 wt % to 24 wt % based on the total content of the aromatic vinyl-based monomer and the vinyl cyan-based monomer.

METHOD FOR PREPARING GRAFT COPOLYMER, GRAFT COPOLYMER, AND RESIN COMPOSITION COMPRISING THE SAME

The present disclosure relates to a method for preparing a graft copolymer, a graft copolymer prepared therefrom, and a resin composition including the same. The method includes introducing a polymer coagulant latex including a polymer coagulant to a rubbery polymer latex including a rubbery polymer and coagulating the polymer coagulant latex to prepare an enlarged rubbery polymer latex containing an enlarged rubbery polymer, and introducing an aromatic vinyl-based monomer and a vinyl cyan-based monomer to the prepared enlarged rubbery polymer latex and performing graft polymerization to prepare a graft copolymer latex including a graft copolymer. The polymer coagulant includes an acid group-containing copolymer having a weight average molecular weight of 550,000 g/mol to 750,000 g/mol, and the content of the vinyl cyan-based monomer is 15 wt % to 24 wt % based on the total content of the aromatic vinyl-based monomer and the vinyl cyan-based monomer.

METHOD FOR PREPARING GRAFT COPOLYMER, GRAFT COPOLYMER, AND RESIN COMPOSITION COMPRISING THE SAME

The present disclosure relates to a method for preparing a graft copolymer, a graft copolymer prepared therefrom, and a resin composition including the same. The method includes introducing a polymer coagulant latex including a polymer coagulant to a rubbery polymer latex including a rubbery polymer and coagulating the polymer coagulant latex to prepare an enlarged rubbery polymer latex containing an enlarged rubbery polymer, and introducing an aromatic vinyl-based monomer and a vinyl cyan-based monomer to the prepared enlarged rubbery polymer latex and performing graft polymerization to prepare a graft copolymer latex including a graft copolymer. The polymer coagulant includes an acid group-containing copolymer having a weight average molecular weight of 550,000 g/mol to 750,000 g/mol, and the content of the vinyl cyan-based monomer is 15 wt % to 24 wt % based on the total content of the aromatic vinyl-based monomer and the vinyl cyan-based monomer.

Method of preparing thermoplastic resin

The present invention relates to a method of preparing a thermoplastic resin. In accordance with the present invention, provided is a thermoplastic resin having superior antibiosis and melt-kneadability prepared through preparation of a graft copolymer latex and coagulation of the graft copolymer latex with a specific antimicrobial agent, and a method of preparing the thermoplastic resin to prepare a thermoplastic resin composition including the thermoplastic resin.

Method of preparing thermoplastic resin

The present invention relates to a method of preparing a thermoplastic resin. In accordance with the present invention, provided is a thermoplastic resin having superior antibiosis and melt-kneadability prepared through preparation of a graft copolymer latex and coagulation of the graft copolymer latex with a specific antimicrobial agent, and a method of preparing the thermoplastic resin to prepare a thermoplastic resin composition including the thermoplastic resin.

Method of preparing thermoplastic resin

The present invention relates to a method of preparing a thermoplastic resin. In accordance with the present invention, provided is a thermoplastic resin having superior antibiosis and melt-kneadability prepared through preparation of a graft copolymer latex and coagulation of the graft copolymer latex with a specific antimicrobial agent, and a method of preparing the thermoplastic resin to prepare a thermoplastic resin composition including the thermoplastic resin.